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Abstract:

The kinetics of hydrogen evolution reaction (HER) was studied on nickel catalysts prepared using a ruthenium spontaneous deposition method. Rotating disk electrode (RDE) and electrochemical impedance spectroscopy (EIS) were used for electrochemical characterization, and the results of the analysis were compared with pure nickel catalysts. Three different deposition times were used to obtain different ruthenium loads and to analyze their impact on the electrocatalytic activity. Kinetic and thermodynamic parameters of the reaction were obtained for freshly synthesized catalysts, and also for catalysts aged using a short chronoamperometric procedure. The presence of ruthenium was found to shift the reaction onset potential up to about 160 mV to lower overpotentials comparing with pure nickel, which not increases after ageing, showing a substantial improvement in catalytic activity. Results of Tafel and Koutecky-Levich (K-L) analysis have shown that the HER rate determining step is the Volmer reaction with Langmuir type adsorption for both, Ni/Ru fresh and aged catalysts. © 2015 Hydrogen Energy Publications, LLC.

Registro:

Documento: Artículo
Título:Kinetics of hydrogen evolution reaction on nickel modified by spontaneous Ru deposition: A rotating disk electrode and impedance spectroscopy approach
Autor:Franceschini, E.A.; Lacconi, G.I.; Corti, H.R.
Filiación:Departamento de Física de la Materia Condensada, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499 (B1650KNA), San Martín, Buenos Aires, Argentina
INFIQC-CONICET, Dto. de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Córdoba, 5000, Argentina
Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE-CONICET, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón II, C1428EHA, Buenos Aires, Argentina
Palabras clave:Hydrogen generation; Impedance spectroscopy; Nickel/ruthenium; Rotating disk electrode; Spontaneous deposition; Catalyst activity; Catalysts; Deposition; Electrochemical electrodes; Electrochemical impedance spectroscopy; Electrodes; Hydrogen production; Kinetics; Nickel; Reaction kinetics; Ruthenium; Spectroscopy; Spectrum analysis; Electrocatalytic activity; Electrochemical characterizations; Hydrogen evolution reactions; Hydrogen generations; Impedance spectroscopy; Kinetic and thermodynamic parameters; Rotating disk electrodes; Spontaneous deposition; Rotating disks
Año:2016
Volumen:41
Número:5
Página de inicio:3326
Página de fin:3338
DOI: http://dx.doi.org/10.1016/j.ijhydene.2015.12.143
Título revista:International Journal of Hydrogen Energy
Título revista abreviado:Int J Hydrogen Energy
ISSN:03603199
CODEN:IJHED
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v41_n5_p3326_Franceschini

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Citas:

---------- APA ----------
Franceschini, E.A., Lacconi, G.I. & Corti, H.R. (2016) . Kinetics of hydrogen evolution reaction on nickel modified by spontaneous Ru deposition: A rotating disk electrode and impedance spectroscopy approach. International Journal of Hydrogen Energy, 41(5), 3326-3338.
http://dx.doi.org/10.1016/j.ijhydene.2015.12.143
---------- CHICAGO ----------
Franceschini, E.A., Lacconi, G.I., Corti, H.R. "Kinetics of hydrogen evolution reaction on nickel modified by spontaneous Ru deposition: A rotating disk electrode and impedance spectroscopy approach" . International Journal of Hydrogen Energy 41, no. 5 (2016) : 3326-3338.
http://dx.doi.org/10.1016/j.ijhydene.2015.12.143
---------- MLA ----------
Franceschini, E.A., Lacconi, G.I., Corti, H.R. "Kinetics of hydrogen evolution reaction on nickel modified by spontaneous Ru deposition: A rotating disk electrode and impedance spectroscopy approach" . International Journal of Hydrogen Energy, vol. 41, no. 5, 2016, pp. 3326-3338.
http://dx.doi.org/10.1016/j.ijhydene.2015.12.143
---------- VANCOUVER ----------
Franceschini, E.A., Lacconi, G.I., Corti, H.R. Kinetics of hydrogen evolution reaction on nickel modified by spontaneous Ru deposition: A rotating disk electrode and impedance spectroscopy approach. Int J Hydrogen Energy. 2016;41(5):3326-3338.
http://dx.doi.org/10.1016/j.ijhydene.2015.12.143