Artículo

González-Gil, R.; Chamorro-Burgos, I.; Herrera, C.; Larrubia, M.A.; Laborde, M.; Mariño, F.; Alemany, L.J. "Production of hydrogen by catalytic steam reforming of oxygenated model compounds on Ni-modified supported catalysts. Simulation and experimental study" (2015) International Journal of Hydrogen Energy. 40(34):11217-11227
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Abstract:

Steam reforming of two representative components in the aqueous fraction of bio-oil, acetone and ethanol, was investigated over nickel based supported catalysts (Ni/Al2O3). The effect of Rh incorporation (Ni-Rh/Al2O3) and the properties of different γ-Al2O3 used as support was tested. Hydrogen-rich gas is produced at temperatures higher than 673 K in both acetone and ethanol reforming with maximum mole fraction of 0.6-0.7. The reactions involved and the possible routes were studied. Rh incorporation and nanostructured alumina affects the Ni metal size and the amount of carbon deposited onto catalysts' surface after reforming tests; besides, acetone is also found as an important intermediate in ethanol reforming, and Rh improve hydrogen production with negligible intermediates presence. The effect of S/Acetone or S/Ethanol feed molar ratios, space velocity and temperature over acetone/ethanol conversion and over H2/CO ratio were modeled using the Matlab software in order to find the regions and the optimal operating conditions in both processes. Simulation results are consistent with the experimental data. © 2015 Hydrogen Energy Publications, LLC. All rights reserved.

Registro:

Documento: Artículo
Título:Production of hydrogen by catalytic steam reforming of oxygenated model compounds on Ni-modified supported catalysts. Simulation and experimental study
Autor:González-Gil, R.; Chamorro-Burgos, I.; Herrera, C.; Larrubia, M.A.; Laborde, M.; Mariño, F.; Alemany, L.J.
Filiación:Tecnologías de Procesos Catalíticos (PROCAT), Departamento de Ingeniería Química, Facultad de Ciencias, Universidad de MálagaE-29071, Spain
ITHES (CONICET/Universidad de Buenos Aires) - Pabellón de Industrias, Ciudad Universitaria1428, Argentina
Palabras clave:Hydrogen; Mathematical model; Ni-modified catalysts; Oxygenated compounds; Steam reforming; Acetone; Alumina; Carbon; Catalyst supports; Catalysts; Catalytic reforming; Ethanol; Hydrogen; Hydrogen production; Mathematical models; MATLAB; Nickel; Rhodium; Aqueous fractions; Catalytic steam reforming; Ethanol reforming; Hydrogen-rich gas; Ni-modified; Optimal operating conditions; Oxygenated compounds; Production of hydrogen; Steam reforming
Año:2015
Volumen:40
Número:34
Página de inicio:11217
Página de fin:11227
DOI: http://dx.doi.org/10.1016/j.ijhydene.2015.05.167
Título revista:International Journal of Hydrogen Energy
Título revista abreviado:Int. J. Hydrogen Energy
ISSN:03603199
CODEN:IJHED
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v40_n34_p11217_GonzalezGil

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Citas:

---------- APA ----------
González-Gil, R., Chamorro-Burgos, I., Herrera, C., Larrubia, M.A., Laborde, M., Mariño, F. & Alemany, L.J. (2015) . Production of hydrogen by catalytic steam reforming of oxygenated model compounds on Ni-modified supported catalysts. Simulation and experimental study. International Journal of Hydrogen Energy, 40(34), 11217-11227.
http://dx.doi.org/10.1016/j.ijhydene.2015.05.167
---------- CHICAGO ----------
González-Gil, R., Chamorro-Burgos, I., Herrera, C., Larrubia, M.A., Laborde, M., Mariño, F., et al. "Production of hydrogen by catalytic steam reforming of oxygenated model compounds on Ni-modified supported catalysts. Simulation and experimental study" . International Journal of Hydrogen Energy 40, no. 34 (2015) : 11217-11227.
http://dx.doi.org/10.1016/j.ijhydene.2015.05.167
---------- MLA ----------
González-Gil, R., Chamorro-Burgos, I., Herrera, C., Larrubia, M.A., Laborde, M., Mariño, F., et al. "Production of hydrogen by catalytic steam reforming of oxygenated model compounds on Ni-modified supported catalysts. Simulation and experimental study" . International Journal of Hydrogen Energy, vol. 40, no. 34, 2015, pp. 11217-11227.
http://dx.doi.org/10.1016/j.ijhydene.2015.05.167
---------- VANCOUVER ----------
González-Gil, R., Chamorro-Burgos, I., Herrera, C., Larrubia, M.A., Laborde, M., Mariño, F., et al. Production of hydrogen by catalytic steam reforming of oxygenated model compounds on Ni-modified supported catalysts. Simulation and experimental study. Int. J. Hydrogen Energy. 2015;40(34):11217-11227.
http://dx.doi.org/10.1016/j.ijhydene.2015.05.167