Artículo

Viva, F.A.; Bruno, M.M.; Franceschini, E.A.; Thomas, Y.R.J.; Ramos Sanchez, G.; Solorza-Feria, O.; Corti, H.R. "Mesoporous carbon as Pt support for PEM fuel cell" (2014) International Journal of Hydrogen Energy. 39(16):8821-8826
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Abstract:

A mesoporous carbon (MP) supported Pt nanocatalyst was evaluated as anode and cathode catalyst for PEM fuel cell. Kinetics study of the oxygen reduction reaction were characterized by using the rotating disk electrode (RDE) and rotating ring disk electrode (RRDE) techniques in acid media. Membrane electrode assemblies (MEAs) were prepared using Pt supported on MP as anodic and cathodic catalysts and the fuel cell performance evaluated. Polarization and power curves show a similar performance as cathode catalyst when compared to commercial catalyst while there is an 8% improvement when used as anode catalyst. © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

Registro:

Documento: Artículo
Título:Mesoporous carbon as Pt support for PEM fuel cell
Autor:Viva, F.A.; Bruno, M.M.; Franceschini, E.A.; Thomas, Y.R.J.; Ramos Sanchez, G.; Solorza-Feria, O.; Corti, H.R.
Filiación:Grupo Celdas de Combustible, Departamento de Física de la Materia Condensada, Comisión Nacional de Energía Atómica (CNEA), Av General Paz 1499, 1650 San-Martín, Buenos Aires, Argentina
Escuela de Ciencia y Tecnología, Universidad de Gral. San Martín, Martin de Irigoyen 3100, 1650 San-Martín, Buenos Aires, Argentina
Departamento de Química, Centro de Investigación y Estudios Avanzados Del IPN, Av. IPN 2508, Col. San Pedro Zacatenco, A. Postal 14-740, 07360 Mexico D.F., Mexico
Instituto de Química Física de Los Materiales, Medio Ambiente y Energía (INQUIMAE), Ciudad Universitaria, Pabellón II, 1428 Buenos Aire, Argentina
Palabras clave:Mesoporous carbon; ORR; Polarization curves; RDE; Supported Pt; Carbon; Cathodes; Electrolytic reduction; Mesoporous materials; Platinum; Polarization; Proton exchange membrane fuel cells (PEMFC); Reaction kinetics; Rotating disks; Mesoporous carbon; ORR; Polarization curves; RDE; Supported Pt; Catalysts
Año:2014
Volumen:39
Número:16
Página de inicio:8821
Página de fin:8826
DOI: http://dx.doi.org/10.1016/j.ijhydene.2013.12.027
Título revista:International Journal of Hydrogen Energy
Título revista abreviado:Int J Hydrogen Energy
ISSN:03603199
CODEN:IJHED
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v39_n16_p8821_Viva

Referencias:

  • Peighambardoust, S.J., Rowshanzamir, S., Amjadi, M., Review of the proton exchange membranes for fuel cell applications (2010) Int J Hydrogen Energy, 35, pp. 9349-9384
  • Kriston, Á., Xie, T., Gamliel, D., Ganesan, P., Popov, B.N., Effect of ultra-low Pt loading on mass activity of polymer electrolyte membrane fuel cells (2013) J Power Sources, 243, pp. 958-963
  • Bar-On, I., Kirchain, R., Roth, R., Technical cost analysis for PEM fuel cells (2004) J Power Sources, 109 (2002), pp. 71-75
  • O'Hayre, R., Cha, S.W., Colella, W., Prinz, F.B., (2006) Fuel Cell Fundamentals, , John Wiley & Sons New York
  • Figueiredo, J., Pereira, M., Serp, P., Kalck, P., Samant, P., Fernandes, J., Development of carbon nanotube and carbon xerogel supported catalysts for the electro-oxidation of methanol in fuel cells (2006) Carbon, 44, pp. 2516-2522
  • Liu, H., Song, C., Zhang, L., Zhang, J., Wang, H., Wilkinson, D., A review of anode catalysis in the direct methanol fuel cell (2006) J Power Sources, 155, pp. 95-110
  • Cui, Z., Liu, C., Liao, J., Xing, W., Highly active PtRu catalysts supported on carbon nanotubes prepared by modified impregnation method for methanol electro-oxidation (2008) Electrochim Acta, 53, pp. 7807-7811
  • Park, S.J., Kim, B.J., Lee, S.Y., Effect of surface modification of mesoporous carbon supports on the electrochemical activity of fuel cells (2013) J Coll Interfac Sci, 405, pp. 150-156
  • Arbizzani, C., Beninati, S., Soavi, F., Varzi, A., Mastragostino, M., Supported PtRu on mesoporous carbons for direct methanol fuel cells (2008) J Power Sources, 185, pp. 615-620
  • Alegre, C., Calvillo, L., Moliner, R., Gonzalez-Exposito, J.A., Guillen-Villafuerte, O., Martinez Huerta, M.V., Pt and PtRu electrocatalysts supported on carbon xerogels for direct methanol fuel cells (2011) J Power Sources, 196, pp. 4226-4235
  • Joo, S.H., Pak, C., You, D.J., Lee, S.-A., Lee, H.I., Kim, J.M., Ordered mesoporous carbons (OMC) as supports of electrocatalysts for direct methanol fuel cells (DMFC): Effect of carbon precursors of OMC on DMFC performances (2006) Electrochim Acta, 52, pp. 1618-1626
  • Sharma, S., Pollet, B.G., Support materials for PEMFC and DMFC electrocatalysts - A review (2012) J Power Sources, 208 (0), pp. 96-119
  • Joo, S.H., Kwon, K., You, D.J., Pak, C., Chang, H., Kim, J.M., Preparation of high loading Pt nanoparticles on ordered mesoporous carbon with a controlled Pt size and its effects on oxygen reduction and methanol oxidation reactions (2009) Electrochim Acta, 54, pp. 5746-5753
  • Cheon, J.Y., Ahn, C., You, D.J., Pak, C., Hur, S.H., Kim, J., Ordered mesoporous carbon-carbon nanotube nanocomposites as highly conductive and durable cathode catalyst supports for polymer electrolyte fuel cells (2013) J Mater Chem A, 1, pp. 1270-1283
  • Bruno, M.M., Petruccelli, M.A., Viva, F.A., Corti, H.R., Mesoporous carbon supported PtRu as anode catalyst for direct methanol fuel cell: Polarization measurements and electrochemical impedance analysis of mass transport (2013) Int J Hydrogen Energ, 38, pp. 4116-4123
  • Ramos-Sánchez, G., Bruno, M.M., Thomas, Y.R.J., Corti, H.R., Solorza-Feria, O., Mesoporous carbon supported nanoparticulated PdNi2: A methanol tolerant oxygen reduction electrocatalyst (2012) Int J Hydrogen Energ, 37, pp. 31-40
  • Viva, F.A., Bruno, M.M., Jobbagy, M., Corti, H.R., Electrochemical characterization of PtRu nanoparticles supported on mesoporous carbon for methanol electrooxidation (2012) J Phys Chem C, 116, pp. 4097-4104
  • Bruno, M.M., Viva, F.A., Petruccelli, M.A., Corti, H.R., Pt electrocatalyst supported on mesoporous carbon as cathode for direct methanol fuel cell (2013) J Appl Elect, , [submitted for publication]
  • Bruno, M.M., Cotella, N.G., Miras, M.C., Koch, T., Seidler, S., Barbero, C., Characterization of monolithic porous carbon prepared from resorcinol/formaldehyde gels with cationic surfactant (2010) Colloids Surfaces A, 358, pp. 13-20
  • Suárez-Alcántara, K., Rodríguez-Castellanos, A., Dante, R., Solorza-Feria, O., RuxCrySez electrocatalyst for oxygen reduction in a polymer electrolyte membrane fuel cell (2006) J Power Sources, 157, pp. 114-120
  • Suárez-Alcántara, K., Solorza-Feria, O., Evaluation of RuxWySez catalyst as a cathode electrode in a polymer electrolyte membrane fuel cell (2010) Fuel Cells, 10, pp. 84-92
  • Franceschini, E.A., Bruno, M.M., Viva, A.F., Williams, F.J., Jobbágy, M., Corti, H.R., Mesoporous Pt electrocatalyst for methanol tolerant cathodes of DMFC (2012) Electrochim Acta, 71, pp. 173-180
  • Bard, A.J., Faulkner, L.R., (1980) Electrochemical Methods. Fundamentals and Applications, , 1st ed. J. Wiley & Sons
  • Couteanceau, C., Crouigneau, P., Léger, J.M., Lamy, C., Mechanism of oxygen electroreduction at polypyrrole electrodes modified by cobalt phtalocyanine (1994) J Electroanal Chem, p. 389
  • Lide, D.R., (2009) CRC Handbook of Chemistry and Physics, , 90th ed. CRC
  • Gasteiger, H.A., Gu, W., Makharia, R., Mathias, M.F., Sompalli, B., (2003) Handbook of Fuel Cells: Fundamentals, Technology, Applications, , W. Vielstich, A. Lamm, H.A. Gasteiger, John Wiley & Sons West Sussex, UK
  • Rao, V., Simonov, P.A., Savinova, E.R., Plaksin, G.V., Cherepanova, S.V., Kryukova, G.N., The influence of carbon support porosity on the activity of PtRu/Sibunit anode catalysts for methanol oxidation (2005) J Power Sources, 145, pp. 178-187
  • Mu, S., Tian, M., Optimization of perfluorosulfonic acid ionomer loadings in catalyst layers of proton exchange membrane fuel cells (2012) Electrochim Acta, 60, pp. 437-442

Citas:

---------- APA ----------
Viva, F.A., Bruno, M.M., Franceschini, E.A., Thomas, Y.R.J., Ramos Sanchez, G., Solorza-Feria, O. & Corti, H.R. (2014) . Mesoporous carbon as Pt support for PEM fuel cell. International Journal of Hydrogen Energy, 39(16), 8821-8826.
http://dx.doi.org/10.1016/j.ijhydene.2013.12.027
---------- CHICAGO ----------
Viva, F.A., Bruno, M.M., Franceschini, E.A., Thomas, Y.R.J., Ramos Sanchez, G., Solorza-Feria, O., et al. "Mesoporous carbon as Pt support for PEM fuel cell" . International Journal of Hydrogen Energy 39, no. 16 (2014) : 8821-8826.
http://dx.doi.org/10.1016/j.ijhydene.2013.12.027
---------- MLA ----------
Viva, F.A., Bruno, M.M., Franceschini, E.A., Thomas, Y.R.J., Ramos Sanchez, G., Solorza-Feria, O., et al. "Mesoporous carbon as Pt support for PEM fuel cell" . International Journal of Hydrogen Energy, vol. 39, no. 16, 2014, pp. 8821-8826.
http://dx.doi.org/10.1016/j.ijhydene.2013.12.027
---------- VANCOUVER ----------
Viva, F.A., Bruno, M.M., Franceschini, E.A., Thomas, Y.R.J., Ramos Sanchez, G., Solorza-Feria, O., et al. Mesoporous carbon as Pt support for PEM fuel cell. Int J Hydrogen Energy. 2014;39(16):8821-8826.
http://dx.doi.org/10.1016/j.ijhydene.2013.12.027