Abstract:
Hydrogen to be used as a raw material in fuel cells or even as a direct fuel can be obtained from steam reforming of bioethanol. The key aim of this process is to maximize hydrogen production, discouraging at the same time those reactions leading to undesirable products, such as methane, acetaldehyde, diethyl ether or acetic acid, that compete with H2 for the hydrogen atoms. Cu-Ni-K/γ-Al2O3 catalysts are suitable for this reaction since they are able to produce acceptable amounts of hydrogen working at atmospheric pressure and a temperature of 300°C. The effect of nickel content in the catalyst on the steam-reforming reaction was analyzed. Nickel addition enhances ethanol gasification, increasing the gas yield and reducing acetaldehyde and acetic acid production. © 2001 International Association for Hydrogen Energy.
Registro:
Documento: |
Artículo
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Título: | Hydrogen production from steam reforming of bioethanol using Cu/Ni/K/γ-Al2O3 catalysts. Effect of Ni |
Autor: | Mariño, F.; Boveri, M.; Baronetti, G.; Laborde, M. |
Filiación: | Departamento de Ingenierı́a Quı́mica (FI), Universidad de Buenos Aires, Pabellón de Industrias, Ciudad Universitaria, Buenos Aires 1428, Argentina INCAPE, CONICET, Universidad Nacional del Litoral, Santiago del Estero 2654, Santa Fe 3000, Argentina
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Palabras clave: | Bioethanol steam reforming; Cu-Ni catalysts; Hydrogen production; Alumina; Atmospheric pressure; Catalysts; Copper alloys; Ethanol; Fuel cells; Thermal effects; Bioethanol steam reforming; Hydrogen fuels |
Año: | 2001
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Volumen: | 26
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Número: | 7
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Página de inicio: | 665
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Página de fin: | 668
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DOI: |
http://dx.doi.org/10.1016/S0360-3199(01)00002-7 |
Título revista: | International Journal of Hydrogen Energy
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Título revista abreviado: | Int J Hydrogen Energy
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ISSN: | 03603199
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v26_n7_p665_Marino |
Referencias:
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- García, E., Laborde, M., Hydrogen production by the steam reforming of ethanol: Thermodynamic analysis (1991) Int J Hydrogen Energy, 16 (5), pp. 307-312
- Vasudeva, K., Mitra, N., Umasankar, P., Dringa, S.C., Steam reforming of ethanol for hydrogen production. Thermodynamic analysis (1996) Int J Hydrogen Energy, 21 (1), pp. 13-18
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Citas:
---------- APA ----------
Mariño, F., Boveri, M., Baronetti, G. & Laborde, M.
(2001)
. Hydrogen production from steam reforming of bioethanol using Cu/Ni/K/γ-Al2O3 catalysts. Effect of Ni. International Journal of Hydrogen Energy, 26(7), 665-668.
http://dx.doi.org/10.1016/S0360-3199(01)00002-7---------- CHICAGO ----------
Mariño, F., Boveri, M., Baronetti, G., Laborde, M.
"Hydrogen production from steam reforming of bioethanol using Cu/Ni/K/γ-Al2O3 catalysts. Effect of Ni"
. International Journal of Hydrogen Energy 26, no. 7
(2001) : 665-668.
http://dx.doi.org/10.1016/S0360-3199(01)00002-7---------- MLA ----------
Mariño, F., Boveri, M., Baronetti, G., Laborde, M.
"Hydrogen production from steam reforming of bioethanol using Cu/Ni/K/γ-Al2O3 catalysts. Effect of Ni"
. International Journal of Hydrogen Energy, vol. 26, no. 7, 2001, pp. 665-668.
http://dx.doi.org/10.1016/S0360-3199(01)00002-7---------- VANCOUVER ----------
Mariño, F., Boveri, M., Baronetti, G., Laborde, M. Hydrogen production from steam reforming of bioethanol using Cu/Ni/K/γ-Al2O3 catalysts. Effect of Ni. Int J Hydrogen Energy. 2001;26(7):665-668.
http://dx.doi.org/10.1016/S0360-3199(01)00002-7