Artículo
Doctorovich, F.; Granara, M.; Di Salvo, F. "The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent" (2001) Transition Metal Chemistry. 26(4-5):505-509
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Abstract:
[Fe(CN)5NO]2-, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidation products are generated even in the absence of oxygen, a mechanism in which the nitrosyl ligand acts as an oxidant is proposed.
Registro:
| Documento: | Artículo |
| Título: | The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent |
| Autor: | Doctorovich, F.; Granara, M.; Di Salvo, F. |
| Filiación: | Departamento de Quimica Inorganica, Analitica y Quimica Fisica/INQUIMAE, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellón II, piso 3, C1428EHA, Buenos Aires, Argentina |
| Palabras clave: | Agents; Amines; Chemistry; Chromatography; Coordination reactions; Iron compounds; Oxidation; Ruthenium compounds; Benzylamine; Benzylphenylmethanimine; Nitrosyl; Oxidation products; Oxidizing agents; Chemical reactions |
| Año: | 2001 |
| Volumen: | 26 |
| Número: | 4-5 |
| Página de inicio: | 505 |
| Página de fin: | 509 |
| DOI: | http://dx.doi.org/10.1023/A:1011033312510 |
| Título revista: | Transition Metal Chemistry |
| Título revista abreviado: | Transition Met Chem |
| ISSN: | 03404285 |
| CODEN: | TMCHD |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03404285_v26_n4-5_p505_Doctorovich |
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Citas:
---------- APA ----------
Doctorovich, F., Granara, M. & Di Salvo, F. (2001) . The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent. Transition Metal Chemistry, 26(4-5), 505-509.http://dx.doi.org/10.1023/A:1011033312510
---------- CHICAGO ----------
Doctorovich, F., Granara, M., Di Salvo, F. "The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent" . Transition Metal Chemistry 26, no. 4-5 (2001) : 505-509.http://dx.doi.org/10.1023/A:1011033312510
---------- MLA ----------
Doctorovich, F., Granara, M., Di Salvo, F. "The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent" . Transition Metal Chemistry, vol. 26, no. 4-5, 2001, pp. 505-509.http://dx.doi.org/10.1023/A:1011033312510
---------- VANCOUVER ----------
Doctorovich, F., Granara, M., Di Salvo, F. The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent. Transition Met Chem. 2001;26(4-5):505-509.http://dx.doi.org/10.1023/A:1011033312510
