Abstract:
The reaction of 3β-acetoxy-5α-hydroxy-6β-sulfanylpregnan-20-one with HgO-I2-hv or phenyliodoso diacetate-I2-hv gave the corresponding sulfenyl iodide which was further cleaved by HgO-I2-hv to a 5,10-secopregnane with a sulfur bridge between C-6 and C-10.
Registro:
Documento: |
Artículo
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Título: | Photochemically-induced Oxidation of 6β-Sulfanylpregnanes |
Autor: | Monteserín, M.C.; Veleiro, A.S.; Burton, G. |
Filiación: | Depto. de Quim. Orgánica, Fac. de Ciencias Exactas y Naturales, Ciudad Universitaria, (1428) Buenos Aires, Argentina
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Año: | 1996
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Número: | 10
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Página de inicio: | 450
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Página de fin: | 451
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Título revista: | Journal of Chemical Research - Part S
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Título revista abreviado: | J. Chem. Res. Part S
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ISSN: | 03082342
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CODEN: | JRPSD
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03082342_v_n10_p450_Monteserin |
Referencias:
- Majetich, G., Wheless, K., (1995) Tetrahedron, 51, p. 7095
- Heckendorn, R., Fuhrer, H., Kalvoda, J., Lorenc, L., Pavlovic, V., Mihailovic, M., (1995) Helv. Chim. Acta, 78, p. 1291
- Arencibia, T., Salazar, J., Suárez, E., (1994) Tetrahedron Lett., 35, p. 7463
- Nicoletti, D., Ghini, A.A., Brachet-Cota, A.L., Burton, G., (1995) J. Chem. Soc., Perkin Trans. 1, p. 1089
- Brachet-Cota, A.L., Burton, G., (1988) Z. Naturforsch, Teil B, 43, p. 491
- Lightner, D.A., Djerassi, C., (1965) Tetrahedron, 21, p. 583
- Boigegrain, R.A., Gross, B., (1975) Carbohydr. Res., 41, p. 135
- Patai, S., (1974) The Chemistry of the Thiol Group, Part 2, p. 785. , Wiley, London
Citas:
---------- APA ----------
Monteserín, M.C., Veleiro, A.S. & Burton, G.
(1996)
. Photochemically-induced Oxidation of 6β-Sulfanylpregnanes. Journal of Chemical Research - Part S(10), 450-451.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03082342_v_n10_p450_Monteserin [ ]
---------- CHICAGO ----------
Monteserín, M.C., Veleiro, A.S., Burton, G.
"Photochemically-induced Oxidation of 6β-Sulfanylpregnanes"
. Journal of Chemical Research - Part S, no. 10
(1996) : 450-451.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03082342_v_n10_p450_Monteserin [ ]
---------- MLA ----------
Monteserín, M.C., Veleiro, A.S., Burton, G.
"Photochemically-induced Oxidation of 6β-Sulfanylpregnanes"
. Journal of Chemical Research - Part S, no. 10, 1996, pp. 450-451.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03082342_v_n10_p450_Monteserin [ ]
---------- VANCOUVER ----------
Monteserín, M.C., Veleiro, A.S., Burton, G. Photochemically-induced Oxidation of 6β-Sulfanylpregnanes. J. Chem. Res. Part S. 1996(10):450-451.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03082342_v_n10_p450_Monteserin [ ]