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Abstract:

Surface-enhanced resonance-Raman spectroelectrochemistry represents a powerful approach for studying the structure and reaction dynamics of redox proteins immobilized on biocompatible electrodes in fundamental and applied sciences. Using this approach it has been recently shown that electric fields of biologically relevant magnitude are able to influence crucial parameters for the functioning of a variety of soluble and membrane bound heme proteins. Electric field effects discussed in this tutorial review include modulation of redox potentials, reorganization energies, protein dynamics and redox-linked structural changes. © The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:Disentangling interfacial redox processes of proteins by SERR spectroscopy
Autor:Murgida, D.H.; Hildebrandt, P.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE-CONICET, Ciudad Universitaria, Pab. 2, piso 1, C1428EHA-Buenos Aires, Argentina
Technische Universität Berlin, Institut für Chemie, Straße des 17. Juni 135, D-10623 Berlin, Germany
Palabras clave:hemoprotein; immobilized enzyme; silver; article; chemistry; electrochemistry; electrode; oxidation reduction reaction; Raman spectrometry; Electrochemistry; Electrodes; Enzymes, Immobilized; Hemeproteins; Oxidation-Reduction; Silver; Spectrum Analysis, Raman
Año:2008
Volumen:37
Número:5
Página de inicio:937
Página de fin:945
DOI: http://dx.doi.org/10.1039/b705976k
Título revista:Chemical Society Reviews
Título revista abreviado:Chem. Soc. Rev.
ISSN:03060012
CODEN:CSRVB
CAS:silver, 7440-22-4; Enzymes, Immobilized; Hemeproteins; Silver, 7440-22-4
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03060012_v37_n5_p937_Murgida

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Citas:

---------- APA ----------
Murgida, D.H. & Hildebrandt, P. (2008) . Disentangling interfacial redox processes of proteins by SERR spectroscopy. Chemical Society Reviews, 37(5), 937-945.
http://dx.doi.org/10.1039/b705976k
---------- CHICAGO ----------
Murgida, D.H., Hildebrandt, P. "Disentangling interfacial redox processes of proteins by SERR spectroscopy" . Chemical Society Reviews 37, no. 5 (2008) : 937-945.
http://dx.doi.org/10.1039/b705976k
---------- MLA ----------
Murgida, D.H., Hildebrandt, P. "Disentangling interfacial redox processes of proteins by SERR spectroscopy" . Chemical Society Reviews, vol. 37, no. 5, 2008, pp. 937-945.
http://dx.doi.org/10.1039/b705976k
---------- VANCOUVER ----------
Murgida, D.H., Hildebrandt, P. Disentangling interfacial redox processes of proteins by SERR spectroscopy. Chem. Soc. Rev. 2008;37(5):937-945.
http://dx.doi.org/10.1039/b705976k