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Abstract:

Vinal-derived Activated Carbon (VAC) developed by phosphoric acid activation of sawdust from Prosopis ruscifolia native wood was tested for the adsorption of Ni(II) ions from dilute solutions in both batch and dynamic modes, comparing it with a Commercial Activated Carbon (CAC). Batch experiments were performed to determine adsorption kinetics and equilibrium isotherms for both carbons. It was possible to remove near 6.55mg Nig -1 VAC and 7.65mg Nig -1 CAC after 5h and 10h contact time, respectively. A pseudo second order equation fitted well with the kinetics of the process, and Langmuir adsorption model was used to adjust the experimental results concerning the adsorption isotherm. The parameters obtained indicate a stronger interaction between sorbent and sorbate for VAC (K=26.56Lmmol -1) than for CAC (K=19.54Lmmol -1). Continuous experiments were performed in a fixed-bed column packed with the investigated carbons, evaluating the influence of operational parameters such as flow rate, bed height and feed concentration on the breakthrough curves obtained. The breakthrough occurred more slowly for low concentrations of the metal ion in the feed, low flow rates and high bed height. The breakthrough curves were properly represented by Hall's model for both carbon types. Regeneration of the vinal activated carbon in column was tested, obtaining the same breakthrough curve in a new cycle of use. Finally, vinal-derived activated carbon can effectively be used to treat wastewater having until 30ppm Ni(II). © 2011 Elsevier Ltd.

Registro:

Documento: Artículo
Título:Batch and dynamic sorption of Ni(II) ions by activated carbon based on a native lignocellulosic precursor
Autor:Nabarlatz, D.; de Celis, J.; Bonelli, P.; Cukierman, A.L.
Filiación:Programa de Investigacion y Desarrollo de Fuentes Alternativas de Materias Primas y Energia PINMATE, Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2620, Ciudad Universitaria, (C1428BGA) Buenos Aires, Argentina
Cátedra Farmacotecnia II-Tecnología Especial, Departamento de Tecnología Farmacéutica, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Junín 956, (C1113AAD) Buenos Aires, Argentina
Departament d'Enginyeria Química, ETSEQ, Universitat Rovira i Virgili, Av. Països Catalans 26, E43007 Tarragona, Catalonia, Spain
Escuela de Ingeniería Química, Universidad Industrial de Santander, Carrera 27 # 9, AA 678 Bucaramanga, Colombia
Palabras clave:Breakthrough; Native wood-derived activated carbon; Nickel adsorption; Regeneration; activated carbon; lignocellulose; nickel; activated carbon; adsorption; cellulose; concentration (composition); inorganic acid; ion; isotherm; legume; lignin; nickel; numerical model; reaction kinetics; regeneration; adsorption kinetics; article; flow rate; isotherm; waste water management; Adsorption; Carbon; Environmental Remediation; Kinetics; Nickel; Prosopis; Water Purification; Prosopis ruscifolia
Año:2012
Volumen:97
Número:1
Página de inicio:109
Página de fin:115
DOI: http://dx.doi.org/10.1016/j.jenvman.2011.11.008
Título revista:Journal of Environmental Management
Título revista abreviado:J. Environ. Manage.
ISSN:03014797
CODEN:JEVMA
CAS:activated carbon, 64365-11-3, 82228-96-4; lignocellulose, 11132-73-3; nickel, 7440-02-0; Carbon, 7440-44-0; Nickel, 7440-02-0
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03014797_v97_n1_p109_Nabarlatz

Referencias:

  • Ahluwalia, S., Goyal, D., Microbial and plant derived biomass for removal of heavy metals from wastewater (2007) Biores. Technol., 98, pp. 2243-2257
  • Ahmedna, M., Johns, M.M., Clarke, S.J., Marshall, W.E., Rao, R.M., Potential of agricultural by-product-based activated carbons for use in raw sugar decolourisation (1997) J.Sci. Food Agric., 75, pp. 117-124
  • Basso, M.C., Cukierman, A.L., Arundo donax-based activated carbons for aqueous-phase adsorption of volatile organic compounds (2005) Ind. Eng. Chem. Res., 44, pp. 2091-2100
  • Basso, M.C., Cerrella, E.G., Cukierman, A.L., Activated carbons developed from a rapidly renewable biosource for removal of cadmium (II) and nickel (II) ions from dilute aqueous solutions (2002) Ind. Eng. Chem. Res., 41, pp. 180-189
  • Basso, M.C., Cerrella, E.G., Cukierman, A.L., Lignocellulosic materials as potential biosorbents of trace toxic metals from wastewater (2002) Ind. Eng. Chem. Res., 41, pp. 3580-3585
  • Betancur, M., Bonelli, P.R., Velázquez, J.A., Cukierman, A.L., Potentiality of lignin from the Kraft pulping process for removal of trace nickel from wastewater: effect of demineralisation (2009) Biores. Technol., 100, pp. 1130-1137
  • Blanco Castro, J., Bonelli, P.R., Cerrella, E.G., Cukierman, A.L., Phosphoric acid activation of agricultural residues and bagasse from sugar cane: influence of the experimental conditions on adsorption characteristics of activated carbons (2000) Ind. Eng. Chem. Res., 39, pp. 4166-4172
  • Borba, C.E., Guirardello, R., Silva, E.A., Veit, M.T., Tavares, C.R.G., Removal of nickel (II) ions from aqueous solution by biosorption in a fixed bed column: experimental and theoretical breakthrough curves (2006) Biochem. Eng. J., 30, pp. 184-191
  • Carrott, P.J.M., Ribeiro Carrott, M.M.L., Mourao, P.A.M., Pore size control in activated carbons obtained by pyrolysis under different conditions of chemically impregnated cork (2006) J.Anal. Appl. Pyrol, 75, pp. 120-127
  • Chen, J., Wang, X., Removing copper, zinc and lead ion by granular activated carbon in pretreated fixed-bed columns (2000) Sep. Purif. Technol., 19, pp. 157-167
  • Cooney, D., (1998) Adsorption Design for Wastewater Treatment, , Lewis Publishers
  • de Celis, J.P., Villaverde, M.S., Basso, M.C., Cukierman, A.L., Amadeo, N.E., Obtención de estireno por deshidrogenación oxidativa de etilbenceno utilizando como catalizador carbón activado desarrollado a partir de aserrín de vinal (2003) XIII Congreso Argentino de Catálisis (JAC 2003) - 2° Congreso MERCOSUR de Catálisis (2° MERCOCAT), , Villa Giardino, Córdoba, Argentina
  • de Celis, J.P., Amadeo, N.E., Cukierman, A.L., In situ modification of activated carbons developed from a native invasive wood on removal of trace toxic metals from wastewater (2009) J.Hazard. Mater., 161, pp. 217-223
  • Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L., Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes (2010) Biores. Technol., 101, pp. 9500-9507
  • Fierro, V., Torné-Fernández, V., Celzard, A., Kraft lignin as a precursor for microporous activated carbons prepared by impregnation with ortho-phosphoric acid: synthesis and textural characterisation (2006) Micropor. Mesopor. Mater., 92, pp. 243-250
  • Hall, K., Eagleton, L., Acrivos, A., Vermeulen, T., Pore- and solid-diffusion kinetics in fixed-bed adsorption under constant-pattern conditions (1966) Ind. Eng. Chem. Fund., 5, pp. 212-223
  • Ho, Y., Review of second-order models for adsorption systems (2006) J.Hazard. Mater., B136, pp. 681-689
  • Klijanienko, A., Lorenc-Grabowska, E., Gryglewicz, G., Development of mesoporosity during phosphoric acid activation of wood in steam atmosphere (2008) Biores. Technol., 99, pp. 7208-7214
  • Kratochvil, D., Volesky, B., Advances in the biosorption of heavy metals (1998) Trends Biotechnol., 16, pp. 291-300
  • Lata, H., Garg, V.K., Gupta, R.K., Sequestration of nickel from aqueous solution onto activated carbon prepared from Parthenium hysterophorus L (2008) J.Hazard. Mat, 157, pp. 503-509
  • Liang, S., Guo, X.Y., Feng, N.C., Tian, Q.H., Effective removal of heavy metals from aqueous solutions by orange peel xanthate (2010) Trans. Nonferrous Met. Soc. China, 20, pp. 187-191
  • Nabais, J.V., Carrott, P., Ribeiro Carrott, M.M.L., Luz, V., Ortiz, A.L., Influence of preparation conditions in the textural and chemical properties of activated carbons from a novel biomass precursor: the coffee endocarp (2008) Biores. Technol., 99, pp. 7224-7231
  • Patnukao, P., Pavasant, P., Activated carbon from Eucalyptus camaldulensis Dehn bark using phosphoric acid activation (2008) Biores. Technol., 99, pp. 8540-8543
  • Rangel-Mendez, J.R., Streat, M., Adsorption of cadmium by activated carbon cloth: influence of surface oxidation and solution pH (2002) Water Res., 36, pp. 1244-1252
  • Rosas, J.M., Bedia, J., Rodríguez-Mirasol, J., Cordero, T., Preparation of hemp-derived activated carbon monoliths. Adsorption of water vapor (2008) Ind. Eng. Chem. Res., 47, pp. 1288-1296
  • Sharma, Y.C., Srivastava, V., Upadhyay, S.N., Weng, C.H., Alumina Nanoparticles for Removal Ni(II) Aqueous Solutions (2008) Ind. Eng. Chem. Res., 47, pp. 8095-8100
  • Singh, C.K., Sahu, J.N., Mahalik, K.K., Mohanty, C.R., Raj Mohan, B., Meikap, B.C., Studies on the removal of Pb(II) from wastewater by activated carbon developed from Tamarind wood activated with sulphuric acid (2008) J.Hazard. Mat, 153, pp. 221-228
  • Sousa, F., Oliveira, A., Ribeiro, J., Rosa, M., Keukeleire, D., Nascimento, R.F., Green coconut shells applied as adsorbent for removal of toxic metal ions using fixed-bed column technology (2010) J.Environ. Manage., 91, pp. 1634-1640
  • Vernersson, T., Bonelli, P.R., Cerrella, E.G., Cukierman, A.L., Arundo donax cane as a precursor for activated carbons preparation by phosphoric acid activation (2002) Biores. Technol., 83, pp. 95-104
  • Zein, R., Suhaili, R., Earnestly, F., Indrawati Munaf, E., Removal of Pb(II), Cd(II) and Co(II) from aqueous solution using Garcinia mangostana L. fruit shell (2010) J.Hazard. Mater., 181, pp. 52-56

Citas:

---------- APA ----------
Nabarlatz, D., de Celis, J., Bonelli, P. & Cukierman, A.L. (2012) . Batch and dynamic sorption of Ni(II) ions by activated carbon based on a native lignocellulosic precursor. Journal of Environmental Management, 97(1), 109-115.
http://dx.doi.org/10.1016/j.jenvman.2011.11.008
---------- CHICAGO ----------
Nabarlatz, D., de Celis, J., Bonelli, P., Cukierman, A.L. "Batch and dynamic sorption of Ni(II) ions by activated carbon based on a native lignocellulosic precursor" . Journal of Environmental Management 97, no. 1 (2012) : 109-115.
http://dx.doi.org/10.1016/j.jenvman.2011.11.008
---------- MLA ----------
Nabarlatz, D., de Celis, J., Bonelli, P., Cukierman, A.L. "Batch and dynamic sorption of Ni(II) ions by activated carbon based on a native lignocellulosic precursor" . Journal of Environmental Management, vol. 97, no. 1, 2012, pp. 109-115.
http://dx.doi.org/10.1016/j.jenvman.2011.11.008
---------- VANCOUVER ----------
Nabarlatz, D., de Celis, J., Bonelli, P., Cukierman, A.L. Batch and dynamic sorption of Ni(II) ions by activated carbon based on a native lignocellulosic precursor. J. Environ. Manage. 2012;97(1):109-115.
http://dx.doi.org/10.1016/j.jenvman.2011.11.008