A new variational principle is described which leads to an expression for the microscopic salt velocity in a binary electrolyte solution which is identical with that introduced earlier, and shows this velocity to be that which which makes the dissipation function a minimum for a fixed thermodynamic state of the binary system.
| Documento: | Artículo |
| Título: | The microscopic velocity of a salt in an electrolyte solution. An alternative characterization by a new variational principle |
| Autor: | Raineri, F.O.; Timmermann, E.O. |
| Filiación: | Departmento de Quimíca Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, (1428) Buenos Aires, Argentina |
| Año: | 1988 |
| Volumen: | 84 |
| Número: | 4 |
| Página de inicio: | 423 |
| Página de fin: | 426 |
| DOI: | http://dx.doi.org/10.1039/F29888400423 |
| Título revista: | Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics |
| ISSN: | 03009238 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03009238_v84_n4_p423_Raineri |
