A new variational principle is described which leads to an expression for the microscopic salt velocity in a binary electrolyte solution which is identical with that introduced earlier, and shows this velocity to be that which which makes the dissipation function a minimum for a fixed thermodynamic state of the binary system.
Documento: | Artículo |
Título: | The microscopic velocity of a salt in an electrolyte solution. An alternative characterization by a new variational principle |
Autor: | Raineri, F.O.; Timmermann, E.O. |
Filiación: | Departmento de Quimíca Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, (1428) Buenos Aires, Argentina |
Año: | 1988 |
Volumen: | 84 |
Número: | 4 |
Página de inicio: | 423 |
Página de fin: | 426 |
DOI: | http://dx.doi.org/10.1039/F29888400423 |
Título revista: | Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics |
ISSN: | 03009238 |
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03009238_v84_n4_p423_Raineri |