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Abstract:

Hydrazine is oxidized by dissolved oxygen in aqueous solutions containing [Fe(CN)5]3-, in slightly acidic or alkaline conditions. The reaction involves the oxidation of [FeII(CN)5(N2H4)]3- to [FeIII(CN)5(N2H4)]2- as the first step, and kinetic features suggest that this is followed by dimerization to [(NC)5FeIII(N2H4)FeII(CN)5]5-; FeIIIFeIll and FeIIFeII dimers are then originated by fast electron-transfer. The first of these evolves to [(NC)5FeII(N2H2 FeII(CN)5]6-; this diimide complex shows a strong MLCT band at 515 nm and is very stable in alkaline solutions (pH 8) free of O2 or H2O2. In the presence of these, or in more acidic media it evolves further to [Fe(CN)5(H2O)]3-+N2. © 1989.

Registro:

Documento: Artículo
Título:Hydrazine autoxidation in solution: catalysis by pentacyanoferrate(II)
Autor:Funai, I.A.; Blesa, M.A.; Olabe, J.A.
Filiación:Departamento Quimica de Reactores, Comisión Nacional de Energía Atómica, Avenida del Libertador 8250, 1429 Buenos Aires, Argentina
Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universided de Buenos Aires, Argentina
Año:1989
Volumen:8
Número:4
Página de inicio:419
Página de fin:426
DOI: http://dx.doi.org/10.1016/S0277-5387(00)80736-6
Título revista:Polyhedron
Título revista abreviado:Polyhedron
ISSN:02775387
CODEN:PLYHD
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02775387_v8_n4_p419_Funai

Referencias:

  • Bottomley, The reactions of hydrazine with transition-metal complexes (1970) Quarterly Reviews, Chemical Society, p. 617
  • Audrieth, Ogg, (1951) The Chemistry of Hydrazine, , John Wiley, New York
  • Olabe, Gentil, (1983) Transition Metal Chem., 8, p. 65
  • Williams, (1986) PhD Thesis, , University of La Plata
  • Ferreira, Toma, Electron-transfer kinetics and mechanism of di-imine bond formation in tetracyano(ethylenediamine)ferrate(II) (1983) Journal of the Chemical Society, Dalton Transactions, p. 2051
  • Goto, Takeshita, Kauda, Sakai, Goedken, (1985) Inorg. Chem., 24, p. 582. , and refs therein
  • Katz, Olabe, Aymonino, (1977) J. Inorg. Nucl. Chem., 39, p. 908
  • James, Murray, Higginson, Iron(II) catalysis in substitution reactions of amminepentacyano- and aquopentacyano-ferrate(III) ions (1974) Journal of the Chemical Society, Dalton Transactions, p. 1273
  • Vogel, (1977) Química Analitica Cuantitativa, 1. , Kapeluz, Buenos Aires
  • Chadwick, Sharpe, (1976) The Chemistry of Cyano Complexes of the Transition Metals, , Academic Press, New York
  • Olabe, Zerga, (1983) Inorg. Chem., 22, p. 4156
  • Toma, (1975) Inorg. Chim. Acta, 15, p. 205
  • Glauser, Hauser, Herreu, Ludi, Roder, Schmidt, Siegenthaler, Wenk, (1973) J. Am. Chem. Soc., 95, p. 8457
  • Gale, McCaffery, Bonding studies from charge-transfer absorption and magnetic circular dichroism spectra. Part II. The complex hexacyanoferrate(III) and pentacyanoferrate(III) complexes of C4v , symmetry (1973) Journal of the Chemical Society, Dalton Transactions, p. 1344
  • Gutterman, Gray, (1972) Inorg. Chem., 11, p. 1727
  • Itano, Robinson, (1961) J. Am. Chem. Soc., 83, p. 3339
  • Goedken, Oxidative dehydrogenation of diamine ligands co-ordinated to low-spin iron(II) (1972) Journal of the Chemical Society, Chemical Communications, p. 207
  • Bottomley, Some reactions of hydrazine with ruthenium compounds (1970) Canadian Journal of Chemistry, 48, p. 351
  • Nibler, Bondybey, (1974) J. Chem. Phys., 60, p. 1307
  • Petredis, Burke, Balch, (1970) J. Am. Chem. Soc., 92, p. 428
  • F. Cukiernik and J.A. Olabe, work in progress; Emschwiller, (1964) CR Acad. Sci. (France), 259, p. 4281
  • Bowers, Kovacs, Shepherd, (1977) J. Am. Chem. Soc., 99, p. 6555
  • Stanbury, Haas, Taube, (1980) Inorg. Chem., 19, p. 518
  • Bradic, Pribanic, Asperger, Kinetics and mechanism of replacements in pentacyano(ligand)ferrate(II) ions (1975) Journal of the Chemical Society, Dalton Transactions, p. 353
  • James, Murray, Kinetics of formation and bridge cleavage of binuclear complexes derived from the pentacyanoferrate(II and III) ions in aqueous solution (1977) Journal of the Chemical Society, Dalton Transactions, p. 326
  • Felix, Ludi, (1978) Inorg. Chem., 17, p. 1782

Citas:

---------- APA ----------
Funai, I.A., Blesa, M.A. & Olabe, J.A. (1989) . Hydrazine autoxidation in solution: catalysis by pentacyanoferrate(II). Polyhedron, 8(4), 419-426.
http://dx.doi.org/10.1016/S0277-5387(00)80736-6
---------- CHICAGO ----------
Funai, I.A., Blesa, M.A., Olabe, J.A. "Hydrazine autoxidation in solution: catalysis by pentacyanoferrate(II)" . Polyhedron 8, no. 4 (1989) : 419-426.
http://dx.doi.org/10.1016/S0277-5387(00)80736-6
---------- MLA ----------
Funai, I.A., Blesa, M.A., Olabe, J.A. "Hydrazine autoxidation in solution: catalysis by pentacyanoferrate(II)" . Polyhedron, vol. 8, no. 4, 1989, pp. 419-426.
http://dx.doi.org/10.1016/S0277-5387(00)80736-6
---------- VANCOUVER ----------
Funai, I.A., Blesa, M.A., Olabe, J.A. Hydrazine autoxidation in solution: catalysis by pentacyanoferrate(II). Polyhedron. 1989;8(4):419-426.
http://dx.doi.org/10.1016/S0277-5387(00)80736-6