Abstract:
[MmFe(CN)5L·xH2O] (M = Mn, Fe, Co, Ni, Cu; L = pyridine or pyrazine derivative) have been synthesized, and their UV-vis and IR spectral characteristics are reported. Thermolysis of the solids leads to water release, ligand release and/or decomposition, redox interaction between Fe3+ (or Cu2+) with CN- or L, and redox interaction between M2+ (or Cu+) and CN-, yielding elemental metal and metal carbides. © 1987.
Registro:
Documento: |
Artículo
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Título: | Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes |
Autor: | Sileo, E.E.; García Posse, M.G.; Morando, P.J.; Blesa, M.A.; Herrera, H.A.; Della Vedova, C.O.; Esteban, A. |
Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires; Ciudad Universitaria, Pabellón II, 1428 Buenos Aires, República Argentina; and Departamento Química de Reactores, Comisión Nacional de Energía Atómica Laboratorio de Fisicoquímica, Facultad de Agronomía y Agroindustria, Universidad Nacional de Santiago del Estero, Av. Bellgrano 1912, (4200) Santiago Del Estero, Argentina Programa QUINOR, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, Calle 47 y 115 ;, 1900 La Plata, Argentina Departamento Combustibles Nucleares, Comisión Nacional de Energía Atómica, Centro Atomico Constituyentes, Av. Constituyentes y General Paz, 1650 Buenos Aires, Argentina
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Año: | 1987
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Volumen: | 6
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Número: | 9
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Página de inicio: | 1757
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Página de fin: | 1763
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DOI: |
http://dx.doi.org/10.1016/S0277-5387(00)86547-X |
Título revista: | Polyhedron
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Título revista abreviado: | Polyhedron
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ISSN: | 02775387
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CODEN: | PLYHD
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02775387_v6_n9_p1757_Sileo |
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Citas:
---------- APA ----------
Sileo, E.E., García Posse, M.G., Morando, P.J., Blesa, M.A., Herrera, H.A., Della Vedova, C.O. & Esteban, A.
(1987)
. Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes. Polyhedron, 6(9), 1757-1763.
http://dx.doi.org/10.1016/S0277-5387(00)86547-X---------- CHICAGO ----------
Sileo, E.E., García Posse, M.G., Morando, P.J., Blesa, M.A., Herrera, H.A., Della Vedova, C.O., et al.
"Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes"
. Polyhedron 6, no. 9
(1987) : 1757-1763.
http://dx.doi.org/10.1016/S0277-5387(00)86547-X---------- MLA ----------
Sileo, E.E., García Posse, M.G., Morando, P.J., Blesa, M.A., Herrera, H.A., Della Vedova, C.O., et al.
"Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes"
. Polyhedron, vol. 6, no. 9, 1987, pp. 1757-1763.
http://dx.doi.org/10.1016/S0277-5387(00)86547-X---------- VANCOUVER ----------
Sileo, E.E., García Posse, M.G., Morando, P.J., Blesa, M.A., Herrera, H.A., Della Vedova, C.O., et al. Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes. Polyhedron. 1987;6(9):1757-1763.
http://dx.doi.org/10.1016/S0277-5387(00)86547-X