Navegar

Colección

Datos Estadísticas

Artículo

Sileo, E.E.; García Posse, M.G.; Morando, P.J.; Blesa, M.A.; Herrera, H.A.; Della Vedova, C.O.; Esteban, A. "Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes" (1987) Polyhedron. 6(9):1757-1763
Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

[MmFe(CN)5L·xH2O] (M = Mn, Fe, Co, Ni, Cu; L = pyridine or pyrazine derivative) have been synthesized, and their UV-vis and IR spectral characteristics are reported. Thermolysis of the solids leads to water release, ligand release and/or decomposition, redox interaction between Fe3+ (or Cu2+) with CN- or L, and redox interaction between M2+ (or Cu+) and CN-, yielding elemental metal and metal carbides. © 1987.

Registro:

Documento: Artículo
Título:Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes
Autor:Sileo, E.E.; García Posse, M.G.; Morando, P.J.; Blesa, M.A.; Herrera, H.A.; Della Vedova, C.O.; Esteban, A.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires; Ciudad Universitaria, Pabellón II, 1428 Buenos Aires, República Argentina; and Departamento Química de Reactores, Comisión Nacional de Energía Atómica
Laboratorio de Fisicoquímica, Facultad de Agronomía y Agroindustria, Universidad Nacional de Santiago del Estero, Av. Bellgrano 1912, (4200) Santiago Del Estero, Argentina
Programa QUINOR, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, Calle 47 y 115 ;, 1900 La Plata, Argentina
Departamento Combustibles Nucleares, Comisión Nacional de Energía Atómica, Centro Atomico Constituyentes, Av. Constituyentes y General Paz, 1650 Buenos Aires, Argentina
Año:1987
Volumen:6
Número:9
Página de inicio:1757
Página de fin:1763
DOI: http://dx.doi.org/10.1016/S0277-5387(00)86547-X
Título revista:Polyhedron
Título revista abreviado:Polyhedron
ISSN:02775387
CODEN:PLYHD
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02775387_v6_n9_p1757_Sileo

Referencias:

  • Robin, The Color and Electronic Configurations of Prussian Blue (1962) Inorganic Chemistry, 1, p. 337
  • Sharpe, (1976) The Chemistry of Cyano Complexes of the Transition Metals., , Academic Press, New York
  • Day, Theory and Experiments on Valence Delocalization in Mixed-Valence Compounds (1981) Comments on Inorganic Chemistry, 1, p. 55
  • Glauser, Hanser, Herren, Ludi, Schmidt, Siegenthaler, Wenk, (1973) J. Am. Chem. Soc., 95, p. 8457
  • Ludi, Güdel, Structural chemistry of polynuclear transition metal cyanides (1973) Struct. Bonding (Berlin), 14, p. 1
  • Toma, Oliveira, (1979) Inorg. Chim. Acta, 33, p. L143
  • Ben Altabef, Brandan, Katz, (1985) Polyhedron, 4, p. 227
  • Shriver, Shriver, Anderson, (1965) Inorg. Chem., 4, p. 725
  • Shriver, Basset Brown, (1969) Inorg. Chem., 8, p. 42
  • Basset Brown, Shriver, Structures and solid-state reactions of Prussian blue analogs containing chromium, manganese, iron, and cobalt (1969) Inorganic Chemistry, 8, p. 37
  • G. S. B. Megni, S. A. Brandán, A. Ben Altabef and N. E. Katz, Monatsch Chem., in press; Rasmussen, Meyers, (1984) Polyhedron, 3, p. 183
  • Chamberlain, Greene, Jr., (1963) J. Inorg. Nucl. Chem., 25, p. 1471. , and references therein
  • Seifer, (1960) Zh. Neorg. Khim., 5, p. 68
  • Seifer, (1962) Zh. Neorg. Khim., 7, p. 482
  • Kunrath, Müller, Frank, (1978) J. Therm. Anal., 14, p. 253
  • Frank, Kunrath, Müller, (1981) An. Quim., 77, p. 307
  • Gentil, Olabe, Baran, Aymonino, (1975) J. Therm. Anal., 7, p. 279
  • Morando, (1981) Ph.D. Thesis, , Universidad Nacional de La Plata, Argentina
  • Morando, Bruyére, Blesa, Olabe, (1983) Trans. Met. Chem., 8, p. 99
  • Toma, Malin, (1973) Inorg. Chem., 12, p. 1039
  • Morando, Blesa, Aquation of Fe?N bonds in pentacyano(ligand)ferrate(2?) ions: electronic and medium effects (1982) Journal of the Chemical Society, Dalton Transactions, p. 2147
  • Figgis, (1967) Introduction to Ligand Fields, p. 239. , Interscience Publishers, New York, Chapter 9
  • Lever, (1984) Inorganic Electronic Spectroscopy, , 2nd edn., Elsevier, Amsterdam
  • Emschwiller, (1954) Compt. Rend., 238, p. 1414
  • Dows, Haim, Wilmarth, (1961) J. Inorg. Nucl. Chem., 21, p. 33
  • Fluck, Inoue, Nagao, Yanagisawa, (1979) J. Inorg. Nucl. Chem., 41, p. 287
  • Ghosh, (1974) J. Inorg. Nucl. Chem., 36, p. 2465
  • Paris, Thomas, Merrin, (1961) Mem. Soc. Chim. France, 5, p. 707
  • Nagano, Kinoshita, Hirakawa, (1964) Chem. Pharm. Bull., 12, p. 1198
  • Morando, Bruyére, Blesa, Esteban, (1983) Therm. Act., 62, p. 249
  • Nakamoto, (1963) Infrared Spectra of Inorganic and Coordination Compounds., , J. Willys, New York
  • Brown, Dollimore, Galwey, (1982) Comprehensive Chemical Kinetics, 22, p. 228. , Ch. Bamford, C.F.H. Tipper, Elsevier, Amsterdam, Chapter 4

Citas:

---------- APA ----------
Sileo, E.E., García Posse, M.G., Morando, P.J., Blesa, M.A., Herrera, H.A., Della Vedova, C.O. & Esteban, A. (1987) . Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes. Polyhedron, 6(9), 1757-1763.
http://dx.doi.org/10.1016/S0277-5387(00)86547-X
---------- CHICAGO ----------
Sileo, E.E., García Posse, M.G., Morando, P.J., Blesa, M.A., Herrera, H.A., Della Vedova, C.O., et al. "Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes" . Polyhedron 6, no. 9 (1987) : 1757-1763.
http://dx.doi.org/10.1016/S0277-5387(00)86547-X
---------- MLA ----------
Sileo, E.E., García Posse, M.G., Morando, P.J., Blesa, M.A., Herrera, H.A., Della Vedova, C.O., et al. "Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes" . Polyhedron, vol. 6, no. 9, 1987, pp. 1757-1763.
http://dx.doi.org/10.1016/S0277-5387(00)86547-X
---------- VANCOUVER ----------
Sileo, E.E., García Posse, M.G., Morando, P.J., Blesa, M.A., Herrera, H.A., Della Vedova, C.O., et al. Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes. Polyhedron. 1987;6(9):1757-1763.
http://dx.doi.org/10.1016/S0277-5387(00)86547-X