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Abstract:

Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCL4(CH3CN)(syn-I-chloro- 2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reaction between NOCl and alkenes is well-known, there are very few examples of clean electrophilic addition of coordinated NO+ to alkenes. © 2006 American Chemical Society.

Registro:

Documento: Artículo
Título:Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
Autor:Escola, N.; Llebaría, A.; Leitus, G.; Doctorovich, F.
Filiación:Departamento de Quimica Inorganica, Analitica y Quimica Fisica/INQUIMAE-CONICET, Facultad de Ciencias Exactas y Naturales, Pabellón II, piso 3, C1428EHA Buenos Aires, Argentina
Department of Chemical Services, Weizmann Institute of Science, Rehovot 76100, Israel
Palabras clave:Chemical reactions; Crystal structure; Olefins; X ray diffraction; C-nitrosochloroalkanes; Cyclooctene; Electrophilic; NOCl; Potassium compounds
Año:2006
Volumen:25
Número:16
Página de inicio:3799
Página de fin:3801
DOI: http://dx.doi.org/10.1021/om060141v
Título revista:Organometallics
Título revista abreviado:Organometallics
ISSN:02767333
CODEN:ORGND
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02767333_v25_n16_p3799_Escola

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Citas:

---------- APA ----------
Escola, N., Llebaría, A., Leitus, G. & Doctorovich, F. (2006) . Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes. Organometallics, 25(16), 3799-3801.
http://dx.doi.org/10.1021/om060141v
---------- CHICAGO ----------
Escola, N., Llebaría, A., Leitus, G., Doctorovich, F. "Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes" . Organometallics 25, no. 16 (2006) : 3799-3801.
http://dx.doi.org/10.1021/om060141v
---------- MLA ----------
Escola, N., Llebaría, A., Leitus, G., Doctorovich, F. "Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes" . Organometallics, vol. 25, no. 16, 2006, pp. 3799-3801.
http://dx.doi.org/10.1021/om060141v
---------- VANCOUVER ----------
Escola, N., Llebaría, A., Leitus, G., Doctorovich, F. Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes. Organometallics. 2006;25(16):3799-3801.
http://dx.doi.org/10.1021/om060141v