Abstract:
In the present work we describe the formation of primary aromatic and aliphatic coordinated nitrosamines by reaction of the extremely reactive K[IrCl5- NO] with p-toluidine and 2,2,2-trifluoroethylamine, respectively. After the counteranion of the product was changed to tetraphenylphosphonium, crystal structures could be determined by X-ray diffraction. Complexes containing the highly unstable primary nitrosamines as ligands are generally scarce; moreover, to our knowledge this is the first example of isolated primary nitrosamines coordinated to a metal center through the NO moiety. © 2005 American Chemical Society.
Registro:
Documento: |
Artículo
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Título: | Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines |
Autor: | Doctorovich, F.; Di Salvo, F.; Escola, N.; Trápani, C.; Shimon, L. |
Filiación: | Depto. de Química Inorgánica, Analítica y Química Física, INQUIMAE-CONICET, Ciudad Universitaria, Pabellón II, piso 3, C1428EHA Buenos Aires, Argentina Department of Chemical Services, Weizmann Institute of Science, Rehovot 76100, Israel
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Palabras clave: | Complexation; Coordination reactions; Crystal structure; Organometallics; Potassium compounds; X ray diffraction analysis; Coordinated nitrosamines; Ligands; Metal center; P-toluidine; Nitrosamines |
Año: | 2005
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Volumen: | 24
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Número: | 20
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Página de inicio: | 4707
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Página de fin: | 4709
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DOI: |
http://dx.doi.org/10.1021/om050457n |
Título revista: | Organometallics
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Título revista abreviado: | Organometallics
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ISSN: | 02767333
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CODEN: | ORGND
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02767333_v24_n20_p4707_Doctorovich |
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- note
Citas:
---------- APA ----------
Doctorovich, F., Di Salvo, F., Escola, N., Trápani, C. & Shimon, L.
(2005)
. Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines. Organometallics, 24(20), 4707-4709.
http://dx.doi.org/10.1021/om050457n---------- CHICAGO ----------
Doctorovich, F., Di Salvo, F., Escola, N., Trápani, C., Shimon, L.
"Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines"
. Organometallics 24, no. 20
(2005) : 4707-4709.
http://dx.doi.org/10.1021/om050457n---------- MLA ----------
Doctorovich, F., Di Salvo, F., Escola, N., Trápani, C., Shimon, L.
"Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines"
. Organometallics, vol. 24, no. 20, 2005, pp. 4707-4709.
http://dx.doi.org/10.1021/om050457n---------- VANCOUVER ----------
Doctorovich, F., Di Salvo, F., Escola, N., Trápani, C., Shimon, L. Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines. Organometallics. 2005;24(20):4707-4709.
http://dx.doi.org/10.1021/om050457n