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Abstract:

In the present work we describe the formation of primary aromatic and aliphatic coordinated nitrosamines by reaction of the extremely reactive K[IrCl5- NO] with p-toluidine and 2,2,2-trifluoroethylamine, respectively. After the counteranion of the product was changed to tetraphenylphosphonium, crystal structures could be determined by X-ray diffraction. Complexes containing the highly unstable primary nitrosamines as ligands are generally scarce; moreover, to our knowledge this is the first example of isolated primary nitrosamines coordinated to a metal center through the NO moiety. © 2005 American Chemical Society.

Registro:

Documento: Artículo
Título:Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines
Autor:Doctorovich, F.; Di Salvo, F.; Escola, N.; Trápani, C.; Shimon, L.
Filiación:Depto. de Química Inorgánica, Analítica y Química Física, INQUIMAE-CONICET, Ciudad Universitaria, Pabellón II, piso 3, C1428EHA Buenos Aires, Argentina
Department of Chemical Services, Weizmann Institute of Science, Rehovot 76100, Israel
Palabras clave:Complexation; Coordination reactions; Crystal structure; Organometallics; Potassium compounds; X ray diffraction analysis; Coordinated nitrosamines; Ligands; Metal center; P-toluidine; Nitrosamines
Año:2005
Volumen:24
Número:20
Página de inicio:4707
Página de fin:4709
DOI: http://dx.doi.org/10.1021/om050457n
Título revista:Organometallics
Título revista abreviado:Organometallics
ISSN:02767333
CODEN:ORGND
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02767333_v24_n20_p4707_Doctorovich

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  • note

Citas:

---------- APA ----------
Doctorovich, F., Di Salvo, F., Escola, N., Trápani, C. & Shimon, L. (2005) . Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines. Organometallics, 24(20), 4707-4709.
http://dx.doi.org/10.1021/om050457n
---------- CHICAGO ----------
Doctorovich, F., Di Salvo, F., Escola, N., Trápani, C., Shimon, L. "Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines" . Organometallics 24, no. 20 (2005) : 4707-4709.
http://dx.doi.org/10.1021/om050457n
---------- MLA ----------
Doctorovich, F., Di Salvo, F., Escola, N., Trápani, C., Shimon, L. "Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines" . Organometallics, vol. 24, no. 20, 2005, pp. 4707-4709.
http://dx.doi.org/10.1021/om050457n
---------- VANCOUVER ----------
Doctorovich, F., Di Salvo, F., Escola, N., Trápani, C., Shimon, L. Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines. Organometallics. 2005;24(20):4707-4709.
http://dx.doi.org/10.1021/om050457n