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Abstract:

In the present work, Iridaea cordata (IC), a red marine macroalgae, was used as an efficient biosorbent for the removal of crystal violet (CV) and methylene blue (MB) dyes from aqueous solutions. The effects of pH (5, 7, and 9) and IC concentration (1, 3, and 5 g L-1) on the biosorption were studied through a 32 full factorial design. Under the optimal conditions (pH: 7, biosorbent concentration: 1 g L-1), biosorption kinetic studies were developed and the obtained experimental data were evaluated by pseudo-first order and pseudo-second order models. The results showed that the pseudo-second order model was in agreement with the experimental kinetic data for both dyes. Equilibrium studies were also carried out, and results exhibited good concordance with the Brunauer-Emmett-Teller isotherm. The biosorption capacities were 36.5 and 45.0 mg g-1 for CV and MB dyes, respectively. The dye removal percentages were around 75% for CV and 90% for MB. Thermodynamically, the biosorption process proved to be exothermic, spontaneous, and favorable. These results showed that IC biomass is a promising biosorbent for removal of CV and MB dyes from aqueous solutions. © 2017 The Authors.

Registro:

Documento: Artículo
Título:Macroalgae of Iridaea cordata as an efficient biosorbent to remove hazardous cationic dyes from aqueous solutions
Autor:Escudero, L.B.; Smichowski, P.N.; Dotto, G.L.
Filiación:Laboratory of Analytical Chemistry for Research and Development (QUIANID), Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Cuyo, Padre J. Contreras 1300, Mendoza, Argentina
Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires, Argentina
Comisión Nacional de Energía Atómica, Gerencia Química, Av. General Paz 1499, Buenos Aires, Argentina
Chemical Engineering Department, Federal University of Santa Maria-UFSM, 1000 Roraima Avenue, Santa Maria, RS, Brazil
Palabras clave:Algae; Biosorption; Cationic dyes; Kinetic; Thermodynamic; Algae; Aromatic compounds; Biosorption; Dyes; Integrated circuits; Kinetics; Solutions; Sorption; Stripping (dyes); Thermodynamics; Biosorption capacity; Biosorption process; Brunauer emmett tellers; Cationic dyes; Experimental kinetics; Full factorial design; Optimal conditions; Pseudo-second order model; Biohazards; crystal violet; methylene blue; absorption; aqueous solution; biological uptake; biomass; bioremediation; biotechnology; dye; experimental design; isotherm; macroalga; pollutant removal; reaction kinetics; thermodynamics; aqueous solution; Article; biosorption; concentration (parameters); equilibrium constant; factorial design; hazardous waste; Iridaea cordata; kinetics; macroalga; nonhuman; pH; thermodynamics; algae; Iridaea cordata
Año:2017
Volumen:76
Número:12
Página de inicio:3379
Página de fin:3391
DOI: http://dx.doi.org/10.2166/wst.2017.505
Título revista:Water Science and Technology
Título revista abreviado:Water Sci. Technol.
ISSN:02731223
CODEN:WSTED
CAS:crystal violet, 467-63-0, 548-62-9; methylene blue, 61-73-4
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02731223_v76_n12_p3379_Escudero

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Citas:

---------- APA ----------
Escudero, L.B., Smichowski, P.N. & Dotto, G.L. (2017) . Macroalgae of Iridaea cordata as an efficient biosorbent to remove hazardous cationic dyes from aqueous solutions. Water Science and Technology, 76(12), 3379-3391.
http://dx.doi.org/10.2166/wst.2017.505
---------- CHICAGO ----------
Escudero, L.B., Smichowski, P.N., Dotto, G.L. "Macroalgae of Iridaea cordata as an efficient biosorbent to remove hazardous cationic dyes from aqueous solutions" . Water Science and Technology 76, no. 12 (2017) : 3379-3391.
http://dx.doi.org/10.2166/wst.2017.505
---------- MLA ----------
Escudero, L.B., Smichowski, P.N., Dotto, G.L. "Macroalgae of Iridaea cordata as an efficient biosorbent to remove hazardous cationic dyes from aqueous solutions" . Water Science and Technology, vol. 76, no. 12, 2017, pp. 3379-3391.
http://dx.doi.org/10.2166/wst.2017.505
---------- VANCOUVER ----------
Escudero, L.B., Smichowski, P.N., Dotto, G.L. Macroalgae of Iridaea cordata as an efficient biosorbent to remove hazardous cationic dyes from aqueous solutions. Water Sci. Technol. 2017;76(12):3379-3391.
http://dx.doi.org/10.2166/wst.2017.505