Abstract:
Composites of cobalt ferrite nanoparticles in a polypyrrole (PPy) matrix have been synthesized in acid media and characterized by X-ray diffraction studies, scanning and transmission electron microscopy observation, thermogravimetric analysis, conductivity, and infrared spectroscopy measurements. Two types of composites were prepared: one including dodecylbenzenesulphonic acid as a particle protector and another one without protection. The magnetic behavior was studied through DC magnetization measurements; hysteresis loops were observed, showing ferromagnetic behavior for particles and composites. Materials with particle protection showed magnetic parameters independent of the PPy/ferrite ratio; in the absence of protector, both the coercivity and remanence ratio decreased as the PPy/ferrite ratio increased. These results are attributed to conducting polymer effects on the ferrite particles, affecting the magnetic anisotropy. On the other hand, composites with low PPy/ferrite ratio showed positive magnetoresistance of up to 20% at room temperature, indicating an effect of the magnetic particles on polymer conduction. POLYM. COMPOS., 39:4617–4627, 2018. © 2017 Society of Plastics Engineers. © 2017 Society of Plastics Engineers
Registro:
Documento: |
Artículo
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Título: | Polypyrrole-CoFe 2 O 4 nanocomposites: Polymer influence on magnetic behavior and particle effects on polymer conduction |
Autor: | Muñoz Resta, I.; Sellés, J.M.; Lanús-Méndez-Elizalde, M.; Antonel, P.S.; Molina, F.V. |
Filiación: | Instituto de Química Física de Materiales, Ambiente y Energía (INQUIMAE), Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon II, piso 1, Buenos Aires, C1428EGA, Argentina
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Palabras clave: | Conducting polymers; Ferrite; High resolution transmission electron microscopy; Infrared spectroscopy; Magnetic anisotropy; Magnetic materials; Plastic products; Polypyrroles; Scanning electron microscopy; Synthesis (chemical); Thermogravimetric analysis; Transmission electron microscopy; Cobalt ferrite nanoparticles; Coercivity and remanences; Ferromagnetic behaviors; Magnetic parameters; Positive magnetoresistance; Scanning and transmission electron microscopy; Spectroscopy measurements; X-ray diffraction studies; Magnetic bubbles |
Año: | 2018
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Volumen: | 39
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Número: | 12
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Página de inicio: | 4617
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Página de fin: | 4627
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DOI: |
http://dx.doi.org/10.1002/pc.24575 |
Título revista: | Polymer Composites
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Título revista abreviado: | Polym Compos
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ISSN: | 02728397
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CODEN: | PCOMD
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02728397_v39_n12_p4617_MunozResta |
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Citas:
---------- APA ----------
Muñoz Resta, I., Sellés, J.M., Lanús-Méndez-Elizalde, M., Antonel, P.S. & Molina, F.V.
(2018)
. Polypyrrole-CoFe 2 O 4 nanocomposites: Polymer influence on magnetic behavior and particle effects on polymer conduction. Polymer Composites, 39(12), 4617-4627.
http://dx.doi.org/10.1002/pc.24575---------- CHICAGO ----------
Muñoz Resta, I., Sellés, J.M., Lanús-Méndez-Elizalde, M., Antonel, P.S., Molina, F.V.
"Polypyrrole-CoFe 2 O 4 nanocomposites: Polymer influence on magnetic behavior and particle effects on polymer conduction"
. Polymer Composites 39, no. 12
(2018) : 4617-4627.
http://dx.doi.org/10.1002/pc.24575---------- MLA ----------
Muñoz Resta, I., Sellés, J.M., Lanús-Méndez-Elizalde, M., Antonel, P.S., Molina, F.V.
"Polypyrrole-CoFe 2 O 4 nanocomposites: Polymer influence on magnetic behavior and particle effects on polymer conduction"
. Polymer Composites, vol. 39, no. 12, 2018, pp. 4617-4627.
http://dx.doi.org/10.1002/pc.24575---------- VANCOUVER ----------
Muñoz Resta, I., Sellés, J.M., Lanús-Méndez-Elizalde, M., Antonel, P.S., Molina, F.V. Polypyrrole-CoFe 2 O 4 nanocomposites: Polymer influence on magnetic behavior and particle effects on polymer conduction. Polym Compos. 2018;39(12):4617-4627.
http://dx.doi.org/10.1002/pc.24575