Artículo

Pessagno, R.C.; Torres Sánchez, R.M.; dos Santos Afonso, M. "Glyphosate behavior at soil and mineral-water interfaces" (2008) Environmental Pollution. 153(1):53-59
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Abstract:

Adsorption isotherms and surface coverage of glyphosate, N-phosphonomethylglycine (PMG), in aqueous suspensions of three Argentine soils with different mineralogical composition were measured as a function of PMG concentration and pH. Zeta potential curves for PMG/soils system were also determined. Montmorillonite and soil sample surface charges were negative and increased as the amount of adsorbed PMG increased, showing that the surface complexes are more negative than those formed during the surface protonation. PMG adsorption on soils were described using Langmuir isotherms and the affinity constants, and the maximum surface coverage was estimated at pH 4 and 7 using a two-term Langmuir isotherm, the mineralogical composition percentages, and maximum surface coverage and Langmuir constants for pure minerals. The influence of organic matter (OM) and iron content of soils on the PMG adsorption was evaluated. The surface coverage of PMG decreased when the OM and iron content decreased for minerals and soils. © 2007 Elsevier Ltd. All rights reserved.

Registro:

Documento: Artículo
Título:Glyphosate behavior at soil and mineral-water interfaces
Autor:Pessagno, R.C.; Torres Sánchez, R.M.; dos Santos Afonso, M.
Filiación:INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria Pabellon II, C1428EHA Buenos Aires, Argentina
CETMIC, CC 49, B1896ZCA M.B. Gonnet, Buenos Aires Province, Argentina
Palabras clave:Adsorption; Clays; Glyphosate; Soils; Surface complexes; Glyphosate behavior; Surface complexes; Biological materials; Isotherms; Minerals; pH effects; Water; Soils; glyphosate; iron; mineral; montmorillonite; n phosphonomethylglycine; organic matter; unclassified drug; adsorption; chemical composition; clay; glyphosate; iron; isotherm; montmorillonite; organic matter; soil; adsorption; article; isotherm; Langmuir isotherm; pH; proton transport; soil; zeta potential; Adsorption; Argentina; Bentonite; Environmental Monitoring; Glycine; Herbicides; Humic Substances; Hydrogen-Ion Concentration; Iron; Soil Pollutants; Water Pollutants; Argentina; South America
Año:2008
Volumen:153
Número:1
Página de inicio:53
Página de fin:59
DOI: http://dx.doi.org/10.1016/j.envpol.2007.12.025
Título revista:Environmental Pollution
Título revista abreviado:Environ. Pollut.
ISSN:02697491
CODEN:ENPOE
CAS:glyphosate, 1071-83-6; iron, 14093-02-8, 53858-86-9, 7439-89-6; montmorillonite, 1318-93-0, 61029-13-8; Bentonite, 1302-78-9; Glycine, 56-40-6; Herbicides; Humic Substances; Iron, 7439-89-6; Soil Pollutants; Water Pollutants; glyphosate, 1071-83-6
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02697491_v153_n1_p53_Pessagno

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Citas:

---------- APA ----------
Pessagno, R.C., Torres Sánchez, R.M. & dos Santos Afonso, M. (2008) . Glyphosate behavior at soil and mineral-water interfaces. Environmental Pollution, 153(1), 53-59.
http://dx.doi.org/10.1016/j.envpol.2007.12.025
---------- CHICAGO ----------
Pessagno, R.C., Torres Sánchez, R.M., dos Santos Afonso, M. "Glyphosate behavior at soil and mineral-water interfaces" . Environmental Pollution 153, no. 1 (2008) : 53-59.
http://dx.doi.org/10.1016/j.envpol.2007.12.025
---------- MLA ----------
Pessagno, R.C., Torres Sánchez, R.M., dos Santos Afonso, M. "Glyphosate behavior at soil and mineral-water interfaces" . Environmental Pollution, vol. 153, no. 1, 2008, pp. 53-59.
http://dx.doi.org/10.1016/j.envpol.2007.12.025
---------- VANCOUVER ----------
Pessagno, R.C., Torres Sánchez, R.M., dos Santos Afonso, M. Glyphosate behavior at soil and mineral-water interfaces. Environ. Pollut. 2008;153(1):53-59.
http://dx.doi.org/10.1016/j.envpol.2007.12.025