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Abstract:

Physico-chemical and rheological characterization of the gum extracted from the endosperm of vinal (Prosopis ruscifolia) seeds was performed. The CG-MS analysis revealed that vinal gum is a galactomannan with a mannose/galactose ratio of 1.6, with traces of arabinose and glucose residues. The structure was further confirmed by 13C NMR which showed several similarities between vinal gum and guar gum spectra. The viscosity molecular weight was 1.43±0.04·106Da (obtained from Huggins plot) and the average number molecular weight was 0.7·105Da. Shear continuous rheology studies showed a shear thinning behavior at concentrations higher than 0.04% (w/v) of vinal gum and an apparent viscosity slightly lower than that of guar gum at the same concentration. Mechanical spectra revealed that vinal gum has a typical macromolecular solution behavior with the moduli crossing point that characterized semi-diluted (0.16-0.3% w/v) gum solutions. The present work provides structural, physicochemical and rheological information of a new galactomannan from an abundant and available non-traditional source, being a starting point for food, pharmaceutical or other industrial potential applications of vinal gum. © 2015 Elsevier Ltd.

Registro:

Documento: Artículo
Título:Vinal gum, a galactomannan from Prosopis ruscifolia seeds: Physicochemical characterization
Autor:Busch, V.M.; Kolender, A.A.; Santagapita, P.R.; Buera, M.P.
Filiación:Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2160, Ciudad Universitaria, Ciudad Autónoma de Buenos Aires, C1428EGA, Argentina
Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Av. Rivadavia 1917, Ciudad Autónoma de Buenos Aires, C1033AAJ, Argentina
Departamento de Química Orgánica, CIHIDECAR-CONICET-UBA, Facultad de Ciencias Exactas y Naturales Pab. 2, Universidad de Buenos Aires, Intendente Güiraldes 2160, Ciudad Autónoma de Buenos Aires, Argentina
Palabras clave:Guar gum; Hydrocolloids; Non-traditional sources; Prosopis; Rheology; Thickener agent; Cyamopsis tetragonoloba; Prosopis; Prosopis ruscifolia
Año:2015
Volumen:51
Página de inicio:495
Página de fin:502
DOI: http://dx.doi.org/10.1016/j.foodhyd.2015.04.035
Título revista:Food Hydrocolloids
Título revista abreviado:Food Hydrocolloids
ISSN:0268005X
CODEN:FOHYE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0268005X_v51_n_p495_Busch

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Citas:

---------- APA ----------
Busch, V.M., Kolender, A.A., Santagapita, P.R. & Buera, M.P. (2015) . Vinal gum, a galactomannan from Prosopis ruscifolia seeds: Physicochemical characterization. Food Hydrocolloids, 51, 495-502.
http://dx.doi.org/10.1016/j.foodhyd.2015.04.035
---------- CHICAGO ----------
Busch, V.M., Kolender, A.A., Santagapita, P.R., Buera, M.P. "Vinal gum, a galactomannan from Prosopis ruscifolia seeds: Physicochemical characterization" . Food Hydrocolloids 51 (2015) : 495-502.
http://dx.doi.org/10.1016/j.foodhyd.2015.04.035
---------- MLA ----------
Busch, V.M., Kolender, A.A., Santagapita, P.R., Buera, M.P. "Vinal gum, a galactomannan from Prosopis ruscifolia seeds: Physicochemical characterization" . Food Hydrocolloids, vol. 51, 2015, pp. 495-502.
http://dx.doi.org/10.1016/j.foodhyd.2015.04.035
---------- VANCOUVER ----------
Busch, V.M., Kolender, A.A., Santagapita, P.R., Buera, M.P. Vinal gum, a galactomannan from Prosopis ruscifolia seeds: Physicochemical characterization. Food Hydrocolloids. 2015;51:495-502.
http://dx.doi.org/10.1016/j.foodhyd.2015.04.035