Abstract:
Thin films of polymerized acetylene have been deposited by Plasma Enhanced Chemical Vapor Deposition with a capacitively coupled RF discharge of acetylene. From the results of elemental analysis, FTIR, 1 H-NMR and electrical conductivity, a highly branched chemical structure for the polymeric film is proposed. The morphology of the film surface, as well as its thickness was determined by scanning electron microscopy. The optical constants of the film, refractive index and optical band gap energy were obtained by the UV-vis transmittance spectrum using different models from the literature. The films presented a moderate degree of hydrophobicity and showed a high capacity to absorb and retain benzene after drying at room temperature during 24h. This result shows the potential of the obtained polymer to be used in filler of filters employed for the treatment of industrial effluents. © 2012 Elsevier B.V.
Registro:
Documento: |
Artículo
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Título: | Thin films of polymerized acetylene by RF discharge and its benzene absorption ability |
Autor: | Arias-Durán, A.; Giuliani, L.; Accorso, N.B. D.'.; Grondona, D.; Goyanes, S. |
Filiación: | LP and MC, Departamento de Física, FCEyN - UBA, IFIBA, CONICET Ciudad Universitaria 1428, Ciudad Autónoma de Buenos Aires, Argentina INFIP, CONICET, Departamento de Física, FCEyN -UBA, Ciudad Universitaria 1428, Ciudad Autónoma de Buenos Aires, Argentina CIHIDECAR-CONICET; Departamento de Química Orgánica, FCEyN - UBA, Ciudad Universitaria 1428, Ciudad Autónoma de Buenos Aires, Argentina
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Palabras clave: | Acetylene; Benzene absorption; Polymerization; RF plasma; Capacitively coupled RF discharge; Electrical conductivity; Film surfaces; FTIR; High capacity; Industrial effluent; Optical band gap energy; RF discharge; RF plasma; Room temperature; Transmittance spectra; Benzene; Electric conductivity; Filled polymers; Lighting; Optical constants; Plasma enhanced chemical vapor deposition; Polymerization; Refractive index; Scanning electron microscopy; Sewage; Thin films; Acetylene |
Año: | 2013
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Volumen: | 216
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Página de inicio: | 185
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Página de fin: | 190
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DOI: |
http://dx.doi.org/10.1016/j.surfcoat.2012.11.063 |
Título revista: | Surface and Coatings Technology
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Título revista abreviado: | Surf. Coat. Technol.
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ISSN: | 02578972
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02578972_v216_n_p185_AriasDuran |
Referencias:
- Shi Frank, F., (1996) Surf. Coat. Technol., 82, p. 1
- König, H., Helwig, G., (1951) Z. Phys., 129, p. 491
- Goodman, J., (1960) J. Polym. Sci., 44, p. 551
- Gregor, L.V., (1968) IBM J., 2, p. 140
- Jesch, K., Bloor, J.E., Kronick, P.L., (1966) J. Polym. Sci., 4, p. 1487
- Liang, T.S., Akagi, K., Shirakawa, H., (1999) Synth. Met., 101, p. 67
- Biederman, H., Slavínská, D., (2000) Surf. Coat. Technol., 125, p. 371
- Zajickova, L., Rudakowski, S., Becker, W., Meyer, D., Valtr, M., Wiesemann, K., (2003) Thin Solid Films, 425, p. 72
- Kang, H., (2009) Bull. Korean Chem. Soc., 30, p. 2589
- Li, Y., Yang, M.J., (2002) Sens. Actuators B, 87, p. 184
- Li, Y., Yang, M., (2002) Synth. Met., 129, p. 285
- Chena, K.-S., Wei, T.-C., Li, M.-S., Wu, H.-M., Tang, T.-P., Wang, C.-Y., Tu, Y.-C., (2007) Radiat. Phys. Chem., 76, p. 941
- Goodman, A.M., (1978) Appl. Optics, 17, p. 2729
- Tauc, J., Grigorovici, R., Vancu, A., (1966) Phys. Status Solidi, 15, p. 627
- Le Dû Gwénaëlle, Celini, N., Bergaya, F., Poncin-Epaillard, F., (2007) Surf. Coat. Technol., 201, p. 5815
- Friedrich, J., (2011) Plasma Process. Polym., 8, p. 783
- Terje Hansen, A.R., van de Sanden, R., Engeln, R., (2011) Plasma Process. Polym., 8, p. 832
- Vizireanu, S., Stoica, S.D., Luculescu, C., Nistor, L.C., Mitu, B., Dinescu, G., (2010) Plasma Sources Sci. Technol., 19, p. 034016
- Benediikt, J., (2010) J. Phys. D: Appl. Phys., 43, p. 043001
- Valderrama, E., Favre, M., Bhuyan, H., Ruiz, H.M., Wyndham, E., Valenzuela, J., Chuaqui, H., (2010) Surf. Coat. Technol., 204, p. 2940
- Kovacevic, E., Berndt, J., Strunskus, T., Boufendi, L., (2012) J. Appl. Phys., 112, p. 013303
- Hegger, J., (2001) Rev. Mod. Phys., 73, p. 687
- Skorobogatov, V.M., Krivoshei, I.V., (1988) Russ. Chem. Rev., 57, p. 461
Citas:
---------- APA ----------
Arias-Durán, A., Giuliani, L., Accorso, N.B. D.'., Grondona, D. & Goyanes, S.
(2013)
. Thin films of polymerized acetylene by RF discharge and its benzene absorption ability. Surface and Coatings Technology, 216, 185-190.
http://dx.doi.org/10.1016/j.surfcoat.2012.11.063---------- CHICAGO ----------
Arias-Durán, A., Giuliani, L., Accorso, N.B. D.'., Grondona, D., Goyanes, S.
"Thin films of polymerized acetylene by RF discharge and its benzene absorption ability"
. Surface and Coatings Technology 216
(2013) : 185-190.
http://dx.doi.org/10.1016/j.surfcoat.2012.11.063---------- MLA ----------
Arias-Durán, A., Giuliani, L., Accorso, N.B. D.'., Grondona, D., Goyanes, S.
"Thin films of polymerized acetylene by RF discharge and its benzene absorption ability"
. Surface and Coatings Technology, vol. 216, 2013, pp. 185-190.
http://dx.doi.org/10.1016/j.surfcoat.2012.11.063---------- VANCOUVER ----------
Arias-Durán, A., Giuliani, L., Accorso, N.B. D.'., Grondona, D., Goyanes, S. Thin films of polymerized acetylene by RF discharge and its benzene absorption ability. Surf. Coat. Technol. 2013;216:185-190.
http://dx.doi.org/10.1016/j.surfcoat.2012.11.063