Artículo
Marzocca, A.J.; Goyanes, S.; Garraza, A.L.R. "Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system " (2010) Revista Latinoamericana de Metalurgia y Materiales. 30(1):67-72
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Abstract:
Samples of cured medium cis polybutadiene compound, formulated with sulphur and accelerator and vulcanized at 433 K, were prepared at different cure times in order to obtain different network structures. Uniaxial stress strain tests were performed at room temperature and analyzed in the frame of the tube model and the molecular weight between crosslinks was obtained. Swelling tests in toluene at room temperature were made in the same samples and the volume fraction of rubber was calculated in each case. By means of the Flory-Rehner relationship and using the molecular weight between crosslinks, the Flory's parameter χ was estimated for the polybutadiene/toluene system. © 2010 Universidad Simón Bolívar (Venezuela).
Registro:
| Documento: | Artículo |
| Título: | Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system |
| Autor: | Marzocca, A.J.; Goyanes, S.; Garraza, A.L.R. |
| Filiación: | Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Física, LPMPyMC, Pabellón 1, Buenos Aires (C1428EGA), Argentina Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Argentina |
| Palabras clave: | Polybutadiene rubber; Swelling; Toluene; Vulcanization |
| Año: | 2010 |
| Volumen: | 30 |
| Número: | 1 |
| Página de inicio: | 67 |
| Página de fin: | 72 |
| Título revista: | Revista Latinoamericana de Metalurgia y Materiales |
| Título revista abreviado: | Rev. Latinoam. Met. Materiales |
| ISSN: | 02556952 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02556952_v30_n1_p67_Marzocca |
Referencias:
- Marzocca, A.J., (2007) European Polym. J., 43, pp. 2682-2689
- Flory, P.J., Rehner, J., (1943) J. Chem. Phys., 11, pp. 512-520
- Hergenrother, W.T., (1972) J. Appl. Polym. Sci., 16, pp. 2611-2622
- Scott, R.L., Magat, M., (1949) J. Polym. Sci., 4, pp. 555-571
- Short, J., Thornton, V., Kraus, G., (1957) Rubber Chem. Technol., 30, pp. 1118-1141
- Kraus, G., (1963) J. Appl. Polym. Sci., 7, pp. 1257-1263
- Gavrilov, V.M., Shvarts, A.G., (1974) Rubber Chem. Technol., 47, pp. 303-306
- Heinrich, G., Straube, E., Helmis, G., (1988) Adv. Polym. Sci., 85, pp. 33-87
- Heinrich, G., Vilgis, T.A., (1993) Macromolecules, 26, pp. 1109-1119
- Marzocca, A.J., Goyanes, S., (2004) J. Appl. Polym. Sci., 91, pp. 2601-2609
- Marzocca, A.J., (1995) J. Appl. Polym. Sci., 58, pp. 1839-1845
- Marzocca, A.J., Cerveny, S., Raimondo, R.B., (1997) J. Appl. Polym. Sci., 66, pp. 1085-1092
- Cerveny, S., Marzocca, A.J., (1999) J. Appl. Polym. Sci., 74, pp. 2747-2755
- (1997) CRC Handbook of Chemistry and Physics, pp. 3-55. , Lide DR, editor, 78th ed., New York, CRC Press
- Gronski, W., Hoffmann, V., Simon, G., Wutzler, A., Straube, E., (1991) Rubber Chem. Technol., 65, pp. 63-77
- Clough, R.S., Koenig, J.L., (1989) Rubber Chem. Technol., 62, pp. 908-927
- Posh, B.T., Adachi, K., Kotaka, T., (1987) Macromolecules, 20, pp. 2574-2579
Citas:
---------- APA ----------
Marzocca, A.J., Goyanes, S. & Garraza, A.L.R. (2010) . Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system . Revista Latinoamericana de Metalurgia y Materiales, 30(1), 67-72.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02556952_v30_n1_p67_Marzocca [ ]
---------- CHICAGO ----------
Marzocca, A.J., Goyanes, S., Garraza, A.L.R. "Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system " . Revista Latinoamericana de Metalurgia y Materiales 30, no. 1 (2010) : 67-72.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02556952_v30_n1_p67_Marzocca [ ]
---------- MLA ----------
Marzocca, A.J., Goyanes, S., Garraza, A.L.R. "Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system " . Revista Latinoamericana de Metalurgia y Materiales, vol. 30, no. 1, 2010, pp. 67-72.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02556952_v30_n1_p67_Marzocca [ ]
---------- VANCOUVER ----------
Marzocca, A.J., Goyanes, S., Garraza, A.L.R. Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system . Rev. Latinoam. Met. Materiales. 2010;30(1):67-72.Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02556952_v30_n1_p67_Marzocca [ ]
