Artículo
Rodríguez, J.; Feuillet, G.; Donatini, F.; Onna, D.; Sanchez, L.; Candal, R.; Marchi, M.C.; Bilmes, S.A.; Chandezon, F. "Influence of the spray pyrolysis seeding and growth parameters on the structure and optical properties of ZnO nanorod arrays" (2015) Materials Chemistry and Physics. 151:378-384
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Abstract:
ZnO nanorods (NRs) were grown on fluorine doped tin oxide (FTO) substrates at low temperatures (90 °C) from Zn 2+ precursors in alkaline media previously seeded with ZnO nanoparticles. These were deposited onto the FTO substrate heated at 350 °C by spray pyrolysis of a Zn acetate solution in a water ethanol mixture. The structure of seeds was tuned by the ethanol to water ratio, Γ, which controls the solvent evaporation rate of drops impinging the substrate. From a detailed characterization using a combination of scanning electron microscopy, X-ray diffraction, UV-visible absorption and cathodoluminescence spectroscopies, the dependence of the morphology and optical properties of the ZnO NRs on the seeding conditions was demonstrated. NRs grown on seeds deposited from solutions with Γ in the 0.03-0.06 range - i.e. when the surface excess of ethanol in the water-ethanol mixture has a maximum - show thinner average diameters and stacking faults due to the presence of zinc blende domains embedded into an overall wurtzite NR. They furthermore exhibit blue-shifted near band edge emission peak and a high deep level emission in cathodoluminescence. All these findings support the use of spray pyrolysis as a simple and reproducible way to control the seeds deposition, influencing the growth, the structure and the optical properties of the final ZnO NRs.
Registro:
| Documento: | Artículo |
| Título: | Influence of the spray pyrolysis seeding and growth parameters on the structure and optical properties of ZnO nanorod arrays |
| Autor: | Rodríguez, J.; Feuillet, G.; Donatini, F.; Onna, D.; Sanchez, L.; Candal, R.; Marchi, M.C.; Bilmes, S.A.; Chandezon, F. |
| Filiación: | Facultad de Ciencias, Universidad Nacional de Ingeniería, P.O. Box 31-139, Lima 31, Peru CEA Grenoble/LETI, 17 rue des Martyrs, Grenoble Cedex 9, F-38054, France Univ. Grenoble Alpes, Inst NEEL, Grenoble, F-38000, France CNRS, Inst NEEL, Grenoble, F-38042, France DQIAQF-INQUIMAE, FCEyN-Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, Buenos Aires, 1428, Argentina ECyT, 3iA, Universidad Nacional de San Martín, Martín de Irigoyen N° 3100 (1650), San Martín, Pcia de Buenos Aires, Argentina CMA, FCEyN-Universidad de Buenos Aires, Ciudad Universitaria, Pab. i, Buenos Aires, 1428, Argentina University Grenoble Alpes, INAC-SPRAM, Grenoble, F-38000, France CNRS, INAC-SPRAM, Grenoble, F-38000, France CEA, INAC-SPRAM, Grenoble, F-38000, France |
| Palabras clave: | Chemical synthesis; Nanostructures; Optical properties; Semiconductors; Thin films; Vapour deposition; Alkalinity; Cathodoluminescence; Deposition; Ethanol; Film growth; Mixtures; Nanocomposites; Nanorods; Nanostructures; Organic solvents; Scanning electron microscopy; Semiconductor materials; Spray pyrolysis; Stacking faults; Substrates; Synthesis (chemical); Thin films; Tin oxides; X ray diffraction; Zinc; Zinc oxide; Zinc sulfide; Cathodoluminescence spectroscopy; Deep level emission; Fluorine doped tin oxide; Near band edge emissions; Solvent evaporation; UV-visible absorption; Vapour deposition; Water ethanol mixtures; Optical properties |
| Año: | 2015 |
| Volumen: | 151 |
| Página de inicio: | 378 |
| Página de fin: | 384 |
| DOI: | http://dx.doi.org/10.1016/j.matchemphys.2014.12.013 |
| Título revista: | Materials Chemistry and Physics |
| Título revista abreviado: | Mater Chem Phys |
| ISSN: | 02540584 |
| CODEN: | MCHPD |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02540584_v151_n_p378_Rodriguez |
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Citas:
---------- APA ----------
Rodríguez, J., Feuillet, G., Donatini, F., Onna, D., Sanchez, L., Candal, R., Marchi, M.C.,..., Chandezon, F. (2015) . Influence of the spray pyrolysis seeding and growth parameters on the structure and optical properties of ZnO nanorod arrays. Materials Chemistry and Physics, 151, 378-384.http://dx.doi.org/10.1016/j.matchemphys.2014.12.013
---------- CHICAGO ----------
Rodríguez, J., Feuillet, G., Donatini, F., Onna, D., Sanchez, L., Candal, R., et al. "Influence of the spray pyrolysis seeding and growth parameters on the structure and optical properties of ZnO nanorod arrays" . Materials Chemistry and Physics 151 (2015) : 378-384.http://dx.doi.org/10.1016/j.matchemphys.2014.12.013
---------- MLA ----------
Rodríguez, J., Feuillet, G., Donatini, F., Onna, D., Sanchez, L., Candal, R., et al. "Influence of the spray pyrolysis seeding and growth parameters on the structure and optical properties of ZnO nanorod arrays" . Materials Chemistry and Physics, vol. 151, 2015, pp. 378-384.http://dx.doi.org/10.1016/j.matchemphys.2014.12.013
---------- VANCOUVER ----------
Rodríguez, J., Feuillet, G., Donatini, F., Onna, D., Sanchez, L., Candal, R., et al. Influence of the spray pyrolysis seeding and growth parameters on the structure and optical properties of ZnO nanorod arrays. Mater Chem Phys. 2015;151:378-384.http://dx.doi.org/10.1016/j.matchemphys.2014.12.013
