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Abstract:

Cu-Au skarn deposits of the mining district of Santa María de La Paz are located in the Sierra del Fraile, in the northern part of San Luis Potosí, Mexico. Samples of four different intrusions and their related skarn deposits were taken underground, in order to obtain whole-rock and mineral geochemical data. U-Pb LA-ICP-MS zircon data indicate crystallization ages of ca. 37.6–35.0 Ma for skarn-related granitic and granodioritic stocks, which show dominant metaluminous to slightly peraluminous, high-K calc-alkaline compositions. These intrusions were emplaced in a post-Laramide continental arc setting under shallow conditions, as suggested by fast cooling inferred from K-Ar biotite ages of ca. 35–33 Ma. Skarn deposits were contemporaneous with emplacement and crystallization of stocks, as revealed by Re-Os molybdenite geochronological data of exoskarn rocks. Skarn rocks show a general depletion of LILE and REE and a slightly enrichment in HFSE in comparison with intrusive rocks. Pyroxene and garnet show dominant hedenbergite and andradite compositions, respectively. The association of hedenbergite, pyrite, chalcopyrite, native bismuth and pyrrhotite during skarn mineralization suggest reducing conditions, typical for Au but not for Cu skarns. Highest metal contents are concentrated in exoskarn rocks, including anomalies of Cu, Fe, Ni, Sn, Sb, Zn, W and Bi. Metal contents, ore minerals and environmental conditions of skarn rocks, together with whole-rock geochemical data of stocks and pyroxene-garnet compositions, reveal some singularities for the Sierra del Fraile deposits, as they exhibit characteristics of both Cu and Au skarn deposits but might be also compatible with Fe, W, and Zn skarns. Hence, skarn and associated vein deposits of the Sierra del Fraile might have a high potential not only for Cu-Au, but also for several base metals, as reported for comparable post-Laramide skarn and hydrothermal deposits of central and northern Mexico. © 2018 Elsevier B.V.

Registro:

Documento: Artículo
Título:Geochronological and geochemical constraints on the genesis of Cu-Au skarn deposits of the Santa María de la Paz district (Sierra del Fraile, Mexico)
Autor:Siesgesmund, S.; López-Doncel, R.; Sieck, P.; Wilke, H.; Wemmer, K.; Frei, D.; Oriolo, S.
Filiación:Geoscience Centre, Georg-August-Universität Göttingen, Goldschmidtstraße 3, Göttingen, 37077, Germany
Instituto de Geología, Universidad Autónoma de San Luis Potosí, Av. Manuel Nava 5, San Luis Potosí, 78240, Mexico
División de Geociencias Aplicadas, Instituto Potosino de Investigación Científica y Tecnológica (IPICyT), Camino a la Presa San José 2055, Lomas 4° Sección, San Luis Potosí, 78216, Mexico
Department of Earth Sciences, University of the Western Cape, Private Bag X17, Bellville, 7530, South Africa
Department of Earth Sciences, Stellenbosch University, Private Bag X1, Matieland, 7602, South Africa
CONICET-Universidad de Buenos Aires. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires (IGEBA), Intendente Güiraldes 2160, C1428EHA Buenos Aires, Argentina
Palabras clave:Andradite-hedenbergite skarn; Cu-Au mineralization; Eocene; Ore deposits; Post-Laramide magmatism; Re-Os geochronology; Binary alloys; Copper; Copper alloys; Copper compounds; Deposits; Garnets; Geochemistry; Geochronology; Gold; Gold alloys; Gold deposits; Lead alloys; Mica; Mineralogy; Ore deposits; Osmium alloys; Pyrites; Rhenium alloys; Rocks; Silicate minerals; Zircon; Crystallization age; Environmental conditions; Eocene; Geochemical data; Hedenbergite; Hydrothermal deposits; Magmatisms; Reducing conditions; Potassium compounds; age determination; andradite; copper; crystallization; emplacement; Eocene; geochemistry; geochronology; gold; hedenbergite; hydrothermal deposit; magmatism; ore deposit; petrogenesis; skarn; Mexico [North America]; San Luis Potosi; Sierra del Fraile; Potos
Año:2018
Volumen:94
Página de inicio:310
Página de fin:325
DOI: http://dx.doi.org/10.1016/j.oregeorev.2018.02.010
Título revista:Ore Geology Reviews
Título revista abreviado:Ore Geol. Rev.
ISSN:01691368
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01691368_v94_n_p310_Siesgesmund

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Citas:

---------- APA ----------
Siesgesmund, S., López-Doncel, R., Sieck, P., Wilke, H., Wemmer, K., Frei, D. & Oriolo, S. (2018) . Geochronological and geochemical constraints on the genesis of Cu-Au skarn deposits of the Santa María de la Paz district (Sierra del Fraile, Mexico). Ore Geology Reviews, 94, 310-325.
http://dx.doi.org/10.1016/j.oregeorev.2018.02.010
---------- CHICAGO ----------
Siesgesmund, S., López-Doncel, R., Sieck, P., Wilke, H., Wemmer, K., Frei, D., et al. "Geochronological and geochemical constraints on the genesis of Cu-Au skarn deposits of the Santa María de la Paz district (Sierra del Fraile, Mexico)" . Ore Geology Reviews 94 (2018) : 310-325.
http://dx.doi.org/10.1016/j.oregeorev.2018.02.010
---------- MLA ----------
Siesgesmund, S., López-Doncel, R., Sieck, P., Wilke, H., Wemmer, K., Frei, D., et al. "Geochronological and geochemical constraints on the genesis of Cu-Au skarn deposits of the Santa María de la Paz district (Sierra del Fraile, Mexico)" . Ore Geology Reviews, vol. 94, 2018, pp. 310-325.
http://dx.doi.org/10.1016/j.oregeorev.2018.02.010
---------- VANCOUVER ----------
Siesgesmund, S., López-Doncel, R., Sieck, P., Wilke, H., Wemmer, K., Frei, D., et al. Geochronological and geochemical constraints on the genesis of Cu-Au skarn deposits of the Santa María de la Paz district (Sierra del Fraile, Mexico). Ore Geol. Rev. 2018;94:310-325.
http://dx.doi.org/10.1016/j.oregeorev.2018.02.010