Artículo

Marco-Brown, J.L.; Barbosa-Lema, C.M.; Torres Sánchez, R.M.; Mercader, R.C.; dos Santos Afonso, M. "Adsorption of picloram herbicide on iron oxide pillared montmorillonite" (2012) Applied Clay Science. 58:25-33
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Abstract:

The adsorption of picloram on Fe Oxide Pillared Clays (PILC) as a possible basis for the development of adsorbent materials for the remediation of polluted environments was studied. To this end, after characterizing PILC obtained from raw clay from Wyoming, USA by XRD, elemental analysis, Mössbauer spectroscopy, DTA, TGA and N 2 adsorption (BET), the picloram adsorption was studied at constant pH and ionic strength after 48h equilibration with an aqueous solution of PCM. PCM adsorbed samples were characterized by SEM, zeta-potential vs pH functions, FTIR and TGA-DTA and the adsorption was modellated using Langmuir and Freundlich models. The results reveal that the surface area and interlayer space of PILC are bigger than those of raw montmorillonite. An analysis of the adsorption isotherms of picloram on the PILC showed that picloram adsorption increases with decreasing pH. The adsorption of PCM on PILC was 150 times higher than that found for raw montmorillonite under similar conditions. The zeta-potential vs pH functions shape and FTIR indicated that PCM coordinates the surface iron centers throughout pyridinic nitrogen atom forming inner-sphere complexes. The much greater PCM adsorption on PILC turns the process into an excellent candidate to be used for dosing or remediation of pesticides. © 2012 Elsevier B.V.

Registro:

Documento: Artículo
Título:Adsorption of picloram herbicide on iron oxide pillared montmorillonite
Autor:Marco-Brown, J.L.; Barbosa-Lema, C.M.; Torres Sánchez, R.M.; Mercader, R.C.; dos Santos Afonso, M.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física e INQUIMAE, FCEN, UBA, Ciudad Universitaria, Pabellón II, C1428EHA, Buenos Aires, Argentina
CETMIC (Centro de Tecnología en Minerales y Cerámica), Camino Centenario y 506, CC (49) (B1897ZCA) M. B. Gonnet, Argentina
Departamento de Física, IFLP, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, La Plata, Argentina
Palabras clave:Herbicides; Montmorillonite; Picloram; Pillared clay; Adsorbent materials; Fe oxide; Freundlich models; FTIR; Inner sphere complexes; Interlayer spaces; Iron centers; Langmuirs; Picloram; Pillared clay; Pillared montmorillonite; Pyridinic nitrogen; Raw clay; Ssbauer spectroscopies; Surface area; Wyoming ,USA; XRD; Adsorption; Clay minerals; Fourier transform infrared spectroscopy; Ionic strength; Iron compounds; Iron oxides; Pollution; Pyridine; Spheres; Weed control; Herbicides; adsorption; aqueous solution; herbicide; iron oxide; montmorillonite; pH; phase equilibrium; pillared clay; remediation
Año:2012
Volumen:58
Página de inicio:25
Página de fin:33
DOI: http://dx.doi.org/10.1016/j.clay.2012.01.004
Título revista:Applied Clay Science
Título revista abreviado:Appl. Clay Sci.
ISSN:01691317
CODEN:ACLSE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01691317_v58_n_p25_MarcoBrown

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Citas:

---------- APA ----------
Marco-Brown, J.L., Barbosa-Lema, C.M., Torres Sánchez, R.M., Mercader, R.C. & dos Santos Afonso, M. (2012) . Adsorption of picloram herbicide on iron oxide pillared montmorillonite. Applied Clay Science, 58, 25-33.
http://dx.doi.org/10.1016/j.clay.2012.01.004
---------- CHICAGO ----------
Marco-Brown, J.L., Barbosa-Lema, C.M., Torres Sánchez, R.M., Mercader, R.C., dos Santos Afonso, M. "Adsorption of picloram herbicide on iron oxide pillared montmorillonite" . Applied Clay Science 58 (2012) : 25-33.
http://dx.doi.org/10.1016/j.clay.2012.01.004
---------- MLA ----------
Marco-Brown, J.L., Barbosa-Lema, C.M., Torres Sánchez, R.M., Mercader, R.C., dos Santos Afonso, M. "Adsorption of picloram herbicide on iron oxide pillared montmorillonite" . Applied Clay Science, vol. 58, 2012, pp. 25-33.
http://dx.doi.org/10.1016/j.clay.2012.01.004
---------- VANCOUVER ----------
Marco-Brown, J.L., Barbosa-Lema, C.M., Torres Sánchez, R.M., Mercader, R.C., dos Santos Afonso, M. Adsorption of picloram herbicide on iron oxide pillared montmorillonite. Appl. Clay Sci. 2012;58:25-33.
http://dx.doi.org/10.1016/j.clay.2012.01.004