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Abstract:

The purpose of this study is to evaluate the efficiency of benzimidazole removal using raw, thermally and mechanically treated montmorillonite surfaces. The comparison of benzimidazole adsorption curves on these montmorillonite surfaces was made. A two step sorption mechanism that describes the data was corroborated by X-ray diffraction (XRD) results.The removal efficiency for the different sorbents at pH 6 follows the sequence raw montmorillonite > thermally treated montmorillonite > mechanically treated montmorillonite.The external and the interlayer surfaces were proposed as adsorption sites. On the latter, benzimidazole adsorbs in a planar monolayer arrangement with a consequent reduced water uptake.Two different foms of benzimidazole nitrogen surface coordination were indicated by X-ray photoelectron spectroscopy (XPS) results and isoelectric point (IEP) values. Protonated and deprotonated nitrogen were equally coordinated to the surface for raw and thermally treated samples at low temperature (350 °C). Stronger coordination of deprotonated nitrogen was found for samples treated at higher temperature (550 °C), while only a cationic exchange and no coordination to the surface was observed for the mechanically treated sample. © 2010 Elsevier B.V.

Registro:

Documento: Artículo
Título:Benzimidazole adsorption on the external and interlayer surfaces of raw and treated montmorillonite
Autor:Torres Sánchez, R.M.; Genet, M.J.; Gaigneaux, E.M.; dos Santos Afonso, M.; Yunes, S.
Filiación:Cetmic (Centro de Tecnología en Minerales y Cerámica), Camino Centenario y 506 CC (49), (B1897ZCA) M. B. Gonnet, Argentina
Unité de chimie des Interfaces Université Catholique de Louvain, Croix du Sud 2/18, B-1348 Louvain-la-Neuve, Belgium
Unité de catalyse et de chimie des matériaux divisés, Université Catholique de Louvain, Croix du Sud 2/17, B-1348 Louvain-la-Neuve, Belgium
Dep. de Química Inorgánica, Analítica y Química Física e Inquimae, FCEN, UBA Ciudad Universitaria, Pabellón II, C1428EHA, Buenos Aires, Argentina
YUMA Consulting, Calle 5 Terrazas del Ávila, Caracas-107, Venezuela
Palabras clave:Benzimidazole; Montmorillonite; Sorption mechanism; Thermal and mechanical treatments; Adsorption curves; Adsorption site; Benzimidazoles; Cationic exchange; Higher temperatures; Interlayer surface; Iso-electric points; Low temperatures; Mechanical treatments; Montmorillonite surface; Planar monolayers; Protonated; Removal efficiencies; Sorption mechanism; Adsorption; Monolayers; Nitrogen; Photoelectron spectroscopy; X ray diffraction; X ray photoelectron spectroscopy; Clay minerals; adsorption; cation; heating; ion exchange; montmorillonite; reaction kinetics; X-ray diffraction
Año:2011
Volumen:53
Número:3
Página de inicio:366
Página de fin:373
DOI: http://dx.doi.org/10.1016/j.clay.2010.06.026
Título revista:Applied Clay Science
Título revista abreviado:Appl. Clay Sci.
ISSN:01691317
CODEN:ACLSE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01691317_v53_n3_p366_TorresSanchez

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Citas:

---------- APA ----------
Torres Sánchez, R.M., Genet, M.J., Gaigneaux, E.M., dos Santos Afonso, M. & Yunes, S. (2011) . Benzimidazole adsorption on the external and interlayer surfaces of raw and treated montmorillonite. Applied Clay Science, 53(3), 366-373.
http://dx.doi.org/10.1016/j.clay.2010.06.026
---------- CHICAGO ----------
Torres Sánchez, R.M., Genet, M.J., Gaigneaux, E.M., dos Santos Afonso, M., Yunes, S. "Benzimidazole adsorption on the external and interlayer surfaces of raw and treated montmorillonite" . Applied Clay Science 53, no. 3 (2011) : 366-373.
http://dx.doi.org/10.1016/j.clay.2010.06.026
---------- MLA ----------
Torres Sánchez, R.M., Genet, M.J., Gaigneaux, E.M., dos Santos Afonso, M., Yunes, S. "Benzimidazole adsorption on the external and interlayer surfaces of raw and treated montmorillonite" . Applied Clay Science, vol. 53, no. 3, 2011, pp. 366-373.
http://dx.doi.org/10.1016/j.clay.2010.06.026
---------- VANCOUVER ----------
Torres Sánchez, R.M., Genet, M.J., Gaigneaux, E.M., dos Santos Afonso, M., Yunes, S. Benzimidazole adsorption on the external and interlayer surfaces of raw and treated montmorillonite. Appl. Clay Sci. 2011;53(3):366-373.
http://dx.doi.org/10.1016/j.clay.2010.06.026