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Abstract:

A detailed analysis of typical master curves reported in the literature for the dynamic modulus and compliance of unfilled polyuretane rubber and poly(n-octyl methacrylate), respectively, and for the transient modulus of styrene-butadiene rubber is performed. It is shown that the time-temperature superposition is not strictly obeyed, that is, the individual curves do not satisfy the scaling conditions with a translation path parallel to the horizontal axis. In fact, only a partial matching of the individual curves is obtained, on constructing the master curve, which can be described by a Maxwell. Finally, the meaning of the parameters obtained for the Maxwell element and for the constants of the Williams-Landel-Ferry equation is discussed. © 1991.

Registro:

Documento: Artículo
Título:Analysis of the master curve for the viscoelastic behaviour of polymers
Autor:Povolo, F.; Hermida, E.B.
Filiación:Comisión Nacional de Energia Atómica, Dto. Materiales, Au. Libertador 8250, 1429 Buenos Aires, Argentina
Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Dto. de Fisica. Pabellón I, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Palabras clave:Polymethyl Methacrylate; Polyurethanes; Rubber; Compliance; Dynamic Modulus; Poly(n-octyl-methacrylate); Unfilled Polyurethane Rubber; Polymers
Año:1991
Volumen:12
Número:1
Página de inicio:35
Página de fin:46
DOI: http://dx.doi.org/10.1016/0167-6636(91)90051-Z
Título revista:Mechanics of Materials
Título revista abreviado:Mech Mater
ISSN:01676636
CODEN:MSMSD
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01676636_v12_n1_p35_Povolo

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Citas:

---------- APA ----------
Povolo, F. & Hermida, E.B. (1991) . Analysis of the master curve for the viscoelastic behaviour of polymers. Mechanics of Materials, 12(1), 35-46.
http://dx.doi.org/10.1016/0167-6636(91)90051-Z
---------- CHICAGO ----------
Povolo, F., Hermida, E.B. "Analysis of the master curve for the viscoelastic behaviour of polymers" . Mechanics of Materials 12, no. 1 (1991) : 35-46.
http://dx.doi.org/10.1016/0167-6636(91)90051-Z
---------- MLA ----------
Povolo, F., Hermida, E.B. "Analysis of the master curve for the viscoelastic behaviour of polymers" . Mechanics of Materials, vol. 12, no. 1, 1991, pp. 35-46.
http://dx.doi.org/10.1016/0167-6636(91)90051-Z
---------- VANCOUVER ----------
Povolo, F., Hermida, E.B. Analysis of the master curve for the viscoelastic behaviour of polymers. Mech Mater. 1991;12(1):35-46.
http://dx.doi.org/10.1016/0167-6636(91)90051-Z