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Abstract:

The influence of internal and interfacial diffusion on catalyst deactivation by simultaneous sintering and poisoning is examined. The study focuses on the copper catalyst used in the water gas shift reaction (WGSR). It is found that catalyst life increases when internal and external poison diffusional resistance increases. Temperature reduces the total average activity but this effect is partially neutralized by the diffusional effects undergone by the reactants inside the pellet. © 1997 Elsevier Science B. V. All rights reserved.

Registro:

Documento: Artículo
Título:Catalyst decay by simultaneous sintering and poisoning: effects of intraparticle and interfacial gradients
Autor:Chocron, M.; Amadeo, N.; Laborde, M.
Filiación:A Departamento de Ingeniería Química, Universidad de Buenos Aires, Pabellón de Industrias, Ciudad Universitaria, (1428) Buenos Aires, Argentina
U. A. Q., Comisión Nacional de Energía Atómica, Buenos Aires, Argentina
Año:1997
Volumen:111
Página de inicio:311
Página de fin:318
Título revista:Studies in Surface Science and Catalysis
Título revista abreviado:Stud. Surf. Sci. Catal.
ISSN:01672991
CODEN:SSCTD
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672991_v111_n_p311_Chocron

Referencias:

  • Chocrón, M., Raffo Calderón, M.D.C., Amadeo, N.B., Laborde, M., (1996) Chem. Eng. Sci., 51, p. 683
  • Amadeo, N., Laborde, M., (1995) Int. J. Hydrogen Energy, 20, p. 949
  • Petersen, E., (1965); Wheeler, A., Catalysis, Vol, I.I., (1965) Chap., 2
  • Froment, G., Bischoff, K., Analysis, C.R., Design, Wiley, J., Sons, N.Y., (1979); Taylor, R., Krishna, R., Transfer, M.M., Wiley, J., Sons, N.Y., (1993); Salmi, T., Wärnå, J., (1991) Chem. Eng. Sci., 15, p. 715
  • Aparicio, M.L., Laborde, M., Amadeo, N.E., (1996) Información Tecnológica, 7, p. 29
  • Fuentes, G.A., (1985) Appl. Catal., 15, p. 33
  • González Velasco, J., Gutiérrez Ortiz, M., González Marcos, J., Amadeo, N., Laborde, M., Paz, M., (1992) Chem. Eng. Sci., 47, p. 1495

Citas:

---------- APA ----------
Chocron, M., Amadeo, N. & Laborde, M. (1997) . Catalyst decay by simultaneous sintering and poisoning: effects of intraparticle and interfacial gradients. Studies in Surface Science and Catalysis, 111, 311-318.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672991_v111_n_p311_Chocron [ ]
---------- CHICAGO ----------
Chocron, M., Amadeo, N., Laborde, M. "Catalyst decay by simultaneous sintering and poisoning: effects of intraparticle and interfacial gradients" . Studies in Surface Science and Catalysis 111 (1997) : 311-318.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672991_v111_n_p311_Chocron [ ]
---------- MLA ----------
Chocron, M., Amadeo, N., Laborde, M. "Catalyst decay by simultaneous sintering and poisoning: effects of intraparticle and interfacial gradients" . Studies in Surface Science and Catalysis, vol. 111, 1997, pp. 311-318.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672991_v111_n_p311_Chocron [ ]
---------- VANCOUVER ----------
Chocron, M., Amadeo, N., Laborde, M. Catalyst decay by simultaneous sintering and poisoning: effects of intraparticle and interfacial gradients. Stud. Surf. Sci. Catal. 1997;111:311-318.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672991_v111_n_p311_Chocron [ ]