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Abstract:

The dehydration behavior of copper(ii) bis (hydrogen o-phthalate)dihydrate is interpreted in terms of its crystal structure. Single crystal XRD data were used to derive important structural parameters. The TD of the anhydrous salt is also discussed in terms of proton transfer between adjacent anions. © 1993.

Registro:

Documento: Artículo
Título:Structure and reactivity of copper (II) carboxylates II. Copper (II) bis(hydrogen o-phthalate) dihydrate
Autor:Goeta, A.E.; Rigotti, G.; Sileo, E.E.; Blesa, M.A.
Filiación:Laboratorio de Cristalografia, Departamento de Física, Faculted de Ciencias Exactas, UMLP, Calle 47 y 115, 1900 La Plata, Argentina
Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon II, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Departamento Química de Reactores, Comisión Nacional de Energía Atómica, Avenida del Libertador 8250, 1429 Buenos Aires, Argentina
Palabras clave:Copper compounds; Crystal structure; Dehydration; Hydrates; Organometallics; Protons; Pyrolysis; Salts; X ray analysis; Copper(II) bis(hydrogen o-phthalate)dihydrate; Proton transfer; X-ray diffractometry; Solid electrolytes
Año:1993
Volumen:62
Número:3-4
Página de inicio:159
Página de fin:165
DOI: http://dx.doi.org/10.1016/0167-2738(93)90367-C
Título revista:Solid State Ionics
Título revista abreviado:Solid State Ionics
ISSN:01672738
CODEN:SSIOD
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672738_v62_n3-4_p159_Goeta

Referencias:

  • Sileo, Quinteros-Rivero, Rivero, Rigotti, Blesa, (1992) 12th Intern. Symp. Reactivity of Solids, , Madrid, Spain
  • Cingi, Guastini, Musatti, Nardelli, (1969) Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 25 B, p. 1833
  • Fair, (1990) MolEN: Enraf-Nonius Structure Determination System, , Version 1.0, Enraf-Nonius, Delft Instrument, The Netherlands
  • Sheldrick, SHELXS76 (1985) Program for the Solution of Crystal Structure, , Univ. Goettingen, Germany
  • Seldrick, SHELXS76 (1976) Program for Crystal Structure Determination, , Univ. Cambridge, UK
  • Johnson, ORTEP (1975) Report ORLN-3794, , Oak Ridge Nat. Lab, TN, USA
  • Cingi, Villa, Guastini, Nardelli, (1972) Gazz. Chim. Ital., 102, p. 1026
  • Sarchet, Loiseleur, (1973) Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 29 B, p. 1345
  • Sileo, Morando, Vedova, Blesa, (1989) Thermochim. Acta, 138, p. 233
  • Sileo, Morando, Blesa, (1989) Thermochim. Acta, 152, p. 299
  • Sileo, Morando, Baumgartner, Blesa, (1991) Thermochim. Acta, 184, p. 295
  • Carr, Galwey, (1986) Proc. R. Soc. London Scr. A, 404, p. 101. , 4th Ed
  • Galwey, (1990) React. Solids, 8, p. 211

Citas:

---------- APA ----------
Goeta, A.E., Rigotti, G., Sileo, E.E. & Blesa, M.A. (1993) . Structure and reactivity of copper (II) carboxylates II. Copper (II) bis(hydrogen o-phthalate) dihydrate. Solid State Ionics, 62(3-4), 159-165.
http://dx.doi.org/10.1016/0167-2738(93)90367-C
---------- CHICAGO ----------
Goeta, A.E., Rigotti, G., Sileo, E.E., Blesa, M.A. "Structure and reactivity of copper (II) carboxylates II. Copper (II) bis(hydrogen o-phthalate) dihydrate" . Solid State Ionics 62, no. 3-4 (1993) : 159-165.
http://dx.doi.org/10.1016/0167-2738(93)90367-C
---------- MLA ----------
Goeta, A.E., Rigotti, G., Sileo, E.E., Blesa, M.A. "Structure and reactivity of copper (II) carboxylates II. Copper (II) bis(hydrogen o-phthalate) dihydrate" . Solid State Ionics, vol. 62, no. 3-4, 1993, pp. 159-165.
http://dx.doi.org/10.1016/0167-2738(93)90367-C
---------- VANCOUVER ----------
Goeta, A.E., Rigotti, G., Sileo, E.E., Blesa, M.A. Structure and reactivity of copper (II) carboxylates II. Copper (II) bis(hydrogen o-phthalate) dihydrate. Solid State Ionics. 1993;62(3-4):159-165.
http://dx.doi.org/10.1016/0167-2738(93)90367-C