Artículo
Rusjan, M.; Sileo, E.E.; Cukiernik, F.D. "Thermal stability of mixed-valent diruthenium (II,III) carboxylates" (2003) Solid State Ionics. 159(3-4):389-396
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Abstract:
The thermal stability of mixed-valent diruthenium carboxylates, Ru2 II,III (O2CR)4X, where RCO2 - are the equatorial carboxylates and X- is the axial ligand (halide or carboxylate anion) was investigated. The nature of the axial ligands determines two decomposition pathways, while the equatorial carboxylate plays a minor role. The general behavior involves the reduction of the bimetallic center to Ru0. The halocomplexes (X- = halide) decompose in just one complex step. The pentacarboxylates (X- = CH3(CH2)n-2CO2 -) have a two-step mechanism being the intermediate product Ru2 II,II (O2C(CH2)n-2CH3)4. The influence of the liquid crystalline phase was explored. © 2003 Elsevier Science B.V. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Thermal stability of mixed-valent diruthenium (II,III) carboxylates |
| Autor: | Rusjan, M.; Sileo, E.E.; Cukiernik, F.D. |
| Filiación: | ICI, Univ. Nacional de General Sarmiento, Roca 850, 1663 San Miguel, Buenos Aires, Argentina INQUIMAE, DQIAyQF, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina INQUIMAE, FCEyN, Pabellón 2, C1428EHA Buenos Aires, Argentina |
| Palabras clave: | Metallomesogens; Ruthenium carboxylates; Thermal stability; Bimetals; Decomposition; Liquid crystals; Thermodynamic stability; Ligands; Ruthenium compounds |
| Año: | 2003 |
| Volumen: | 159 |
| Número: | 3-4 |
| Página de inicio: | 389 |
| Página de fin: | 396 |
| DOI: | http://dx.doi.org/10.1016/S0167-2738(03)00079-1 |
| Título revista: | Solid State Ionics |
| Título revista abreviado: | Solid State Ionics |
| ISSN: | 01672738 |
| CODEN: | SSIOD |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672738_v159_n3-4_p389_Rusjan |
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Citas:
---------- APA ----------
Rusjan, M., Sileo, E.E. & Cukiernik, F.D. (2003) . Thermal stability of mixed-valent diruthenium (II,III) carboxylates. Solid State Ionics, 159(3-4), 389-396.http://dx.doi.org/10.1016/S0167-2738(03)00079-1
---------- CHICAGO ----------
Rusjan, M., Sileo, E.E., Cukiernik, F.D. "Thermal stability of mixed-valent diruthenium (II,III) carboxylates" . Solid State Ionics 159, no. 3-4 (2003) : 389-396.http://dx.doi.org/10.1016/S0167-2738(03)00079-1
---------- MLA ----------
Rusjan, M., Sileo, E.E., Cukiernik, F.D. "Thermal stability of mixed-valent diruthenium (II,III) carboxylates" . Solid State Ionics, vol. 159, no. 3-4, 2003, pp. 389-396.http://dx.doi.org/10.1016/S0167-2738(03)00079-1
---------- VANCOUVER ----------
Rusjan, M., Sileo, E.E., Cukiernik, F.D. Thermal stability of mixed-valent diruthenium (II,III) carboxylates. Solid State Ionics. 2003;159(3-4):389-396.http://dx.doi.org/10.1016/S0167-2738(03)00079-1
