Abstract:
The acidity of Cr(III) and Fe(III) (hydr)oxides in water was studied. The experimental point-of zero-charge condition of the particles differs from that of the solution due to solvation effects on ionic adsorption; the surface charge is attributed to polymeric surface complexes. A simple model for the acidity of solid solutions MxR1-xO is presented and contrasted with the complex behavior of ilmenite, which is influenced by the kinetics of FeO leaching and the acid-base properties of the leached layer.
Registro:
Documento: |
Artículo
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Título: | Structure and reactivity of colloidal metal oxide particles immersed in water |
Autor: | Blesa, M.A.; Magaz, G.; Salfity, J.A.; Weisz, A.D. |
Filiación: | Unidad de Actividad Química, Comn. Nac. de Ener. Atómica, Avenida del Libertador 8250, 1429 Buenos Aires, Argentina INQUIMAE, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina Universidad Nacional del Sur, Bahía Blanca, Argentina
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Palabras clave: | Aqueous suspensions; Leached layer; Metal oxides; Particles; Surface acidity; Adsorption; Colloids; Leaching; pH effects; Solid solutions; Colloidal metal oxide particles; Chromium compounds |
Año: | 1997
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Volumen: | 101-103
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Número: | PART 1
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Página de inicio: | 1235
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Página de fin: | 1241
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Título revista: | Solid State Ionics
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Título revista abreviado: | Solid State Ionics
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ISSN: | 01672738
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CODEN: | SSIOD
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672738_v101-103_nPART1_p1235_Blesa |
Referencias:
- Blesa, M.A., Morando, P.J., Regazzoni, A.E., (1994) Chemical Dissolution of Metal Oxides, , CRC Press, Boca Raton, FL, Ch. 17
- Magaz, G., Weisz, A.D., Blesa, M.A., to be published; Kittaka, S., Fujinaga, R., Morishige, K., Morimoto, T., (1984) J. Colloid Interface Sci., 102, p. 453
- Ohshima, H., (1994) J. Colloid Interface Sci., 168, p. 269
- Regazzoni, A.E., Blesa, M.A., Maroto, A.J.G., (1988) J. Colloid Interface Sci., 122, p. 315
- Regazzoni, A.E., Blesa, M.A., Maroto, A.J.G., (1983) J. Colloid Interface Sci., 91, p. 560
- Blesa, M.A., Maroto, A.J.G., Regazzoni, A.E., (1990) J. Colloid Interface Sci., 140, p. 287
- Pauling, L., (1960) The Nature of the Chemical Bond, 3rd Ed., , Cornell University Press, Ithaca, NY
- Parks, G.A., (1965) Chem. Rev., 65, p. 177
- Yoon, R.H., Salman, T., Donnay, G., (1979) J. Colloid Interface Sci., 70, p. 483
- Bleam, W.F., (1993) J. Colloid Interface Sci., 159, p. 312
- Hierastra, T., Van Riemsdijk, W.H., Bolt, G.H., (1989) J. Colloid Interface Sci., 133, p. 91
- Hiemstra, T., De Wit, J.C.M., Van Riemsdijk, W.H., (1989) J. Colloid Interface Sci., 133, p. 105
- Sverjensky, D.A., (1994) Geochim. Cosmochim. Acta, 58, p. 3123
- Salfity, J.A., Regazzoni, A.E., Blesa, M.A., unpublished; Imahashi, M., Takamatsu, N., (1976) Bull. Chem. Soc. Jpn., 49, p. 1549
- Girgin, I., (1990) Hydrometallurgy, 24, p. 127
- White, A.F., Peterson, M.L., Hochella M.F., Jr., (1994) Geochim. Cosmochim. Acta, 58, p. 1859
- Castro, P.A., Vago, E.R., Calvo, E.J., (1996) J. Chem. Soc. Faraday Trans., 92, p. 3371
- Cicerone, D.S., Regazzoni, A.E., Blesa, M.A., (1992) J. Colloid Interface Sci., 154, p. 423
Citas:
---------- APA ----------
Blesa, M.A., Magaz, G., Salfity, J.A. & Weisz, A.D.
(1997)
. Structure and reactivity of colloidal metal oxide particles immersed in water. Solid State Ionics, 101-103(PART 1), 1235-1241.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672738_v101-103_nPART1_p1235_Blesa [ ]
---------- CHICAGO ----------
Blesa, M.A., Magaz, G., Salfity, J.A., Weisz, A.D.
"Structure and reactivity of colloidal metal oxide particles immersed in water"
. Solid State Ionics 101-103, no. PART 1
(1997) : 1235-1241.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672738_v101-103_nPART1_p1235_Blesa [ ]
---------- MLA ----------
Blesa, M.A., Magaz, G., Salfity, J.A., Weisz, A.D.
"Structure and reactivity of colloidal metal oxide particles immersed in water"
. Solid State Ionics, vol. 101-103, no. PART 1, 1997, pp. 1235-1241.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672738_v101-103_nPART1_p1235_Blesa [ ]
---------- VANCOUVER ----------
Blesa, M.A., Magaz, G., Salfity, J.A., Weisz, A.D. Structure and reactivity of colloidal metal oxide particles immersed in water. Solid State Ionics. 1997;101-103(PART 1):1235-1241.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01672738_v101-103_nPART1_p1235_Blesa [ ]