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Abstract:

Biological substrates have been introduced in Analytical Chemistry to encourage the development of environment-friendly methodologies. This kind of substrates offers advantages such as low cost, very simple production and biodegradability. Moreover, they are considered highly efficient materials for extraction and separation of elemental species.The current article reviews the applications of biological substrates in elemental preconcentration and speciation analysis, with emphasis in the latest analytical methodologies developed in this field. Batch and on-line microextraction techniques, based on biological substrates are presented and discussed. The applications of immobilized biological substrates are also commented in this work. Special attention is given to the novel immobilization of these substrates on nanomaterials and nanoparticles to develop solid phase extraction techniques. A comparison of methods using biological substrates in terms of analytical performance is provided. Finally, future trends, developments and challenges related to the use of biological substrates for trace metal determination are discussed. © 2016 Elsevier B.V.

Registro:

Documento: Artículo
Título:Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis
Autor:Escudero, L.B.; Maniero, M.Á.; Agostini, E.; Smichowski, P.N.
Filiación:Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires, Argentina
Laboratory of Analytical Chemistry for Research and Development (QUIANID), Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Cuyo, Padre J. Contreras 1300, Parque Gral. San Martín, Mendoza, Argentina
Departamento de Biología Molecular, FCEFQyN, Universidad Nacional de Río Cuarto, Córdoba, Argentina
Comisión Nacional de Energía Atómica, Gerencia Química, Buenos Aires, Argentina
Palabras clave:Biological substrates; Biosorption; Metal; Preconcentration; Speciation; Biodegradability; Biological materials; Biosorption; Chemical analysis; Metals; Phase separation; Substrates; Trace analysis; Trace elements; Analytical methodology; Analytical performance; Biological substrates; Comparison of methods; On-line microextraction; Pre-concentration; Solid phase extraction techniques; Speciation; Extraction; heavy metal; nanomaterial; nanoparticle; trace element; adsorption; agricultural waste; biomass; biosorption; chemical modification; complex formation; filamentous fungus; food analysis; fungus; Gram negative bacterium; Gram positive bacterium; green chemistry; heavy metal removal; ion exchange; metal recovery; micromycete; nonhuman; oxidation reduction reaction; plant seed; precipitation; priority journal; Review; seed husk; solid phase extraction; yeast
Año:2016
Volumen:80
Página de inicio:531
Página de fin:546
DOI: http://dx.doi.org/10.1016/j.trac.2016.04.002
Título revista:TrAC - Trends in Analytical Chemistry
Título revista abreviado:TrAC Trends Anal. Chem.
ISSN:01659936
CODEN:TTAED
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01659936_v80_n_p531_Escudero

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Citas:

---------- APA ----------
Escudero, L.B., Maniero, M.Á., Agostini, E. & Smichowski, P.N. (2016) . Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis. TrAC - Trends in Analytical Chemistry, 80, 531-546.
http://dx.doi.org/10.1016/j.trac.2016.04.002
---------- CHICAGO ----------
Escudero, L.B., Maniero, M.Á., Agostini, E., Smichowski, P.N. "Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis" . TrAC - Trends in Analytical Chemistry 80 (2016) : 531-546.
http://dx.doi.org/10.1016/j.trac.2016.04.002
---------- MLA ----------
Escudero, L.B., Maniero, M.Á., Agostini, E., Smichowski, P.N. "Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis" . TrAC - Trends in Analytical Chemistry, vol. 80, 2016, pp. 531-546.
http://dx.doi.org/10.1016/j.trac.2016.04.002
---------- VANCOUVER ----------
Escudero, L.B., Maniero, M.Á., Agostini, E., Smichowski, P.N. Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis. TrAC Trends Anal. Chem. 2016;80:531-546.
http://dx.doi.org/10.1016/j.trac.2016.04.002