Abstract:
We introduce a new caged glutamate, based in a ruthenium bipyridyl core, that undergoes heterolytic cleavage after irradiation with visible light with wavelengths up to 532. nm, yielding free glutamate in less than 50. ns. Glutamate photorelease occurs also efficiently following two-photon (2P) excitation at 800. nm, and has a functional cross section of 0.14 GM. © 2009 Elsevier Inc.
Registro:
Documento: |
Artículo
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Título: | A fast ruthenium polypyridine cage complex photoreleases glutamate with visible or IR light in one and two photon regimes |
Autor: | Salierno, M.; Marceca, E.; Peterka, D.S.; Yuste, R.; Etchenique, R. |
Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina Howard Hughes Medical Institute, Department of Biological Sciences, Columbia University, New York, NY 10027, United States
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Palabras clave: | Caged compounds; Glutamate; Neuron; Phototriggers; Ruthenium; Two photon; glutamic acid; ruthenium complex; ruthenium derivative; ruthenium polypyridine; unclassified drug; animal tissue; article; chemical structure; complex formation; controlled study; infrared radiation; mouse; nonhuman; photolysis; photon; proton transport; quantum chemistry; Animals; Glutamic Acid; Infrared Rays; Light; Mice; Mice, Inbred C57BL; Molecular Structure; Neurons; Photic Stimulation; Photons; Ruthenium |
Año: | 2010
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Volumen: | 104
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Número: | 4
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Página de inicio: | 418
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Página de fin: | 422
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DOI: |
http://dx.doi.org/10.1016/j.jinorgbio.2009.12.004 |
Título revista: | Journal of Inorganic Biochemistry
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Título revista abreviado: | J. Inorg. Biochem.
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ISSN: | 01620134
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CODEN: | JIBID
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CAS: | glutamic acid, 11070-68-1, 138-15-8, 56-86-0, 6899-05-4; Glutamic Acid, 56-86-0; Ruthenium, 7440-18-8
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01620134_v104_n4_p418_Salierno |
Referencias:
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Citas:
---------- APA ----------
Salierno, M., Marceca, E., Peterka, D.S., Yuste, R. & Etchenique, R.
(2010)
. A fast ruthenium polypyridine cage complex photoreleases glutamate with visible or IR light in one and two photon regimes. Journal of Inorganic Biochemistry, 104(4), 418-422.
http://dx.doi.org/10.1016/j.jinorgbio.2009.12.004---------- CHICAGO ----------
Salierno, M., Marceca, E., Peterka, D.S., Yuste, R., Etchenique, R.
"A fast ruthenium polypyridine cage complex photoreleases glutamate with visible or IR light in one and two photon regimes"
. Journal of Inorganic Biochemistry 104, no. 4
(2010) : 418-422.
http://dx.doi.org/10.1016/j.jinorgbio.2009.12.004---------- MLA ----------
Salierno, M., Marceca, E., Peterka, D.S., Yuste, R., Etchenique, R.
"A fast ruthenium polypyridine cage complex photoreleases glutamate with visible or IR light in one and two photon regimes"
. Journal of Inorganic Biochemistry, vol. 104, no. 4, 2010, pp. 418-422.
http://dx.doi.org/10.1016/j.jinorgbio.2009.12.004---------- VANCOUVER ----------
Salierno, M., Marceca, E., Peterka, D.S., Yuste, R., Etchenique, R. A fast ruthenium polypyridine cage complex photoreleases glutamate with visible or IR light in one and two photon regimes. J. Inorg. Biochem. 2010;104(4):418-422.
http://dx.doi.org/10.1016/j.jinorgbio.2009.12.004