Artículo

Martínez-Gómez, F.; Mansilla, A.; Matsuhiro, B.; Matulewicz, M.C.; Troncoso-Valenzuela, M.A. "Chiroptical characterization of homopolymeric block fractions in alginates" (2016) Carbohydrate Polymers. 146:90-101
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Abstract:

Homopolymannuronic and homopolyguluronic fractions were obtained by partial hydrolysis of the alkaline extracts from the brown seaweeds Ascoseira mirabilis, Desmarestia menziessi, Desmarestia ligulata and Durvillaea sp. collected in southern Chile. Full characterization of the fractions was achieved by FT-IR and NMR spectroscopy. Total hydrolysis with 90% formic acid of the homopolymeric fractions allowed the preparation of mannuronic and guluronic acids. Both monomers and homopolymeric fractions as neutral salts were studied by CD and ORD. Chiroptical spectra were similar in shape and sign to those previously published in the literature, and permitted to assign D configuration to mannuronic acid and L configuration to guluronic acid in alginic acids. Specific optical rotation values at the sodium D light for the homopolymannuronic (∼-100°) and homopolyguluronic (∼-110°) acid fractions were obtained. These high negative values are proposed for the assignment of the absolute configuration of monomers in homopolymeric fractions. © 2016 Elsevier Ltd. All rights reserved.

Registro:

Documento: Artículo
Título:Chiroptical characterization of homopolymeric block fractions in alginates
Autor:Martínez-Gómez, F.; Mansilla, A.; Matsuhiro, B.; Matulewicz, M.C.; Troncoso-Valenzuela, M.A.
Filiación:Departamento de Ciencias del Ambiente, Facultad de Química y Biología, Universidad de Santiago de Chile, Av. Libertador B. O'Higgins 3363, Santiago, Chile
Laboratorio de Macroalgas Antárticas y Subantárticas, Universidad de Magallanes, Instituto de Ecología y Biodiversidad, Av. Bulnes 1465, Punta Arenas, Chile
Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, Buenos Aires, Argentina
Laboratorio de Química de Productos Naturales, Departamento de Botánica, Facultad de Ciencias Naturales y Oceanografía, Universidad de Concepción, Víctor Lamas 1290, Concepción, Chile
Palabras clave:Alginate; Circular dichroism; Homopolyguluronic acid; Homopolymannuronic acid; Optical rotatory dispersion; Specific optical rotation; Alginate; Dichroism; Hydrolysis; Monomers; Nuclear magnetic resonance spectroscopy; Absolute configuration; Ft-ir and nmr spectroscopies; Guluronic acid; Mannuronic acids; Negative values; Optical rotatory dispersion; Partial hydrolysis; Specific optical rotations; Optical rotation; alginic acid; polymer; brown alga; chemistry; infrared spectroscopy; nuclear magnetic resonance spectroscopy; Alginates; Magnetic Resonance Spectroscopy; Phaeophyta; Polymers; Spectroscopy, Fourier Transform Infrared
Año:2016
Volumen:146
Página de inicio:90
Página de fin:101
DOI: http://dx.doi.org/10.1016/j.carbpol.2016.03.047
Título revista:Carbohydrate Polymers
Título revista abreviado:Carbohydr Polym
ISSN:01448617
CODEN:CAPOD
CAS:alginic acid, 28961-37-7, 29894-36-8, 9005-32-7, 9005-38-3; Alginates; Polymers
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01448617_v146_n_p90_MartinezGomez

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Citas:

---------- APA ----------
Martínez-Gómez, F., Mansilla, A., Matsuhiro, B., Matulewicz, M.C. & Troncoso-Valenzuela, M.A. (2016) . Chiroptical characterization of homopolymeric block fractions in alginates. Carbohydrate Polymers, 146, 90-101.
http://dx.doi.org/10.1016/j.carbpol.2016.03.047
---------- CHICAGO ----------
Martínez-Gómez, F., Mansilla, A., Matsuhiro, B., Matulewicz, M.C., Troncoso-Valenzuela, M.A. "Chiroptical characterization of homopolymeric block fractions in alginates" . Carbohydrate Polymers 146 (2016) : 90-101.
http://dx.doi.org/10.1016/j.carbpol.2016.03.047
---------- MLA ----------
Martínez-Gómez, F., Mansilla, A., Matsuhiro, B., Matulewicz, M.C., Troncoso-Valenzuela, M.A. "Chiroptical characterization of homopolymeric block fractions in alginates" . Carbohydrate Polymers, vol. 146, 2016, pp. 90-101.
http://dx.doi.org/10.1016/j.carbpol.2016.03.047
---------- VANCOUVER ----------
Martínez-Gómez, F., Mansilla, A., Matsuhiro, B., Matulewicz, M.C., Troncoso-Valenzuela, M.A. Chiroptical characterization of homopolymeric block fractions in alginates. Carbohydr Polym. 2016;146:90-101.
http://dx.doi.org/10.1016/j.carbpol.2016.03.047