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Abstract:

Biodegradable and non-retrogradable starch-glycerol based films were obtained using citric acid (CA) as crosslinking agent at 75 °C. This material allowed decreasing water vapor permeability (WVP) more than 35%, remained amorphous for at least 45 days as a result of the network formed by the CA that avoided starch retrogradation and maintained the degradability in compost, occurring only six days after the films without citric acid. A simulation of the gelatinization process of starch-glycerol with and without CA, using a differential thermal analysis device, showed that the system with CA completed the gelatinization 5 °C before than the other and, CA first reacted with glycerol and then starch-glycerol-CA reaction occurred. The temperature at which the gelatinization process was carried out was critical to obtain the best results. An increase of gelatinization process temperature at 85 °C in system with CA, led to a worsening on WVP and its integrity after a swelling process with dimethylsulphoxide (DMSO), compared to the films processed at 75 °C. © 2015 Elsevier Ltd.

Registro:

Documento: Artículo
Título:Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent
Autor:Seligra, P.G.; Medina Jaramillo, C.; Famá, L.; Goyanes, S.
Filiación:LP and MC, Dep. de Física - IFIBA, CONICET, FCEyN, UBA, Ciudad Universitaria, CABA, 1428, Argentina
Instituto de Tecnología en Polímeros y Nanotecnología ITPN (UBA-CONICET), FCEyN, UBA, Av. Las Heras 2214, CABA, C1127AAQ, Argentina
Palabras clave:Biodegradability; Biodegradable edible films; Citric acid; Crosslinking; Starch; Amorphous films; Biodegradability; Biodegradation; Citric acid; Composting; Differential thermal analysis; Gelation; Glycerol; Starch; Thermoanalysis; Cross linking agents; Degradability; Edible films; Process temperature; Starch retrogradation; Swelling process; Water vapor permeability; Crosslinking; citric acid; cross linking reagent; dimethyl sulfoxide; glycerol; starch; water; bioremediation; chemistry; infrared spectroscopy; microbiology; permeability; temperature; thermogravimetry; Biodegradation, Environmental; Citric Acid; Cross-Linking Reagents; Dimethyl Sulfoxide; Glycerol; Permeability; Soil Microbiology; Spectroscopy, Fourier Transform Infrared; Starch; Temperature; Thermogravimetry; Water
Año:2016
Volumen:138
Página de inicio:66
Página de fin:74
DOI: http://dx.doi.org/10.1016/j.carbpol.2015.11.041
Título revista:Carbohydrate Polymers
Título revista abreviado:Carbohydr Polym
ISSN:01448617
CODEN:CAPOD
CAS:citric acid, 126-44-3, 5949-29-1, 77-92-9, 8002-14-0; dimethyl sulfoxide, 67-68-5; glycerol, 56-81-5; starch, 9005-25-8, 9005-84-9; water, 7732-18-5; Citric Acid; Cross-Linking Reagents; Dimethyl Sulfoxide; Glycerol; Starch; Water
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01448617_v138_n_p66_Seligra

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Citas:

---------- APA ----------
Seligra, P.G., Medina Jaramillo, C., Famá, L. & Goyanes, S. (2016) . Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent. Carbohydrate Polymers, 138, 66-74.
http://dx.doi.org/10.1016/j.carbpol.2015.11.041
---------- CHICAGO ----------
Seligra, P.G., Medina Jaramillo, C., Famá, L., Goyanes, S. "Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent" . Carbohydrate Polymers 138 (2016) : 66-74.
http://dx.doi.org/10.1016/j.carbpol.2015.11.041
---------- MLA ----------
Seligra, P.G., Medina Jaramillo, C., Famá, L., Goyanes, S. "Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent" . Carbohydrate Polymers, vol. 138, 2016, pp. 66-74.
http://dx.doi.org/10.1016/j.carbpol.2015.11.041
---------- VANCOUVER ----------
Seligra, P.G., Medina Jaramillo, C., Famá, L., Goyanes, S. Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent. Carbohydr Polym. 2016;138:66-74.
http://dx.doi.org/10.1016/j.carbpol.2015.11.041