Artículo

Perez Recalde, M.; Canelón, D.J.; Compagnone, R.S.; Matulewicz, M.C.; Cerezo, A.S.; Ciancia, M. "Carrageenan and agaran structures from the red seaweed Gymnogongrus tenuis" (2016) Carbohydrate Polymers. 136:1370-1378
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Abstract:

The galactan system biosynthesized by the red seaweed Gymnogongrus tenuis (Phyllophoraceae) is constituted by major amounts of κ/ι-carrageenans, with predominance of ι-structures, which were isolated by extraction with hot water in high yield (∼45%). A small amount of non-cyclized carrageenans mostly of the ν-type was also obtained. Besides, 12% of these galactans are agaran structures, which were present in major quantities in the room temperature water extracts, but they were also found in the hot water extract. They are constituted by 3-linked β-d-galactose units partially substituted on C-6 with sulfate or single stubs of β-d-xylose and 4-linked residues that comprise α-l-galactose units partially sulfated or methoxylated on C-3 or sulfated on C-3 and C-6 and 3,6-anhydro-α-l-galactose. Related structural patterns were previously found for agarans synthesized by other carrageenophytes. Results presented here show that these agarans are low molecular weight molecules independent of the carrageenan structures, with strong interactions between them. © 2015 Published by Elsevier Ltd.

Registro:

Documento: Artículo
Título:Carrageenan and agaran structures from the red seaweed Gymnogongrus tenuis
Autor:Perez Recalde, M.; Canelón, D.J.; Compagnone, R.S.; Matulewicz, M.C.; Cerezo, A.S.; Ciancia, M.
Filiación:Cátedra de Química de Biomoléculas, Departamento de Biología Aplicada y Alimentos, Facultad de Agronomía, Universidad de Buenos Aires, Av. San Martín 4453, Buenos Aires, 1417, Argentina
Escuela de Bioanálisis, Facultad de Medicina, Universidad Central de Venezuela, Ciudad Universitaria, Los Chaguaramos, Av. Carlos Raúl Villanueva, Caracas, 1051, Venezuela
Escuela de Química, Facultad de Ciencias, Universidad Central de Venezuela, Ciudad Universitaria, Los Chaguaramos, Av. Paseo de los Ilustres, Caracas, 1450, Venezuela
Departamento de Química Orgánica - CIHIDECAR (CONICET-UBA), Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, 1428, Argentina
Palabras clave:Agaran; Carrageenan; Polysaccharide structure; Red seaweed; Sulfated galactan; Polysaccharides; Seaweed; Water; Xylose; Agaran; Carrageenans; Polysaccharide structure; Red seaweeds; Sulfated galactans; Extraction; carrageenan; galactan; water; chemistry; heat; isolation and purification; red alga; seaweed; Carrageenan; Galactans; Hot Temperature; Rhodophyta; Seaweed; Water
Año:2016
Volumen:136
Página de inicio:1370
Página de fin:1378
DOI: http://dx.doi.org/10.1016/j.carbpol.2015.10.007
Título revista:Carbohydrate Polymers
Título revista abreviado:Carbohydr Polym
ISSN:01448617
CODEN:CAPOD
CAS:carrageenan, 9000-07-1, 9049-05-2, 9061-82-9, 9064-57-7; galactan, 39300-87-3, 9037-55-2; water, 7732-18-5; Carrageenan; Galactans; Water
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01448617_v136_n_p1370_PerezRecalde

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Citas:

---------- APA ----------
Perez Recalde, M., Canelón, D.J., Compagnone, R.S., Matulewicz, M.C., Cerezo, A.S. & Ciancia, M. (2016) . Carrageenan and agaran structures from the red seaweed Gymnogongrus tenuis. Carbohydrate Polymers, 136, 1370-1378.
http://dx.doi.org/10.1016/j.carbpol.2015.10.007
---------- CHICAGO ----------
Perez Recalde, M., Canelón, D.J., Compagnone, R.S., Matulewicz, M.C., Cerezo, A.S., Ciancia, M. "Carrageenan and agaran structures from the red seaweed Gymnogongrus tenuis" . Carbohydrate Polymers 136 (2016) : 1370-1378.
http://dx.doi.org/10.1016/j.carbpol.2015.10.007
---------- MLA ----------
Perez Recalde, M., Canelón, D.J., Compagnone, R.S., Matulewicz, M.C., Cerezo, A.S., Ciancia, M. "Carrageenan and agaran structures from the red seaweed Gymnogongrus tenuis" . Carbohydrate Polymers, vol. 136, 2016, pp. 1370-1378.
http://dx.doi.org/10.1016/j.carbpol.2015.10.007
---------- VANCOUVER ----------
Perez Recalde, M., Canelón, D.J., Compagnone, R.S., Matulewicz, M.C., Cerezo, A.S., Ciancia, M. Carrageenan and agaran structures from the red seaweed Gymnogongrus tenuis. Carbohydr Polym. 2016;136:1370-1378.
http://dx.doi.org/10.1016/j.carbpol.2015.10.007