Artículo

Barahona, T.; Prado, H.J.; Bonelli, P.R.; Cukierman, A.L.; Fissore, E.L.; Gerschenson, L.N.; Matulewicz, M.C. "Cationization of kappa- and iota-carrageenan - Characterization and properties of amphoteric polysaccharides" (2015) Carbohydrate Polymers. 126:70-77
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Abstract:

Commercial kappa- and iota carrageenans were cationized with 3-chloro-2-hydroxypropyltrimethylammonium chloride in aqueous sodium hydroxide solution. For kappa-carrageenan three derivatives with different degrees of substitution were obtained. Native and amphoteric kappa-carrageenans were characterized by NMR and infrared spectroscopy, scanning electron and atomic force microscopy; methanolysis products were studied by electrospray ionization mass spectrometry. Young moduli and the strain at break of films, differential scanning calorimetry, rheological and flocculation behavior were also evaluated; the native and the amphoteric derivatives showed different and interesting properties. Cationization of iota-carrageenan was more difficult, indicating as it was previously observed for agarose, that substitution starts preferentially on the 2-position of 3,6-anhydrogalactose residues; in iota-carrageenan this latter unit is sulfated. © 2015 Elsevier Ltd.

Registro:

Documento: Artículo
Título:Cationization of kappa- and iota-carrageenan - Characterization and properties of amphoteric polysaccharides
Autor:Barahona, T.; Prado, H.J.; Bonelli, P.R.; Cukierman, A.L.; Fissore, E.L.; Gerschenson, L.N.; Matulewicz, M.C.
Filiación:Departamento de Química Orgánica - CIHIDECAR (CONICET-UBA), Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Buenos Aires, 1428EGA, Argentina
PINMATE - Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, 1428EGA, Argentina
Cátedra de Tecnología Farmacéutica II, Departamento de Tecnología Farmacéutica, Universidad de Buenos Aires, Junín 956, Buenos Aires, 1113AAD, Argentina
Departamento de Industrias - CONICET, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, 1428EGA, Argentina
Palabras clave:3-Chloro-2-hydroxypropyltrimethylammonium chloride; Amphoteric polysaccharides; Cationization; Iota-carrageenan; Kappa-carrageenan; Atomic force microscopy; Chlorine compounds; Differential scanning calorimetry; Electrospray ionization; Infrared spectroscopy; Mass spectrometry; 3-chloro-2-hydroxypropyltrimethylammonium chloride; Cationization; Degrees of substitution; Electrospray ionization mass spectrometry; Iota-carrageenan; Kappa carrageenan; Scanning electrons; Sodium hydroxide solutions; Polysaccharides; (3-chloro-2-hydroxypropyl)trimethylammonium chloride; 3,6-anhydrogalactose; carrageenan; cation; galactose; polysaccharide; propanol; quaternary ammonium derivative; sepharose; analogs and derivatives; atomic force microscopy; chemistry; electrospray mass spectrometry; flow kinetics; nuclear magnetic resonance spectroscopy; Young modulus; analogs and derivatives; Carrageenan; Cations; chemistry; chemistry; chemistry; chemistry; chemistry; chemistry; chemistry; Elastic Modulus; Galactose; Magnetic Resonance Spectroscopy; Microscopy, Atomic Force; Polysaccharides; Propanols; Quaternary Ammonium Compounds; Rheology; Sepharose; Spectrometry, Mass, Electrospray Ionization
Año:2015
Volumen:126
Página de inicio:70
Página de fin:77
DOI: http://dx.doi.org/10.1016/j.carbpol.2015.02.053
Título revista:Carbohydrate Polymers
Título revista abreviado:Carbohydr Polym
ISSN:01448617
CODEN:CAPOD
CAS:carrageenan, 9000-07-1, 9049-05-2, 9061-82-9, 9064-57-7; galactose, 26566-61-0, 50855-33-9, 59-23-4; propanol, 62309-51-7, 71-23-8; sepharose, 61970-08-9; (3-chloro-2-hydroxypropyl)trimethylammonium chloride; 3,6-anhydrogalactose; Carrageenan; Cations; Galactose; Polysaccharides; Propanols; Quaternary Ammonium Compounds; Sepharose
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01448617_v126_n_p70_Barahona

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Citas:

---------- APA ----------
Barahona, T., Prado, H.J., Bonelli, P.R., Cukierman, A.L., Fissore, E.L., Gerschenson, L.N. & Matulewicz, M.C. (2015) . Cationization of kappa- and iota-carrageenan - Characterization and properties of amphoteric polysaccharides. Carbohydrate Polymers, 126, 70-77.
http://dx.doi.org/10.1016/j.carbpol.2015.02.053
---------- CHICAGO ----------
Barahona, T., Prado, H.J., Bonelli, P.R., Cukierman, A.L., Fissore, E.L., Gerschenson, L.N., et al. "Cationization of kappa- and iota-carrageenan - Characterization and properties of amphoteric polysaccharides" . Carbohydrate Polymers 126 (2015) : 70-77.
http://dx.doi.org/10.1016/j.carbpol.2015.02.053
---------- MLA ----------
Barahona, T., Prado, H.J., Bonelli, P.R., Cukierman, A.L., Fissore, E.L., Gerschenson, L.N., et al. "Cationization of kappa- and iota-carrageenan - Characterization and properties of amphoteric polysaccharides" . Carbohydrate Polymers, vol. 126, 2015, pp. 70-77.
http://dx.doi.org/10.1016/j.carbpol.2015.02.053
---------- VANCOUVER ----------
Barahona, T., Prado, H.J., Bonelli, P.R., Cukierman, A.L., Fissore, E.L., Gerschenson, L.N., et al. Cationization of kappa- and iota-carrageenan - Characterization and properties of amphoteric polysaccharides. Carbohydr Polym. 2015;126:70-77.
http://dx.doi.org/10.1016/j.carbpol.2015.02.053