Abstract:
Various O-acyl derivatives of 2-mercaptoethanol have been obtained enzymatically by lipase-catalyzed chemospecific esterification reactions of the substrate and several aliphatic carboxylic acid ethyl esters. © 1994 Kluwer Academic Publishers.
Registro:
Documento: |
Artículo
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Título: | An improved procedure for chemospecific acylation of 2-mercaptoethanol by lipase-catalyzed transesterification |
Autor: | Baldessari, A.; Iglesias, L.E.; Gros, E.G. |
Filiación: | Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, Buenos Aires, 1428, Argentina
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Palabras clave: | aliphatic carboxylic acid; ester; mercaptoethanol; solvent; triacylglycerol lipase; acylation; article; catalysis; chemical reaction; esterification; temperature |
Año: | 1994
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Volumen: | 16
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Número: | 5
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Página de inicio: | 479
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Página de fin: | 484
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DOI: |
http://dx.doi.org/10.1007/BF01023329 |
Título revista: | Biotechnology Letters
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Título revista abreviado: | Biotechnol Lett
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ISSN: | 01415492
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CODEN: | BILED
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01415492_v16_n5_p479_Baldessari |
Referencias:
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- Baldessari, A., Iglesias, L. E. and Gros, E. G. (1992). J. Chem. Res. (S), 204–205; Baldessari, A., Iglesias, L. E. and Gros, E. G. (1993), J. Chem. Res. (S), 382–383; Colombo, D., Ronchetti, F., Scala, A., Toma, L., Enzymic Acylation of Methyl D- and L-Glucopyranosides and 6-Deoxy-glucopyranosides (1992) Journal of Carbohydrate Chemistry, 11, pp. 89-94
- Chen, C.S., Sih, C.J., General Aspects and Optimization of Enantioselective Biocatalysis in Organic Solvents: The Use of Lipases[New Synthetic Methods(76)] (1989) Angewandte Chemie International Edition in English, 28, pp. 695-707
- Cheng, H., Zhao, G., Yan, D., (1992) J. Polym. Sci. Part A: Polymer Chem., 30, pp. 2181-2185
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- Kanerva, L., Rahiala, K., Vanttinen, E., (1992) J. Chem. Soc. Perkin Trans., 1, pp. 1759-1762
- Klibanov, A. M. (1986). CHEMTECH, 354–359; Klibanov, A.M., (1989) TIBS, 14, pp. 141-144
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- Manzaen, V.E., Korshiinov, M.A., Rodidnova, N.M., (1975) Osnovn. Org. Sint. Neftekhim., 4, pp. 79-83
- Panza, L., Luisetti, M., Crociati, E., Riva, S., Selective Acylation of 4,6-O-Benzylidene Glycopyranosides by Enzymatic Catalysis (1993) Journal of Carbohydrate Chemistry, 12, pp. 125-130
- Wang, Y.F., Wong, C.H., (1988) J. Org. Chem., 53, pp. 3127-3129
- Zaks, A., Klibanov, A.M., (1985) Proc. Natl. Acad. Sci., 82, pp. 3192-3196
Citas:
---------- APA ----------
Baldessari, A., Iglesias, L.E. & Gros, E.G.
(1994)
. An improved procedure for chemospecific acylation of 2-mercaptoethanol by lipase-catalyzed transesterification. Biotechnology Letters, 16(5), 479-484.
http://dx.doi.org/10.1007/BF01023329---------- CHICAGO ----------
Baldessari, A., Iglesias, L.E., Gros, E.G.
"An improved procedure for chemospecific acylation of 2-mercaptoethanol by lipase-catalyzed transesterification"
. Biotechnology Letters 16, no. 5
(1994) : 479-484.
http://dx.doi.org/10.1007/BF01023329---------- MLA ----------
Baldessari, A., Iglesias, L.E., Gros, E.G.
"An improved procedure for chemospecific acylation of 2-mercaptoethanol by lipase-catalyzed transesterification"
. Biotechnology Letters, vol. 16, no. 5, 1994, pp. 479-484.
http://dx.doi.org/10.1007/BF01023329---------- VANCOUVER ----------
Baldessari, A., Iglesias, L.E., Gros, E.G. An improved procedure for chemospecific acylation of 2-mercaptoethanol by lipase-catalyzed transesterification. Biotechnol Lett. 1994;16(5):479-484.
http://dx.doi.org/10.1007/BF01023329