Navegar

Colección

Datos Estadísticas

Artículo

El editor permite incluir el artículo en su versión final en nuestro repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

Two copper complex solvatomorphs, namely (3,10-C-meso-3,5,7,7,10,12,14,14- octamethyl-1,4,8,11-tetraazacyclotetradecane)bis(perchlorato-κO)copper(II) 1.2-hydrate, [Cu(ClO4)2(C18H 40N4)]·1.2H2O, (I), and (3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane) bis(perchlorato-κO)copper(II), [Cu(ClO4)2(C 18H40N4)], (II), are described and compared with each other and with a third, already reported, anhydrous diastereomer, denoted (III). Both compounds present very similar centrosymmetic coordination environments, with the CuII cation lying on an inversion centre in a distorted 4+2 octahedral environment, defined by the macrocyclic N4 group in the equatorial sites and two perchlorate groups in trans-axial positions [one of the perchlorate ligands in (I) is partially disordered]. The most significant difference in molecular shape is seen in the orientation of the perchlorate anions, and the influence of this on the intramolecular hydrogen bonding is discussed. The (partially) hydrated state of (I) favours the formation of chains along [011], while the anhydrous character of (II) and (III) promotes loosely bound structures with low packing indices. © 2013 International Union of Crystallography.

Registro:

Documento: Artículo
Título:Two solvatomorphic forms of a copper complex formulated as Cu( 1)(ClO4)2-1.2H2O and Cu(1)(ClO4)2, where 1 is 3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane
Autor:Nath, B.C.; Suarez, S.; Doctorovich, F.; Roy, T.G.; Baggio, R.
Filiación:University of Chittagong, Chittagong 4331, Bangladesh
Departamento de Química Inorgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina
Palabras clave:Coordination environment; Copper complexes; Equatorial sites; Intramolecular hydrogen bonding; Molecular shapes; Octahedral environment; Perchlorate anions; Significant differences; Copper; Hydrates; Hydration; Hydrogen bonds; Inorganic compounds; Molecular orientation; Copper compounds; coordination compound; copper; ligand; solvent; article; chemical structure; chemistry; hydrogen bond; stereoisomerism; X ray crystallography; Coordination Complexes; Copper; Crystallography, X-Ray; Hydrogen Bonding; Ligands; Models, Molecular; Molecular Structure; Solvents; Stereoisomerism
Año:2013
Volumen:69
Número:7
Página de inicio:689
Página de fin:695
DOI: http://dx.doi.org/10.1107/S0108270113013711
Título revista:Acta Crystallographica Section C: Crystal Structure Communications
Título revista abreviado:Acta Crystallogr Sect C Cryst Struct Commun
ISSN:01082701
CODEN:ACSCE
CAS:copper, 15158-11-9, 7440-50-8; Coordination Complexes; Copper, 7440-50-8; Ligands; Solvents
PDF:https://bibliotecadigital.exactas.uba.ar/download/paper/paper_01082701_v69_n7_p689_Nath.pdf
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v69_n7_p689_Nath

Referencias:

  • Allen, F.H., (2002) Acta Cryst, B58, pp. 380-388
  • Arai, H., Matshima, Y., Eguchi, T., Kazutoshi, S., Katsumi, K., (1998) Tetrahedron Lett, 39, pp. 3181-3184
  • Bembi, R., Drew, M.G.B., Singh, R., Roy, T.G., (1991) Inorg. Chem, 30, pp. 1403-1406
  • Bembi, R., Sondi, S.M., Singh, A.K., Roy, T.G., (1989) Bull. Chem. Soc. Jpn, 62, pp. 3701-3705
  • Bernhardt, P.V., Lawrance, G.A., (1990) Coord. Chem. Rev, 104, pp. 297-343
  • Bernstein, J., Davis, R.E., Shimoni, L., Chang, N.-L., (1995) Angew. Chem. Int. Ed. Engl, 34, pp. 1555-1573
  • Choi, K.-Y., Chun, K.-M., Suh, I.-H., (1999) Inorg. Chem. Commun, 2, pp. 210-213
  • Choi, K.-Y., Suh, I.-H., (1999) Main Group Met. Chem, 22, pp. 123-125
  • Curtis, N.F., (2012) Coord. Chem. Rev, 256, pp. 878-895
  • Curtis, N.F., Swann, D.A., Waters, T.N., Maxwell, I.E., (1969) J. Am. Chem. Soc, 91, pp. 4588-4589
  • Ferguson, G., Lough, A.J., Bembi, R., (1990) Acta Cryst, C46, pp. 213-215
  • Gao, Z., Tian, G., Zhao, G., Si, C., (2010) Inorg. Chem. Commun, 13, pp. 461-463
  • Hazari, S.K.S., Roy, T.G., Dey, B.K., Chakraborty, S., Tiekink, E.R.T., (1999) Z. Kristallogr. New Cryst. Struct, 214, pp. 51-52
  • Hazari, S.K.S., Roy, T.G., Dey, B.K., Das, S.C., Tiekink, E.R.T., (1997) Met. Based Drugs, 4, pp. 255-263
  • Hazari, S.K.S., Roy, T.G., Dey, B.K., Miah, H.A., Dutta, S., Tiekink, E.R.T., (2001) Z. Kristallogr. New Cryst. Struct, 216, pp. 441-442
  • Hollinshead, A.C., Smith, P.K., (1990) Antibiot. Annu, 313, pp. 1959-1960
  • Horn, E., Roy, T.G., Hazari, S.K.S., Dey, B.K., Tiekink, E.R.T., (2001) Z. Kristallogr. New Cryst. Struct, 216, pp. 71-72
  • Ito, T., Ito, H., Toriumi, K., (1981) Acta Cryst, B37, pp. 1412-1415
  • Kimura, E., Bu, X., Shionoya, M., Wada, S., Maruyama, S., (1992) Inorg. Chem, 31, pp. 4542-4546
  • Kimura, E., Wada, S., Shionoya, M., Okazai, Y., (1994) Inorg. Chem, 33, pp. 770-778
  • Konig, B., Pelka, M., Zieg, H., Jones, P.G., Dix, I., (1996) Chem. Commun, pp. 471-472
  • Lee, T.-J., Lee, T.-Y., Juang, W.-B., Chung, C.-S., (1985) Acta Cryst, C41, pp. 1596-1598
  • Lin, Y.-C., Mistra, T.-K., Lu, T.-H., Maddirala, S.J., Chung, C.-S., (2006) Eur. J. Inorg. Chem, pp. 994-1005
  • Norman, T.J., Parker, D., Smith, F.C., King, D.J., (1995) J. Chem. Soc. Chem. Commun, pp. 1879-1880
  • (2009) CrysAlis PRO, , Oxford Diffraction Oxford Diffraction Ltd, Yarnton, Oxfordshire, England
  • Reid, G., Schroder, M., (1990) Chem. Soc. Rev, 19, pp. 239-269
  • Roy, T.G., Bembi, R., (2005) Indian J. Chem. Sect. A, 44, pp. 700-704
  • Roy, T.G., Hazari, S.K.S., Barua, K.K., Anwar, N., Zukerman-Schpector, J., Tiekink, E.R.T., (2010) Appl. Organomet. Chem, 24, pp. 878-887
  • Roy, T.G., Hazari, S.K.S., Barua, K.K., Tiekink, E.R.T., (2011) Acta Cryst, E67, pp. m1659-m1660
  • Roy, T.G., Hazari, S.K.S., Dey, B.K., Dutta, S., Monsur, M.A., Tiekink, E.R.T., (2006) J. Coord. Chem, 59, pp. 1757-1767
  • Roy, T.G., Hazari, S.K.S., Dey, B.K., Meah, H.A., Rahman, M.S., Kim, D.I., Park, Y.C., (2007) J. Coord. Chem, 60, pp. 1567-1578
  • Roy, T.G., Hazari, S.K.S., Dey, B.K., Miah, H.A., Olbrich, F., Rehder, D., (2007) Inorg. Chem, 46, pp. 5372-5380
  • Roy, T.G., Hazari, S.K.S., Dey, B.K., Nath, A., Anwar, N., Kim, D.I., Kim, E.H., Park, Y.C., (2007) J. Inclusion Phenom. Macrocycl. Chem, 58, pp. 249-255
  • Roy, T.G., Hazari, S.K.S., Dey, B.K., Nath, B.C., Dutta, A., Olbrich, F., Rehder, D., (2011) Inorg. Chim. Acta, 371, pp. 63-70
  • Roy, T.G., Hazari, S.K.S., Nath, B.C., Ng, S.W., Tiekink, E.R.T., (2012) Acta Cryst, E68, pp. m494-m495
  • Sheldrick, G.M., (2008) Acta Cryst, A64, pp. 112-122
  • Singh, A.K., Kumar, A., Panwar, S., Baniwal, S., (1999) Analyst, 124, pp. 521-525
  • Spek, A.L., (2009) Acta Cryst, D65, pp. 148-155
  • Suh, M.-P., Moon, H.-R., Lee, E.-Y., Jang, S.-Y., (2006) J. Am. Chem. Soc, 128, pp. 4710-4718

Citas:

---------- APA ----------
Nath, B.C., Suarez, S., Doctorovich, F., Roy, T.G. & Baggio, R. (2013) . Two solvatomorphic forms of a copper complex formulated as Cu( 1)(ClO4)2-1.2H2O and Cu(1)(ClO4)2, where 1 is 3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane. Acta Crystallographica Section C: Crystal Structure Communications, 69(7), 689-695.
http://dx.doi.org/10.1107/S0108270113013711
---------- CHICAGO ----------
Nath, B.C., Suarez, S., Doctorovich, F., Roy, T.G., Baggio, R. "Two solvatomorphic forms of a copper complex formulated as Cu( 1)(ClO4)2-1.2H2O and Cu(1)(ClO4)2, where 1 is 3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane" . Acta Crystallographica Section C: Crystal Structure Communications 69, no. 7 (2013) : 689-695.
http://dx.doi.org/10.1107/S0108270113013711
---------- MLA ----------
Nath, B.C., Suarez, S., Doctorovich, F., Roy, T.G., Baggio, R. "Two solvatomorphic forms of a copper complex formulated as Cu( 1)(ClO4)2-1.2H2O and Cu(1)(ClO4)2, where 1 is 3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane" . Acta Crystallographica Section C: Crystal Structure Communications, vol. 69, no. 7, 2013, pp. 689-695.
http://dx.doi.org/10.1107/S0108270113013711
---------- VANCOUVER ----------
Nath, B.C., Suarez, S., Doctorovich, F., Roy, T.G., Baggio, R. Two solvatomorphic forms of a copper complex formulated as Cu( 1)(ClO4)2-1.2H2O and Cu(1)(ClO4)2, where 1 is 3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane. Acta Crystallogr Sect C Cryst Struct Commun. 2013;69(7):689-695.
http://dx.doi.org/10.1107/S0108270113013711