Artículo
Suarez, S.; Doctorovich, F.; Harvey, M.A.; Baggio, R. "Tetraaqua(4,4'-dimethyl-2,2'-bipyridine-κ2 N,N')nickel(II) sulfate monohydrate: A simple molecule with an extremely complex hydrogen-bonding scheme" (2013) Acta Crystallographica Section C: Crystal Structure Communications. 69(4):351-355
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Abstract:
The title ionic compound, [Ni(C12H12N 2)(H2O)4]SO4.H2O, is composed of an NiII cation coordinated by a chelating 4,4'-dimethyl-2,2'-bipyridine ligand via its two N atoms [mean Ni-N = 2.056 (2) Å] and by four aqua ligands [mean Ni-O = 2.073 (9) Å], the net charge being balanced by an external sulfate anion. The whole structure is stabilized by a solvent water molecule. Even though the individual constituents are rather featureless, they generate an extremely complex supramolecular structure consisting of a central hydrogen-bonded two-dimensional hydrophilic nucleus made up of complex cations, sulfate anions and coordinated and solvent water molecules, with pendant hydrophobic 4,4'-dimethyl-2,2'-bipyridine ligands which interact laterally with their neighbours via π-π interactions. The structure is compared with closely related analogues in the literature. © 2013 International Union of Crystallography.
Registro:
| Documento: | Artículo |
| Título: | Tetraaqua(4,4'-dimethyl-2,2'-bipyridine-κ2 N,N')nickel(II) sulfate monohydrate: A simple molecule with an extremely complex hydrogen-bonding scheme |
| Autor: | Suarez, S.; Doctorovich, F.; Harvey, M.A.; Baggio, R. |
| Filiación: | Departamento de Química Inorgánica, Analítica y Química Física/INQUIMAE-CONICET, Universidad de Buenos Aires, Buenos Aires, Argentina Universidad Nacional de la Patagonia SJB, Sede Trelew, 9100 Trelew, Chubut, Argentina CenPat, CONICET, 9120 Puerto Madryn, Chubut, Argentina Departamento de Física, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina |
| Palabras clave: | Aqua ligands; Bipyridine ligands; Bipyridines; Complex cation; Complex supramolecular structure; Ionic compounds; Sulfate anions; Water molecule; Hydrogen bonds; Molecules; Negative ions; Nickel; Nickel sulfates; Positive ions; Ligands |
| Año: | 2013 |
| Volumen: | 69 |
| Número: | 4 |
| Página de inicio: | 351 |
| Página de fin: | 355 |
| DOI: | http://dx.doi.org/10.1107/S0108270113005088 |
| Título revista: | Acta Crystallographica Section C: Crystal Structure Communications |
| Título revista abreviado: | Acta Crystallogr Sect C Cryst Struct Commun |
| ISSN: | 01082701 |
| CODEN: | ACSCE |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v69_n4_p351_Suarez |
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Citas:
---------- APA ----------
Suarez, S., Doctorovich, F., Harvey, M.A. & Baggio, R. (2013) . Tetraaqua(4,4'-dimethyl-2,2'-bipyridine-κ2 N,N')nickel(II) sulfate monohydrate: A simple molecule with an extremely complex hydrogen-bonding scheme. Acta Crystallographica Section C: Crystal Structure Communications, 69(4), 351-355.http://dx.doi.org/10.1107/S0108270113005088
---------- CHICAGO ----------
Suarez, S., Doctorovich, F., Harvey, M.A., Baggio, R. "Tetraaqua(4,4'-dimethyl-2,2'-bipyridine-κ2 N,N')nickel(II) sulfate monohydrate: A simple molecule with an extremely complex hydrogen-bonding scheme" . Acta Crystallographica Section C: Crystal Structure Communications 69, no. 4 (2013) : 351-355.http://dx.doi.org/10.1107/S0108270113005088
---------- MLA ----------
Suarez, S., Doctorovich, F., Harvey, M.A., Baggio, R. "Tetraaqua(4,4'-dimethyl-2,2'-bipyridine-κ2 N,N')nickel(II) sulfate monohydrate: A simple molecule with an extremely complex hydrogen-bonding scheme" . Acta Crystallographica Section C: Crystal Structure Communications, vol. 69, no. 4, 2013, pp. 351-355.http://dx.doi.org/10.1107/S0108270113005088
---------- VANCOUVER ----------
Suarez, S., Doctorovich, F., Harvey, M.A., Baggio, R. Tetraaqua(4,4'-dimethyl-2,2'-bipyridine-κ2 N,N')nickel(II) sulfate monohydrate: A simple molecule with an extremely complex hydrogen-bonding scheme. Acta Crystallogr Sect C Cryst Struct Commun. 2013;69(4):351-355.http://dx.doi.org/10.1107/S0108270113005088
