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Abstract:

The title complexes, [RuCl(C9H21N3)(C 12H12N2O2)]ClO4· 2C2H3N, (I), and [Ru(C9H 21N3)(C12H12N2O 2)(H2O)](ClO4)2·2H 2O, (II), display similar structures with the Ru atom in a distorted octa-hedral environment. In the crystal packing of the chloride complex, (I), the Ru complex mol-ecules are held together in pairs through C - H⋯Cl inter-actions of the 4,4′-dimeth-oxy-2,2′-bipyridine and chloride ligands. In the case of the aqua complex, (II), hydrogen bonding affords a tetra-meric hydrogen-bonded network. These two structures are the first examples of complexes with the {Ru(1,4,7-trimethyl-1,4,7-triaza-cyclo-nona-ne)} motif and an electron-rich substituted 2,2′-bipyridine ligand. © 2012 International Union of Crystallography.

Registro:

Documento: Artículo
Título:Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate
Autor:Vera, D.B.; Osa Codesido, N.; De Candia, A.G.; Alborés, P.; Slep, L.D.
Filiación:INQUIMAE-DQIAyQF, Universidad de Buenos Aires, Pab. 2, piso 3, Ciudad Universitaria, (C1428EHA) Buenos Aires, Argentina
Palabras clave:Aqua complexes; Bipyridine ligands; Bipyridines; Chloride complexes; Chloride ligands; Crystal packings; Dihydrates; Electron-rich; Hydrogen bonded network; Ru complexes; Acetonitrile; Crystal atomic structure; Hydrogen bonds; Inorganic compounds; Ligands; Ruthenium; Ruthenium compounds; Chlorine compounds; Tetra
Año:2012
Volumen:68
Número:5
Página de inicio:m127
Página de fin:m130
DOI: http://dx.doi.org/10.1107/S0108270112015259
Título revista:Acta Crystallographica Section C: Crystal Structure Communications
Título revista abreviado:Acta Crystallogr Sect C Cryst Struct Commun
ISSN:01082701
CODEN:ACSCE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v68_n5_pm127_Vera

Referencias:

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Citas:

---------- APA ----------
Vera, D.B., Osa Codesido, N., De Candia, A.G., Alborés, P. & Slep, L.D. (2012) . Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate. Acta Crystallographica Section C: Crystal Structure Communications, 68(5), m127-m130.
http://dx.doi.org/10.1107/S0108270112015259
---------- CHICAGO ----------
Vera, D.B., Osa Codesido, N., De Candia, A.G., Alborés, P., Slep, L.D. "Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate" . Acta Crystallographica Section C: Crystal Structure Communications 68, no. 5 (2012) : m127-m130.
http://dx.doi.org/10.1107/S0108270112015259
---------- MLA ----------
Vera, D.B., Osa Codesido, N., De Candia, A.G., Alborés, P., Slep, L.D. "Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate" . Acta Crystallographica Section C: Crystal Structure Communications, vol. 68, no. 5, 2012, pp. m127-m130.
http://dx.doi.org/10.1107/S0108270112015259
---------- VANCOUVER ----------
Vera, D.B., Osa Codesido, N., De Candia, A.G., Alborés, P., Slep, L.D. Chlorido(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) perchlorate acetonitrile disolvate and aqua-(4,4′-dimeth-oxy-2,2′-bipyridine)(1,4,7-trimethyl-1,4, 7-triaza-cyclo-nona-ne)ruthenium(II) bis-(per-chlorate) dihydrate. Acta Crystallogr Sect C Cryst Struct Commun. 2012;68(5):m127-m130.
http://dx.doi.org/10.1107/S0108270112015259