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Abstract:

The title compound, C21H21NO7S 3, consists of an SO2ON(SO2)2 central fragment and three terminal 4-methyl-phenyl groups each attached at a sulfonyl S atom. The most obvious characteristic is the presence of two nearly face-to-face benzene rings, with their centroids separated by a rather short distance [3.7808 (18) Å], but with a rather slanted relative orientation [dihedral angle = 20.63 (13)°] so as to preclude a strong intra-molecular π-π interaction. The third benzene ring is nearly perpendicular to the other two [dihedral angles = 71.62 (14) and 70.4 (13)°]. The packing of the structure is directed by two C - H⋯O hydrogen bonds involving aromatic H atoms (methyl H atoms are strictly non-inter-acting), which define chains running in the [100] direction. These one-dimensional chains evolve parallel to each other and exhibit no significant lateral interactions. © 2012 International Union of Crystallography.

Registro:

Documento: Artículo
Título:Bis(4-methylphenylsulfonyl)amino 4-methylbenzenesulfonate: A new member of the (RSO2)ON(SO2R)2 family
Autor:Suarez, S.; Doctorovich, F.; Baggio, R.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE-CONICET, Universidad de Buenos Aires, Buenos Aires, Argentina
Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina
Palabras clave:Benzene ring; Lateral interactions; New members; One-dimensional chains; Relative orientation; Running-in; Title compounds; Atoms; Benzene; Dihedral angle; Hydrogen bonds; Sulfur dioxide
Año:2012
Volumen:68
Número:10
Página de inicio:o417
Página de fin:o420
DOI: http://dx.doi.org/10.1107/S0108270112039182
Título revista:Acta Crystallographica Section C: Crystal Structure Communications
Título revista abreviado:Acta Crystallogr Sect C Cryst Struct Commun
ISSN:01082701
CODEN:ACSCE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v68_n10_po417_Suarez

Referencias:

  • Allen, F.H., (2002) Acta Cryst., B58, pp. 380-388
  • Birchall, J.D., Glidewell, C., (1977) J. Chem. Soc. Dalton Trans., pp. 10-14
  • Birchall, J.D., Glidewell, C., (1978) J. Chem. Soc. Dalton Trans., pp. 604-607
  • Brink, K., Mattes, R., (1985) Chem. Ber., 118, pp. 564-573
  • Brink, K., Mattes, R., (1986) Acta Cryst., C42, pp. 1625-1627
  • Farrar, W.V., (1960) J. Chem. Soc., pp. 3063-3069
  • Glidewell, C., Davie, R., (1981) Inorg. Chim. Acta, 47, pp. 77-79
  • Janiak, C., (2000) J. Chem. Soc. Dalton Trans., pp. 3885-3898
  • (2009) CrysAlis PRO., , Oxford Diffraction ( Oxford Diffraction Ltd, Yarnton, Oxfordshire, England
  • Ruff, J.K., Merritt, R., (1968) Inorg. Chem., 7, pp. 1219-1221
  • Scholz, J.N., Engel, P.S., Glidewell, C., Whitmire, K., (1989) Tetrahedron, 45, pp. 7695-7708
  • Sheldrick, G.M., (2008) Acta Cryst., A64, pp. 112-122
  • Spek, A.L., (2009) Acta Cryst., D65, pp. 148-155
  • Tomita, K., (2002), Jpn Kokai Tokkyo Koho JP 2002072459; Wowski, W., Scheittele, E., (1965) J. Am. Chem. Soc., 87, pp. 4359-4365

Citas:

---------- APA ----------
Suarez, S., Doctorovich, F. & Baggio, R. (2012) . Bis(4-methylphenylsulfonyl)amino 4-methylbenzenesulfonate: A new member of the (RSO2)ON(SO2R)2 family. Acta Crystallographica Section C: Crystal Structure Communications, 68(10), o417-o420.
http://dx.doi.org/10.1107/S0108270112039182
---------- CHICAGO ----------
Suarez, S., Doctorovich, F., Baggio, R. "Bis(4-methylphenylsulfonyl)amino 4-methylbenzenesulfonate: A new member of the (RSO2)ON(SO2R)2 family" . Acta Crystallographica Section C: Crystal Structure Communications 68, no. 10 (2012) : o417-o420.
http://dx.doi.org/10.1107/S0108270112039182
---------- MLA ----------
Suarez, S., Doctorovich, F., Baggio, R. "Bis(4-methylphenylsulfonyl)amino 4-methylbenzenesulfonate: A new member of the (RSO2)ON(SO2R)2 family" . Acta Crystallographica Section C: Crystal Structure Communications, vol. 68, no. 10, 2012, pp. o417-o420.
http://dx.doi.org/10.1107/S0108270112039182
---------- VANCOUVER ----------
Suarez, S., Doctorovich, F., Baggio, R. Bis(4-methylphenylsulfonyl)amino 4-methylbenzenesulfonate: A new member of the (RSO2)ON(SO2R)2 family. Acta Crystallogr Sect C Cryst Struct Commun. 2012;68(10):o417-o420.
http://dx.doi.org/10.1107/S0108270112039182