Abstract:
The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography.
Registro:
Documento: |
Artículo
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Título: | N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds |
Autor: | Suarez, S.A.; Foi, A.; Eady, S.; Larsen, A.; Doctorovich, F. |
Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina Department of Chemistry, Ithaca College, 953 Danby Road, Ithaca, NY 14850, United States
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Palabras clave: | Asymmetric unit; Carborane anions; Carborane cages; Counterions; Pyridinium salts; Title compounds; Positive ions; Negative ions |
Año: | 2011
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Volumen: | 67
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Número: | 10
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Página de inicio: | o417
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Página de fin: | o420
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DOI: |
http://dx.doi.org/10.1107/S0108270111035165 |
Título revista: | Acta Crystallographica Section C: Crystal Structure Communications
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Título revista abreviado: | Acta Crystallogr Sect C Cryst Struct Commun
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ISSN: | 01082701
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CODEN: | ACSCE
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PDF: | https://bibliotecadigital.exactas.uba.ar/download/paper/paper_01082701_v67_n10_po417_Suarez.pdf |
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v67_n10_po417_Suarez |
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Citas:
---------- APA ----------
Suarez, S.A., Foi, A., Eady, S., Larsen, A. & Doctorovich, F.
(2011)
. N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds. Acta Crystallographica Section C: Crystal Structure Communications, 67(10), o417-o420.
http://dx.doi.org/10.1107/S0108270111035165---------- CHICAGO ----------
Suarez, S.A., Foi, A., Eady, S., Larsen, A., Doctorovich, F.
"N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds"
. Acta Crystallographica Section C: Crystal Structure Communications 67, no. 10
(2011) : o417-o420.
http://dx.doi.org/10.1107/S0108270111035165---------- MLA ----------
Suarez, S.A., Foi, A., Eady, S., Larsen, A., Doctorovich, F.
"N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds"
. Acta Crystallographica Section C: Crystal Structure Communications, vol. 67, no. 10, 2011, pp. o417-o420.
http://dx.doi.org/10.1107/S0108270111035165---------- VANCOUVER ----------
Suarez, S.A., Foi, A., Eady, S., Larsen, A., Doctorovich, F. N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds. Acta Crystallogr Sect C Cryst Struct Commun. 2011;67(10):o417-o420.
http://dx.doi.org/10.1107/S0108270111035165