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Abstract:

The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography.

Registro:

Documento: Artículo
Título:N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
Autor:Suarez, S.A.; Foi, A.; Eady, S.; Larsen, A.; Doctorovich, F.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina
Department of Chemistry, Ithaca College, 953 Danby Road, Ithaca, NY 14850, United States
Palabras clave:Asymmetric unit; Carborane anions; Carborane cages; Counterions; Pyridinium salts; Title compounds; Positive ions; Negative ions
Año:2011
Volumen:67
Número:10
Página de inicio:o417
Página de fin:o420
DOI: http://dx.doi.org/10.1107/S0108270111035165
Título revista:Acta Crystallographica Section C: Crystal Structure Communications
Título revista abreviado:Acta Crystallogr Sect C Cryst Struct Commun
ISSN:01082701
CODEN:ACSCE
PDF:https://bibliotecadigital.exactas.uba.ar/download/paper/paper_01082701_v67_n10_po417_Suarez.pdf
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v67_n10_po417_Suarez

Referencias:

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Citas:

---------- APA ----------
Suarez, S.A., Foi, A., Eady, S., Larsen, A. & Doctorovich, F. (2011) . N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds. Acta Crystallographica Section C: Crystal Structure Communications, 67(10), o417-o420.
http://dx.doi.org/10.1107/S0108270111035165
---------- CHICAGO ----------
Suarez, S.A., Foi, A., Eady, S., Larsen, A., Doctorovich, F. "N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds" . Acta Crystallographica Section C: Crystal Structure Communications 67, no. 10 (2011) : o417-o420.
http://dx.doi.org/10.1107/S0108270111035165
---------- MLA ----------
Suarez, S.A., Foi, A., Eady, S., Larsen, A., Doctorovich, F. "N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds" . Acta Crystallographica Section C: Crystal Structure Communications, vol. 67, no. 10, 2011, pp. o417-o420.
http://dx.doi.org/10.1107/S0108270111035165
---------- VANCOUVER ----------
Suarez, S.A., Foi, A., Eady, S., Larsen, A., Doctorovich, F. N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds. Acta Crystallogr Sect C Cryst Struct Commun. 2011;67(10):o417-o420.
http://dx.doi.org/10.1107/S0108270111035165