Artículo

Alborés, P.; Baraldo, L.M.; Ibañez, A.; Baggio, R. "4,4′-Bis(N,N-diethylamino)-2,2′-bi-pyridine" (2004) Acta Crystallographica Section C: Crystal Structure Communications. 60(12):o850-o852
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Abstract:

The overall structure including intermolecular interactions and crystal orientation of 4,4′-Bis(N,N-diethylamino)2,2′-bi-pyridine was investigated. Each molecule was found to have a planar bipyridine nucleus and two terminal diethylamine groups oriented at almost right angles to the core. The terminal diethylamine groups was deviated from the mean plane of the molecular core due to the slight rotation of the CNC2 groups around the C-N bonds. The results show that the terminal methyl arms act a effective spacers between molecules.

Registro:

Documento: Artículo
Título:4,4′-Bis(N,N-diethylamino)-2,2′-bi-pyridine
Autor:Alborés, P.; Baraldo, L.M.; Ibañez, A.; Baggio, R.
Filiación:Depto. de Quím. Inorg., INQUIMAE, Universidad de Buenos Aires, Argentina
CIMAT, Casilla 487-3, Santiago de Chile, Chile
Departamento de Física, Comn. Nac. de Ener. Atómica, Buenos Aires, Argentina
Palabras clave:Amines; Catalysis; Complexation; Crystal orientation; Crystal structure; Hydrogen bonds; Redox reactions; Bond lengths; Geometric parameters; Ligands; Spin properties; Aromatic compounds
Año:2004
Volumen:60
Número:12
Página de inicio:o850
Página de fin:o852
DOI: http://dx.doi.org/10.1107/S0108270104025077
Título revista:Acta Crystallographica Section C: Crystal Structure Communications
Título revista abreviado:Acta Crystallogr Sect C Cryst Struct Commun
ISSN:01082701
CODEN:ACSCE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v60_n12_po850_Albores

Referencias:

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Citas:

---------- APA ----------
Alborés, P., Baraldo, L.M., Ibañez, A. & Baggio, R. (2004) . 4,4′-Bis(N,N-diethylamino)-2,2′-bi-pyridine. Acta Crystallographica Section C: Crystal Structure Communications, 60(12), o850-o852.
http://dx.doi.org/10.1107/S0108270104025077
---------- CHICAGO ----------
Alborés, P., Baraldo, L.M., Ibañez, A., Baggio, R. "4,4′-Bis(N,N-diethylamino)-2,2′-bi-pyridine" . Acta Crystallographica Section C: Crystal Structure Communications 60, no. 12 (2004) : o850-o852.
http://dx.doi.org/10.1107/S0108270104025077
---------- MLA ----------
Alborés, P., Baraldo, L.M., Ibañez, A., Baggio, R. "4,4′-Bis(N,N-diethylamino)-2,2′-bi-pyridine" . Acta Crystallographica Section C: Crystal Structure Communications, vol. 60, no. 12, 2004, pp. o850-o852.
http://dx.doi.org/10.1107/S0108270104025077
---------- VANCOUVER ----------
Alborés, P., Baraldo, L.M., Ibañez, A., Baggio, R. 4,4′-Bis(N,N-diethylamino)-2,2′-bi-pyridine. Acta Crystallogr Sect C Cryst Struct Commun. 2004;60(12):o850-o852.
http://dx.doi.org/10.1107/S0108270104025077