Abstract:
The overall structure including intermolecular interactions and crystal orientation of 4,4′-Bis(N,N-diethylamino)2,2′-bi-pyridine was investigated. Each molecule was found to have a planar bipyridine nucleus and two terminal diethylamine groups oriented at almost right angles to the core. The terminal diethylamine groups was deviated from the mean plane of the molecular core due to the slight rotation of the CNC2 groups around the C-N bonds. The results show that the terminal methyl arms act a effective spacers between molecules.
Registro:
Documento: |
Artículo
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Título: | 4,4′-Bis(N,N-diethylamino)-2,2′-bi-pyridine |
Autor: | Alborés, P.; Baraldo, L.M.; Ibañez, A.; Baggio, R. |
Filiación: | Depto. de Quím. Inorg., INQUIMAE, Universidad de Buenos Aires, Argentina CIMAT, Casilla 487-3, Santiago de Chile, Chile Departamento de Física, Comn. Nac. de Ener. Atómica, Buenos Aires, Argentina
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Palabras clave: | Amines; Catalysis; Complexation; Crystal orientation; Crystal structure; Hydrogen bonds; Redox reactions; Bond lengths; Geometric parameters; Ligands; Spin properties; Aromatic compounds |
Año: | 2004
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Volumen: | 60
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Número: | 12
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Página de inicio: | o850
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Página de fin: | o852
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DOI: |
http://dx.doi.org/10.1107/S0108270104025077 |
Título revista: | Acta Crystallographica Section C: Crystal Structure Communications
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Título revista abreviado: | Acta Crystallogr Sect C Cryst Struct Commun
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ISSN: | 01082701
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CODEN: | ACSCE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v60_n12_po850_Albores |
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Citas:
---------- APA ----------
Alborés, P., Baraldo, L.M., Ibañez, A. & Baggio, R.
(2004)
. 4,4′-Bis(N,N-diethylamino)-2,2′-bi-pyridine. Acta Crystallographica Section C: Crystal Structure Communications, 60(12), o850-o852.
http://dx.doi.org/10.1107/S0108270104025077---------- CHICAGO ----------
Alborés, P., Baraldo, L.M., Ibañez, A., Baggio, R.
"4,4′-Bis(N,N-diethylamino)-2,2′-bi-pyridine"
. Acta Crystallographica Section C: Crystal Structure Communications 60, no. 12
(2004) : o850-o852.
http://dx.doi.org/10.1107/S0108270104025077---------- MLA ----------
Alborés, P., Baraldo, L.M., Ibañez, A., Baggio, R.
"4,4′-Bis(N,N-diethylamino)-2,2′-bi-pyridine"
. Acta Crystallographica Section C: Crystal Structure Communications, vol. 60, no. 12, 2004, pp. o850-o852.
http://dx.doi.org/10.1107/S0108270104025077---------- VANCOUVER ----------
Alborés, P., Baraldo, L.M., Ibañez, A., Baggio, R. 4,4′-Bis(N,N-diethylamino)-2,2′-bi-pyridine. Acta Crystallogr Sect C Cryst Struct Commun. 2004;60(12):o850-o852.
http://dx.doi.org/10.1107/S0108270104025077