Artículo
Albores, P.; Chaia, Z.D.; Baraldo, L.; Castellano, E.E.; Piro, O.E. "A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)" (2002) Acta Crystallographica Section C: Crystal Structure Communications. 58(4):m235-m236
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Abstract:
The octahedral title compound, [Ru(C2H5O)(NO)(NO2)2-(C6H 16N2)], crystallizes in the rhombohedral space group P31 with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and to two nitro moieties whose planes are tilted with respect to the mean equatorial plane. Each nitrogen ligand bonded to the metallic centre has a different hybridization state.
Registro:
| Documento: | Artículo |
| Título: | A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II) |
| Autor: | Albores, P.; Chaia, Z.D.; Baraldo, L.; Castellano, E.E.; Piro, O.E. |
| Filiación: | Departamento de QIAQF, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón II, 1428 Buenos Aires, Argentina |
| Palabras clave: | Chemical bonds; Complexation; Crystallization; Ruthenium compounds; Solutions; Stereochemistry; Synthesis (chemical); Hybridization; Ligands; Crystal structure |
| Año: | 2002 |
| Volumen: | 58 |
| Número: | 4 |
| Página de inicio: | m235 |
| Página de fin: | m236 |
| DOI: | http://dx.doi.org/10.1107/S0108270102001701 |
| Título revista: | Acta Crystallographica Section C: Crystal Structure Communications |
| Título revista abreviado: | Acta Crystallogr Sect C Cryst Struct Commun |
| ISSN: | 01082701 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v58_n4_pm235_Albores |
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Citas:
---------- APA ----------
Albores, P., Chaia, Z.D., Baraldo, L., Castellano, E.E. & Piro, O.E. (2002) . A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II). Acta Crystallographica Section C: Crystal Structure Communications, 58(4), m235-m236.http://dx.doi.org/10.1107/S0108270102001701
---------- CHICAGO ----------
Albores, P., Chaia, Z.D., Baraldo, L., Castellano, E.E., Piro, O.E. "A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)" . Acta Crystallographica Section C: Crystal Structure Communications 58, no. 4 (2002) : m235-m236.http://dx.doi.org/10.1107/S0108270102001701
---------- MLA ----------
Albores, P., Chaia, Z.D., Baraldo, L., Castellano, E.E., Piro, O.E. "A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)" . Acta Crystallographica Section C: Crystal Structure Communications, vol. 58, no. 4, 2002, pp. m235-m236.http://dx.doi.org/10.1107/S0108270102001701
---------- VANCOUVER ----------
Albores, P., Chaia, Z.D., Baraldo, L., Castellano, E.E., Piro, O.E. A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II). Acta Crystallogr Sect C Cryst Struct Commun. 2002;58(4):m235-m236.http://dx.doi.org/10.1107/S0108270102001701
