Artículo
Zelcer, A.; Chaia, Z.D.; Cukiernik, F.D.; Castellano, E.E.; Piro, O.E. "A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate" (2002) Acta Crystallographica Section C: Crystal Structure Communications. 58(3):m144-m146
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Abstract:
The title compound, catena-poly[[tetrakis(μ-decanoato- κ2O:O′)-diruthenium(II, III) (Ru - Ru)]- μ-octanesulfonato-κ2O:O′], [Ru2(C10H19O2)4 (C8H17O3S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains.
Registro:
| Documento: | Artículo |
| Título: | A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate |
| Autor: | Zelcer, A.; Chaia, Z.D.; Cukiernik, F.D.; Castellano, E.E.; Piro, O.E. |
| Filiación: | Division of Reproductive Biology, United States University of London, United Kingdom Analitica y Quimica Fisica, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon II, 1428 Buenos Aires, Argentina |
| Palabras clave: | Crystal structure; Liquid crystals; Negative ions; Ruthenium compounds; X ray diffraction analysis; Diruthenium tetradecanoate; Long chain carboxylate; Organometallics; Catena |
| Año: | 2002 |
| Volumen: | 58 |
| Número: | 3 |
| Página de inicio: | m144 |
| Página de fin: | m146 |
| DOI: | http://dx.doi.org/10.1107/S0108270101021540 |
| Título revista: | Acta Crystallographica Section C: Crystal Structure Communications |
| Título revista abreviado: | Acta Crystallogr Sect C Cryst Struct Commun |
| ISSN: | 01082701 |
| PDF: | https://bibliotecadigital.exactas.uba.ar/download/paper/paper_01082701_v58_n3_pm144_Zelcer.pdf |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v58_n3_pm144_Zelcer |
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Citas:
---------- APA ----------
Zelcer, A., Chaia, Z.D., Cukiernik, F.D., Castellano, E.E. & Piro, O.E. (2002) . A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate. Acta Crystallographica Section C: Crystal Structure Communications, 58(3), m144-m146.http://dx.doi.org/10.1107/S0108270101021540
---------- CHICAGO ----------
Zelcer, A., Chaia, Z.D., Cukiernik, F.D., Castellano, E.E., Piro, O.E. "A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate" . Acta Crystallographica Section C: Crystal Structure Communications 58, no. 3 (2002) : m144-m146.http://dx.doi.org/10.1107/S0108270101021540
---------- MLA ----------
Zelcer, A., Chaia, Z.D., Cukiernik, F.D., Castellano, E.E., Piro, O.E. "A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate" . Acta Crystallographica Section C: Crystal Structure Communications, vol. 58, no. 3, 2002, pp. m144-m146.http://dx.doi.org/10.1107/S0108270101021540
---------- VANCOUVER ----------
Zelcer, A., Chaia, Z.D., Cukiernik, F.D., Castellano, E.E., Piro, O.E. A liquid crystal derived from ruthenium(II, III) and a long-chain carboxylate. Acta Crystallogr Sect C Cryst Struct Commun. 2002;58(3):m144-m146.http://dx.doi.org/10.1107/S0108270101021540
