Abstract:
The title complex, aqua(2,2′-bipyridy-N,N′(3-thiapentanedioate-O,S,O′)zinc(II) tetrahydrate, [Zn(C4H4-O4S)(C10H8N 2)(H2O)].4H2O, is mononuclear with a coordination sphere consisting of one S, two N and three O atoms. The Zn atom is linked to a tridentate thiodiacetate ligand, a bidentate 2,2′-bipyridine ligand and an aqua ligand resulting in a slightly distorted octahedral coordination geometry. The molecular units are linked together in the crystal by an extensive hydrogen-bonding network and by intermolecular S⋯S interactions.
Registro:
Documento: |
Artículo
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Título: | Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate |
Autor: | Baggio, R.; Perec, M.; Garland, M.T. |
Filiación: | Div. Física del Sólido, Departamento de Física, Comn. Natl. de Ener. Atómica, Buenos Aires, Argentina Depto. Quim. Inorg., Analitica Q., INQUIMAE, Fac. de Ciencias Exactas y Naturales, Buenos Aires, Argentina Departamento de Física, Fac. de Cie. Fis. y Matemat., Universidad de Chile, Casilla 487-3, Santiago de Chile, Chile
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Palabras clave: | Crystal atomic structure; Crystal defects; Crystallography; Hydrogen bonds; Molecular structure; Zinc compounds; Aqua ligands; Octahedral coordination geometry; Tridentate thiodiacetate ligand; Organometallics |
Año: | 1996
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Volumen: | 52
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Número: | 10
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Página de inicio: | 2457
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Página de fin: | 2460
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DOI: |
http://dx.doi.org/10.1107/S0108270196007329 |
Título revista: | Acta Crystallographica Section C: Crystal Structure Communications
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Título revista abreviado: | Acta Crystallogr Sect C Cryst Struct Commun
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ISSN: | 01082701
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CODEN: | ACSCE
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PDF: | https://bibliotecadigital.exactas.uba.ar/download/paper/paper_01082701_v52_n10_p2457_Baggio.pdf |
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v52_n10_p2457_Baggio |
Referencias:
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Citas:
---------- APA ----------
Baggio, R., Perec, M. & Garland, M.T.
(1996)
. Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate. Acta Crystallographica Section C: Crystal Structure Communications, 52(10), 2457-2460.
http://dx.doi.org/10.1107/S0108270196007329---------- CHICAGO ----------
Baggio, R., Perec, M., Garland, M.T.
"Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate"
. Acta Crystallographica Section C: Crystal Structure Communications 52, no. 10
(1996) : 2457-2460.
http://dx.doi.org/10.1107/S0108270196007329---------- MLA ----------
Baggio, R., Perec, M., Garland, M.T.
"Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate"
. Acta Crystallographica Section C: Crystal Structure Communications, vol. 52, no. 10, 1996, pp. 2457-2460.
http://dx.doi.org/10.1107/S0108270196007329---------- VANCOUVER ----------
Baggio, R., Perec, M., Garland, M.T. Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate. Acta Crystallogr Sect C Cryst Struct Commun. 1996;52(10):2457-2460.
http://dx.doi.org/10.1107/S0108270196007329