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Abstract:

Tobacco hairy roots (THR) were used to evaluate its potential for the biosorption and removal of malachite green (MG) from aqueous solutions. A 32 full factorial design was applied to study the effects of pH and THR concentration on the biosorption capacity. Under the optimal conditions (pH of 7.0 and THR concentration of 1 g L−1), dye removal efficiency was around 92%. Experimental data obtained from kinetic studies demonstrated good concordance with the pseudo-second-order model. Equilibrium studies were developed and the data were evaluated by Langmuir, Freundlich, and Sips models, being the Sips model the most adequate (maximum biosorption capacity of 277.2 mg g−1). Thermodynamically, the biosorption of MG on THR proved to be endothermic, spontaneous, and favorable. Desorption was feasible under acidic conditions and the biosorbent could be reused three times. THR was tested in simulated effluent and the removal percentage was 87%, demonstrating that this material is a promising biosorbent which can be used to treat colored wastewaters. © 2018 Taylor & Francis.

Registro:

Documento: Artículo
Título:Application of tobacco hairy roots for the removal of malachite green from aqueous solutions: Experimental design, kinetic, equilibrium, and thermodynamic studies
Autor:Escudero, L.B.; Agostini, E.; Dotto, G.L.
Filiación:Laboratory of Analytical Chemistry for Research and Development (QUIANID), Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Cuyo, Mendoza, Argentina
Consejo Nacional de Investigaciones Científicas y Técnicas, Buenos Aires, Argentina
Departamento de Biología Molecular, FCEFQyN, Universidad Nacional de Río Cuarto, Córdoba, Argentina
Chemical Engineering Department, Federal University of Santa Maria (UFSM), Santa Maria, Rio Grande do Sul, Brazil
Palabras clave:Biosorption; dye removal; hairy roots; kinetics; malachite green; thermodynamics; Biosorption; Carbonate minerals; Dyes; Enzyme kinetics; Kinetics; Thermodynamics; Tobacco; Wastewater treatment; Biosorption capacity; Dye removal; Full factorial design; Hairy roots; Malachite green; Optimal conditions; Pseudo-second order model; Thermodynamic studies; Solutions
Año:2018
Volumen:205
Número:1
Página de inicio:122
Página de fin:133
DOI: http://dx.doi.org/10.1080/00986445.2017.1377699
Título revista:Chemical Engineering Communications
Título revista abreviado:Chem. Eng. Commun.
ISSN:00986445
CODEN:CEGCA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00986445_v205_n1_p122_Escudero

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Citas:

---------- APA ----------
Escudero, L.B., Agostini, E. & Dotto, G.L. (2018) . Application of tobacco hairy roots for the removal of malachite green from aqueous solutions: Experimental design, kinetic, equilibrium, and thermodynamic studies. Chemical Engineering Communications, 205(1), 122-133.
http://dx.doi.org/10.1080/00986445.2017.1377699
---------- CHICAGO ----------
Escudero, L.B., Agostini, E., Dotto, G.L. "Application of tobacco hairy roots for the removal of malachite green from aqueous solutions: Experimental design, kinetic, equilibrium, and thermodynamic studies" . Chemical Engineering Communications 205, no. 1 (2018) : 122-133.
http://dx.doi.org/10.1080/00986445.2017.1377699
---------- MLA ----------
Escudero, L.B., Agostini, E., Dotto, G.L. "Application of tobacco hairy roots for the removal of malachite green from aqueous solutions: Experimental design, kinetic, equilibrium, and thermodynamic studies" . Chemical Engineering Communications, vol. 205, no. 1, 2018, pp. 122-133.
http://dx.doi.org/10.1080/00986445.2017.1377699
---------- VANCOUVER ----------
Escudero, L.B., Agostini, E., Dotto, G.L. Application of tobacco hairy roots for the removal of malachite green from aqueous solutions: Experimental design, kinetic, equilibrium, and thermodynamic studies. Chem. Eng. Commun. 2018;205(1):122-133.
http://dx.doi.org/10.1080/00986445.2017.1377699