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Abstract:

The thermodynamics of dissolution of non-reactive gases in water under ambient conditions is of importance for the description of the properties of small hydrophobic solutes, and they are also of interest for environmental assessments. The review published in 1977 by Wilhelm, Battino and Wilcock (Chem. Rev. 77:219-262, 1977) constitutes a milestone in this field. However, a number of new data have been published since then, including both solubility and calorimetric determinations. We have analyzed the new data for 27 binary systems reported in the literature at the time of writing this article. Whenever solubility and calorimetric data both exist they have been fitted together. There are, however, systems for which only one type of new thermodynamic information is available; these systems were also analyzed using procedures that are described in this work. © 2008 Springer Science+Business Media, LLC.

Registro:

Documento: Artículo
Título:Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update
Autor:Alvarez, J.L.; Fernández Prini, R.
Filiación:Gerencia Química, Comisión Nacional de Energía Atomica, Buenos Aires, Argentina
INQUIMAE, CONICET Facultad Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Palabras clave:Ambient temperatures; Aqueous solutions; Gaseous solutes; Gibbs energy and enthalpy of dissolution
Año:2008
Volumen:37
Número:10
Página de inicio:1379
Página de fin:1392
DOI: http://dx.doi.org/10.1007/s10953-008-9321-z
Título revista:Journal of Solution Chemistry
Título revista abreviado:J. Solut. Chem.
ISSN:00959782
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00959782_v37_n10_p1379_Alvarez

Referencias:

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Citas:

---------- APA ----------
Alvarez, J.L. & Fernández Prini, R. (2008) . Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update. Journal of Solution Chemistry, 37(10), 1379-1392.
http://dx.doi.org/10.1007/s10953-008-9321-z
---------- CHICAGO ----------
Alvarez, J.L., Fernández Prini, R. "Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update" . Journal of Solution Chemistry 37, no. 10 (2008) : 1379-1392.
http://dx.doi.org/10.1007/s10953-008-9321-z
---------- MLA ----------
Alvarez, J.L., Fernández Prini, R. "Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update" . Journal of Solution Chemistry, vol. 37, no. 10, 2008, pp. 1379-1392.
http://dx.doi.org/10.1007/s10953-008-9321-z
---------- VANCOUVER ----------
Alvarez, J.L., Fernández Prini, R. Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update. J. Solut. Chem. 2008;37(10):1379-1392.
http://dx.doi.org/10.1007/s10953-008-9321-z