Navegar

Colección

Datos Estadísticas

Artículo

Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

Conductivity equations, based on the mean spherical approximation (MSA), have recently been derived. We compare their performance with that of classical equations at the level of experimental uncertainty using conductivity data for some typical electrolyte solutions. For symmetrical electrolytes, the picture is consistent showing a better performance for the classical equations. The Lee and Wheaton equation also shows advantages at moderate concentrations. For unsymmetrical electrolytes, the differences between MSA and classical equations is larger. There is, however, an inherent inconsistency with the equilibrium information, which cannot be resolved at present.

Registro:

Documento: Artículo
Título:Comparison of electrolytic conductivity theories: Performance of classical and new theories
Autor:Bianchi, H.L.; Dujovne, I.; Fernández-Prini, R.
Filiación:Unidad Actividad Química, Comision Nac. de Energia Atomica, Av. Libertador 8250, 1429-Capital Federal, Argentina
INQUIMAE, Fac. Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428-Capital Federal, Argentina
Palabras clave:Conductivity; Electrolyte theory; Electrolytes
Año:2000
Volumen:29
Número:3
Página de inicio:237
Página de fin:253
DOI: http://dx.doi.org/10.1023/A:1005198316676
Título revista:Journal of Solution Chemistry
Título revista abreviado:J. Solut. Chem.
ISSN:00959782
CODEN:JSLCA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00959782_v29_n3_p237_Bianchi

Referencias:

  • Gruskiewicz, M.S., Wood, R., (1997) J. Phys. Chem., 101, p. 6549
  • Zimmerman, G., Gruskiewicz, M.S., Wood, R., (1995) J. Phys. Chem., 99, p. 11612
  • Ho, P., Palmer, D., (1997) Geochim. Cosmochim. Acta, 61, p. 3027
  • Fernández-Prini, R., (1973) Physical Chemical Organic Solvent Systems, , A. K. Covington and T. Dickinson, eds. Plenum Press, London, Chap. 5
  • Bianchi, H., Corti, H., Fernández-Prini, R., (1994) J. Solution Chem., 23, p. 1203
  • Bernard, O., Kunz, W., Turq, P., Blum, L., (1992) J. Phys. Chem., 96, p. 3833
  • Turq, P., Blum, L., Bernard, O., Kunz, W., (1995) J. Phys. Chem., 99, p. 822
  • Durand-Vidal, S., Turq, P., Bernard, O., (1996) J. Phys. Chem., 100, p. 17345
  • Fuoss, R., Hsia, K.-L., (1967) Proc. Natl. Acad. Sci. U.S., 57, p. 1550
  • Fernández-Prini, R., (1969) Trans. Faraday Soc., 65, p. 3311
  • Bianchi, H., Corti, H., Fernández-Prini, R., (1987) J. Chem. Soc. Faraday Trans. I, 83, p. 3027
  • Chhih, A., Turq, P., Bernard, O., Barthel, J., Blum, L., (1994) Ber. Bunsenges. Phys. Chem., 98, p. 1516
  • Leist, M., (1955) Z. Physik. Chem. (Leipzig), 205, p. 16
  • Pitts, E., (1953) Proc. Roy. Soc., 217 A, p. 41
  • Fuoss, R., Onsager, L., (1957) J. Phys. Chem., 61, p. 668
  • Blum, L., Hoye, S., (1977) J. Phys. Chem., 81, p. 1311
  • Blum, L., (1980) Theoretical Chemistry: Advances and Perspectives, 5. , Academic Press, New York
  • Lee, W., Wheaton, R., (1978) J. Chem. Soc. Faraday Trans. II, 74 (743), p. 1456
  • Lee, W., Wheaton, R., (1979) J. Chem. Soc. Faraday Trans. II, 75, p. 1128
  • Bernard, O., (1997), private communication; Bianchi, H., Fernández-Prini, R., (1993) J. Solution Chem., 22, p. 557
  • Shedlovsky, T., Brown, A.S., McInnes, D.A., (1934) Trans. Electrochem. Soc., 66, p. 165
  • Pethybridge, A.D., Taba, S.S., (1977) J. Chem. Soc. Faraday Trans. I, 64, p. 274
  • Johari, G.P., Tewari, P.H., (1965) J. Phys. Chem., 69, p. 2862
  • Bianchi, H., Corti, H.R., Prini, R.F., (1988) J. Solution Chem., 17, p. 1059
  • Jones, G., Bickford, C.F., (1934) J. Phys. Chem., 56, p. 602
  • Wu, Y.C., Hoch, W.F., Hamer, W.J., Kay, R.L., (1990) J. Solution Chem., 19, p. 1053
  • Gunning, H.E., Gordon, A.R., (1942) J. Chem. Phys., 10, p. 126
  • Chiu, Y.-C., Fuoss, R.M., (1968) J. Phys. Chem., 72, p. 4123
  • Corti, H., Fernández-Prini, R., (1986) J. Chem. Soc. Faraday Trans., 82, p. 921
  • Fernández-Prini, R., Corti, H., Japas, M., (1992) High-Temperature Aqueous Solutions: Thermodynamic Properties, , CRC Press, Boca Raton, FL
  • Bjerrum, N., (1926) K. Dan. Vidensk. Selsk. Skr., 7, p. 9
  • Robinson, R.A., Stokes, R.H., (1959) Electrolyte Solutions, , Butterworths, London
  • Friedman, H.L., (1962) Ionic Solution Theory, , Wiley (Interscience), New York
  • Prue, J., (1966) Ionic Equilibria, , Pergamon Press, Oxford
  • Shedlovsky, T., Brown, A.S., (1934) J. Amer. Chem. Soc., 56, p. 1066
  • Shedlovsky, T., MacInnes, D., (1939) J. Amer. Chem. Soc., 61, p. 200
  • Malatesta, F., Giacomelli, A., Zamboni, R., (1994) J. Solution Chem., 23, p. 11
  • Gammons, C., Wood, S., Williamns-Jones, A., (1996) Geochim. Cosmochim. Acta, 60, p. 4615
  • Scatchard, G., Vonnegut, B., Beaumont, D., (1960) J. Chem. Phys., 33, p. 1292
  • Onsager, L., (1933) Chem. Rev., 13, p. 73

Citas:

---------- APA ----------
Bianchi, H.L., Dujovne, I. & Fernández-Prini, R. (2000) . Comparison of electrolytic conductivity theories: Performance of classical and new theories. Journal of Solution Chemistry, 29(3), 237-253.
http://dx.doi.org/10.1023/A:1005198316676
---------- CHICAGO ----------
Bianchi, H.L., Dujovne, I., Fernández-Prini, R. "Comparison of electrolytic conductivity theories: Performance of classical and new theories" . Journal of Solution Chemistry 29, no. 3 (2000) : 237-253.
http://dx.doi.org/10.1023/A:1005198316676
---------- MLA ----------
Bianchi, H.L., Dujovne, I., Fernández-Prini, R. "Comparison of electrolytic conductivity theories: Performance of classical and new theories" . Journal of Solution Chemistry, vol. 29, no. 3, 2000, pp. 237-253.
http://dx.doi.org/10.1023/A:1005198316676
---------- VANCOUVER ----------
Bianchi, H.L., Dujovne, I., Fernández-Prini, R. Comparison of electrolytic conductivity theories: Performance of classical and new theories. J. Solut. Chem. 2000;29(3):237-253.
http://dx.doi.org/10.1023/A:1005198316676