Navegar

Colección

Datos Estadísticas

Artículo

Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The densities of boric acid aqueous solutions and sodium hydroxide-sodium borate mixtures were measured as a function of concentration, between 375 and 523 K at pressures close to saturation. The partial molar volumes of boric acid were obtained and it was found that they are almost independent of the concentration. The partial molar volumes of the sodium hydroxide-sodium borate mixtures were fitted to the Pitzer equation for mixtures using the known parameters for NaOH. Thus, the partial molar volume at infinite dilution and the Pitzer parameters of sodium borate could be obtained by assuming ideal mixing.

Registro:

Documento: Artículo
Título:Volumetric properties of aqueous electrolytes at high temperature. II. B(OH)3 and B(OH)3-NaB(OH)4-NaOH mixtures up to 523 K
Autor:Ganopolsky, J.G.; Bianchi, H.L.; Corti, H.R.
Filiación:Departamento de Química, Comn. Nac. de Ener. Atómica, Av. Libertador 8250, 1429 Buenos Aires, Argentina
Inst. de Quim. Fis. de Materiales, Medio Ambiente Y Energía, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina
Palabras clave:Borate aqueous solutions; Boric acid; Densities; High temperature; Mixtures hydroxide-borate; Partial molar volumes
Año:1996
Volumen:25
Número:4
Página de inicio:377
Página de fin:389
DOI: http://dx.doi.org/10.1007/BF00972893
Título revista:Journal of Solution Chemistry
Título revista abreviado:J. Solut. Chem.
ISSN:00959782
CODEN:JSLCA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00959782_v25_n4_p377_Ganopolsky

Referencias:

  • Corti, H.R., Svarc, F.E., (1995) J. Solution Chem., 24, p. 121
  • Corti, H.R., Crovetto, R., Fernandez Prini, R., (1980) J. C. S. Faraday I, 76, p. 2179
  • Corti, H.R., Fernandez Prini, R., Svarc, F.E., (1990) J. Solution Chem., 19, p. 793
  • Simonson, J.M., Ryther, R.J., (1989) J. Chem. Eng. Data, 34, p. 57
  • Ellis, A.J., (1966) Chem. Commun., 21, p. 802
  • Ward, G.K., Millero, F.J., (1974) J. Solution Chem., 3, p. 417
  • Hovey, J.K., (1988), Ph. D. Thesis. University of Alberta, Edmonton, Canada; Sobol, V.N., Puchkov, L.V., Zarembo, V.I., (1991) Geokhimiya., 9, p. 1349
  • Hnedkovsky, L., Majer, V., Wood, R.H., (1995) J. Chem. Thermodyn., 27, p. 801
  • Alekhin, D.S., Tsai, S.V., Puchkov, L.V., Zarembo, V.I., (1993) Russ. J. Appl. Chem., 66, p. 360
  • Alekhin, D.S., Tsai, S.V., Gilyarov, V.N., Puchkov, L.V., Zarembo, V.I., (1993) Russ. J. Appl. Chem., 66, p. 363
  • Sobol, V.N., Gilyarov, V.N., Zarembo, V.I., (1993) Russian J. Appl. Chem., 66, p. 353
  • Mashovets, V.P., Puchkov, L.V., Sidorova, S.N., Fedorov, M.K., (1972) Russian J. Appl. Chem., 47, p. 548
  • Devina, O.A., Yefimov, M.Y., Medvedev, V.A., Khodakovskiy, L.L., (1982) Geokhimiya, 4, p. 550
  • Hill, P.G., MacMillan, R.D., Lee, V., (1982) J. Phys. Chem. Ref. Data, 11, p. 1
  • Hill, P.G., (1990) J. Phys. Chem. Ref. Data, 19, p. 1233
  • Archer, D.G., Wang, P.J., (1990) J. Phys. Chem. Ref. Data, 19, p. 371
  • Mesmer, R.H., Baes C.F., Jr., Sweeton, F.H., (1972) Inorganic Chem., 11, p. 537
  • Sweeton, F.H., Mesmer, R.H., Baes C.F., Jr., (1974) J. Solution Chem., 3, p. 191
  • Pitzer, K.S., (1987) Rev. Mineral., 17, p. 97
  • Tanger J.C. IV, Helgeson, H.C., (1988) Amer. J. Sci., 288, p. 19
  • Shock, E.L., Helgeson, H.C., (1988) Geochim. Cosmochim. Acta, 52, p. 2009
  • Ganopolsky, J., Bianchi, H., Corti, H.R., (1996) J. Solution Chem., 25, p. 391

Citas:

---------- APA ----------
Ganopolsky, J.G., Bianchi, H.L. & Corti, H.R. (1996) . Volumetric properties of aqueous electrolytes at high temperature. II. B(OH)3 and B(OH)3-NaB(OH)4-NaOH mixtures up to 523 K. Journal of Solution Chemistry, 25(4), 377-389.
http://dx.doi.org/10.1007/BF00972893
---------- CHICAGO ----------
Ganopolsky, J.G., Bianchi, H.L., Corti, H.R. "Volumetric properties of aqueous electrolytes at high temperature. II. B(OH)3 and B(OH)3-NaB(OH)4-NaOH mixtures up to 523 K" . Journal of Solution Chemistry 25, no. 4 (1996) : 377-389.
http://dx.doi.org/10.1007/BF00972893
---------- MLA ----------
Ganopolsky, J.G., Bianchi, H.L., Corti, H.R. "Volumetric properties of aqueous electrolytes at high temperature. II. B(OH)3 and B(OH)3-NaB(OH)4-NaOH mixtures up to 523 K" . Journal of Solution Chemistry, vol. 25, no. 4, 1996, pp. 377-389.
http://dx.doi.org/10.1007/BF00972893
---------- VANCOUVER ----------
Ganopolsky, J.G., Bianchi, H.L., Corti, H.R. Volumetric properties of aqueous electrolytes at high temperature. II. B(OH)3 and B(OH)3-NaB(OH)4-NaOH mixtures up to 523 K. J. Solut. Chem. 1996;25(4):377-389.
http://dx.doi.org/10.1007/BF00972893