Abstract:
Eight new copper(II) complexes with halo-aspirinate anions have been synthesized: [Cu 2(Fasp) 4(MeCN) 2]·2MeCN (1), [Cu 2(Clasp) 4(MeCN) 2]·2MeCN (2), [Cu 2(Brasp) 4 (MeCN) 2]·2MeCN (3), {[Cu 2(Fasp) 4(Pyrz)]·2MeCN} n (4), {[Cu 2(Clasp) 4(Pyrz)]·2MeCN} n (5), [Cu 2(Brasp) 4(Pyrz)] n (6), [Cu 2(Clasp) 4(4,4'-Bipy)] n (7), and [Cu 2(Brasp) 4(4,4'-Bipy)] n (8) (Fasp: fluor-aspirinate; Clasp: chloro-aspirinate; Brasp: bromo-aspirinate; MeCN: acetonitrile; Pyrz: pyrazine; 4,4'-Bipy: 4,4'-bipyridine). The crystal structure of two 2 and 4 have been determined by X-ray diffraction methods. All compounds have been studied employing elemental analysis, IR, and UV-Visible spectroscopic techniques. The results have been compared with previous data reported for complexes with similar structures. © 2012 Taylor & Francis.
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Documento: |
Artículo
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Título: | Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥ |
Autor: | Rustoy, E.M.; Agotegaray, M.; Piro, O.E.; Castellano, E.E. |
Filiación: | Departamento de Quimica Orgánica y UMYMFOR (CONICET-UBA), Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, 3 Piso, C. Universitaria, Argentina Departamento de Química, INQUISUR, Universidad Nacional del Sur, Avda. Alem 1253, B8000CPB Bahía Blanca, Argentina Departamento de Física e Instituto IFLP (CONICET, CCT-La Plata), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C.C. 67, 1900 La Plata, Argentina Instituto de Física de São Paulo, C.P. 369, 13560 São Carlos, SP, Brazil
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Palabras clave: | Copper(II) complexes; Crystal structures; Haloaspirinate anions |
Año: | 2012
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Volumen: | 65
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Número: | 13
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Página de inicio: | 2341
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Página de fin: | 2352
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DOI: |
http://dx.doi.org/10.1080/00958972.2012.691477 |
Título revista: | Journal of Coordination Chemistry
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Título revista abreviado: | J. Coord. Chem.
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ISSN: | 00958972
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CODEN: | JCCMB
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00958972_v65_n13_p2341_Rustoy |
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Citas:
---------- APA ----------
Rustoy, E.M., Agotegaray, M., Piro, O.E. & Castellano, E.E.
(2012)
. Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥. Journal of Coordination Chemistry, 65(13), 2341-2352.
http://dx.doi.org/10.1080/00958972.2012.691477---------- CHICAGO ----------
Rustoy, E.M., Agotegaray, M., Piro, O.E., Castellano, E.E.
"Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥"
. Journal of Coordination Chemistry 65, no. 13
(2012) : 2341-2352.
http://dx.doi.org/10.1080/00958972.2012.691477---------- MLA ----------
Rustoy, E.M., Agotegaray, M., Piro, O.E., Castellano, E.E.
"Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥"
. Journal of Coordination Chemistry, vol. 65, no. 13, 2012, pp. 2341-2352.
http://dx.doi.org/10.1080/00958972.2012.691477---------- VANCOUVER ----------
Rustoy, E.M., Agotegaray, M., Piro, O.E., Castellano, E.E. Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥. J. Coord. Chem. 2012;65(13):2341-2352.
http://dx.doi.org/10.1080/00958972.2012.691477