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Abstract:

Eight new copper(II) complexes with halo-aspirinate anions have been synthesized: [Cu 2(Fasp) 4(MeCN) 2]·2MeCN (1), [Cu 2(Clasp) 4(MeCN) 2]·2MeCN (2), [Cu 2(Brasp) 4 (MeCN) 2]·2MeCN (3), {[Cu 2(Fasp) 4(Pyrz)]·2MeCN} n (4), {[Cu 2(Clasp) 4(Pyrz)]·2MeCN} n (5), [Cu 2(Brasp) 4(Pyrz)] n (6), [Cu 2(Clasp) 4(4,4'-Bipy)] n (7), and [Cu 2(Brasp) 4(4,4'-Bipy)] n (8) (Fasp: fluor-aspirinate; Clasp: chloro-aspirinate; Brasp: bromo-aspirinate; MeCN: acetonitrile; Pyrz: pyrazine; 4,4'-Bipy: 4,4'-bipyridine). The crystal structure of two 2 and 4 have been determined by X-ray diffraction methods. All compounds have been studied employing elemental analysis, IR, and UV-Visible spectroscopic techniques. The results have been compared with previous data reported for complexes with similar structures. © 2012 Taylor & Francis.

Registro:

Documento: Artículo
Título:Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥
Autor:Rustoy, E.M.; Agotegaray, M.; Piro, O.E.; Castellano, E.E.
Filiación:Departamento de Quimica Orgánica y UMYMFOR (CONICET-UBA), Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, 3 Piso, C. Universitaria, Argentina
Departamento de Química, INQUISUR, Universidad Nacional del Sur, Avda. Alem 1253, B8000CPB Bahía Blanca, Argentina
Departamento de Física e Instituto IFLP (CONICET, CCT-La Plata), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C.C. 67, 1900 La Plata, Argentina
Instituto de Física de São Paulo, C.P. 369, 13560 São Carlos, SP, Brazil
Palabras clave:Copper(II) complexes; Crystal structures; Haloaspirinate anions
Año:2012
Volumen:65
Número:13
Página de inicio:2341
Página de fin:2352
DOI: http://dx.doi.org/10.1080/00958972.2012.691477
Título revista:Journal of Coordination Chemistry
Título revista abreviado:J. Coord. Chem.
ISSN:00958972
CODEN:JCCMB
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00958972_v65_n13_p2341_Rustoy

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Citas:

---------- APA ----------
Rustoy, E.M., Agotegaray, M., Piro, O.E. & Castellano, E.E. (2012) . Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥. Journal of Coordination Chemistry, 65(13), 2341-2352.
http://dx.doi.org/10.1080/00958972.2012.691477
---------- CHICAGO ----------
Rustoy, E.M., Agotegaray, M., Piro, O.E., Castellano, E.E. "Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥" . Journal of Coordination Chemistry 65, no. 13 (2012) : 2341-2352.
http://dx.doi.org/10.1080/00958972.2012.691477
---------- MLA ----------
Rustoy, E.M., Agotegaray, M., Piro, O.E., Castellano, E.E. "Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥" . Journal of Coordination Chemistry, vol. 65, no. 13, 2012, pp. 2341-2352.
http://dx.doi.org/10.1080/00958972.2012.691477
---------- VANCOUVER ----------
Rustoy, E.M., Agotegaray, M., Piro, O.E., Castellano, E.E. Crystal structure and spectroscopic properties of polymeric adducts of the tetra-μ-haloaspirinate-dicopper(II)⊥. J. Coord. Chem. 2012;65(13):2341-2352.
http://dx.doi.org/10.1080/00958972.2012.691477