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Abstract:

The viscosity of aqueous solutions of sucrose and trehalose is analyzed over a wide range of concentrations and temperatures covering the normal liquid and supercooled liquid regions, close to the glass transition temperature. These sugar solutions are fragile systems whose viscosity exhibits temperature dependence with a large departure from Arrhenius behavior. A description of the temperature and concentration dependences of the solution viscosity is given in terms of a scaled Arrhenius representation, which adopts the reduced temperature Tg T as the state variable. A comparison with results obtained from other theoretical or semiempirical equations is also presented. © 2008 American Institute of Physics.

Registro:

Documento: Artículo
Título:Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime
Autor:Longinotti, M.P.; Corti, H.R.
Filiación:Unidad de Actividad Química, Comisión Nacional de Energía Atómica, Av. General Paz 1499 (1650), San Martín, Buenos Aires, Argentina
Departamento de Física de la Materia Condensada, Comisión Nacional de Energía Atómica, Av. General Paz 1499 (1650), San Martín, Buenos Aires, Argentina
Instituto de Química Física de Los Materiales, Medio Ambiente y Energía, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria (1428), Buenos Aires, Argentina
Palabras clave:Aqueous solutions; Fragility; Sucrose; Supercooled; Trehalose; Viscosity
Año:2008
Volumen:37
Número:3
Página de inicio:1503
Página de fin:1515
DOI: http://dx.doi.org/10.1063/1.2932114
Título revista:Journal of Physical and Chemical Reference Data
Título revista abreviado:J. Phys. Chem. Ref. Data
ISSN:00472689
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00472689_v37_n3_p1503_Longinotti

Referencias:

  • Carpenter, J.F., Martin, B., Crowe, L.M., Crowe, J.H., (1987) Cryobiology, 24, p. 455
  • Crowe, J.H., Crowe, L.M., Oliver, A.E., Tsvetkova, N., Wolkers, W., Tablin, F., (2001) Cryobiology, 43, p. 89
  • Einstein, A., (1906) Ann. Phys., 19, p. 289
  • Hincha, D.K., (1989) Biochim. Biophys. Acta, 2670, p. 1
  • Israeli, E., Staffer, B.T., Lighthardt, B., (1993) Cryobiology, 30, p. 519
  • Roser, B., (1991) Biopharm., 23, p. 47
  • Longinotti, M.P., Corti, H.R., (2007) Electrochem. Commun., 9, p. 1444
  • Jones, G., Dole, M., (1929) J. Am. Chem. Soc., 51, p. 2950
  • Huggins, M.L., (1942) J. Am. Chem. Soc., 64, p. 2716
  • Vand, V., Vand, V., (1948) J. Phys. Chem., 52, p. 277. , 0022-3654 10.1021/j150458a001, ();, J. Phys. Chem. 52, 314 (1948)
  • Simha, R., (1952) J. Appl. Phys., 23, p. 1020
  • Ǵnotelle, J., (1978) Ind. Alim. Agric., 95, p. 747
  • Kaganov, M., (1949) Sakharnaia Prom., 22, p. 21
  • Angell, C.A., (1988) J. Phys. Chem. Solids, 49, p. 863
  • Angell, C.A., (2002) Chem. Rev. (Washington, D.C.), 102, p. 2627
  • Williams, M.L., Landel, R.F., Ferry, J.D., (1955) J. Am. Chem. Soc., 77, p. 3701
  • Soesanto, T., Williams, M.C., (1981) J. Phys. Chem., 85, p. 3338
  • Rössler, E., (1990) Phys. Rev. Lett., 65, p. 1595
  • Rössler, E., (1990) J. Phys. Chem., 92, p. 3725
  • Götze, W., Sjögren, L., (1992) Rep. Prog. Phys., 55, p. 241
  • Richert, R., Bässler, H., (1990) J. Phys.: Condens. Matter, 2, p. 2273
  • Arkhipov, V.I., Bässler, H., (1994) J. Phys. Chem., 98, p. 662
  • Arkhipov, V.I., Bässler, H., (1994) J. Non-Cryst. Solids, 172, p. 396
  • Wagnerowski, K., (1976) Gaz. Cukrow., 84, p. 241
  • Mathlouthi, M., Ǵnotelle, J., (1995) Sucrose Properties and Applications, p. 126. , in, edited by M. Mathlouthi and P. Reiser (Blackie Academic, Glasgow, UK),
  • Erszterle, M., (1990) Zuckerind., 115, p. 263
  • Först, P., Werner, F., Delgado, A., (2002) Rheol. Acta, 41, p. 369
  • Bingham, E.C., Jackson, R.F., (1917) Bur. Stand. (U.S.), Bull., 14, p. 59
  • Bennett, A.N., Nees, A.R., (1930) Ind. Eng. Chem., 22, p. 91
  • Landt, E., (1935) Z. Wirtschaftsgruppe Zuckerind., 85, p. 395
  • Landt, E., (1936) Z. Wirtschaftsgruppe Zuckerind., 86, p. 8
  • Jones, G., Stauffer, R.E., (1937) J. Am. Chem. Soc., 59, p. 1630
  • Swindells, J.F., Jackson, R.F., Cragoe, C.S., (1942) Polarimetry, Saccharimetry, and the Sugars, , Nat. Bur. Stand. (U.S.) Circ. No. 440 (U.S. GPO, Washington, D.C.)
  • Landt, E., (1953) Zucker, 6, p. 558
  • Landt, E., (1954) Zucker, 7, p. 214
  • Swindells, J.F., Hardy, R.C., Cottington, R.L., (1954) J. Res. Natl. Bur. Stand., 52, p. 105
  • Swindells, J.F., Snyder, C.F., Hardy, R.C., Golden, E., (1958) Viscosities of Sucrose Solutions at Various Temperatures: Tables of Recalculated Values, , Nat. Bur. Stand. (U.S.) Circ. No. 440 Supplement (U.S. GPO, Washington, D.C.)
  • Berg, R.F., Harvey, A.H., (personal communication); Schneider, F., Schliephake, D., Klimmek, A., (1963) Zucker, 16, p. 465
  • Reiser, P., Birch, G.C., Mathlouthi, M., (1995) Sucrose Properties and Applications, p. 186. , in, edited by M. Mathlouthi and P. Reiser (Blackie Academic, Glasgow, UK),
  • Bellows, R.J., King, J., (1973) AIChE Symp. Ser., 69, p. 33
  • James, C.J., Mulcahy, D.E., Steel, B.J., (1984) J. Phys. D: Appl. Phys., 17, p. 225
  • Kerr, W.L., Reid, D.S., (1994) Lebensm.-Wiss. Technol., 27, p. 225
  • Christoph, D., Schmidt, T., Senge, B., Schmidt, T., (1998) Zuckerindustrie, 123, p. 876. , viscosity data reported by, Ph.D. thesis, University of Berlin, 2000
  • Rampp, M., Buttersack, C., Lüdemann, H.D., (2000) Ind. Eng. Chem. Res., 39, p. 4400
  • Chenlo, F., Moreira, R., Pereira, G., Ampudia, A., (2002) J. Food. Eng., 54, p. 347
  • Quintas, M., Brandao, T.R.S., Silva, C.L.M., Cuhna, R.L., (2006) J. Food. Eng., 77, p. 844
  • (1998), http://www.iso.org/iso/iso/catalogue_catalogue/tc/catalogue_detail.htm? csnumber=2860, ISO/ TR 3666: accessible through the URL; Miller, D.P., De Pablo, J.J., Corti, H.R., (1997) Pharm. Res., 14, p. 578
  • Miller, D.P., De Pablo, J.J., Corti, H.R., (1999) J. Phys. Chem. B, 103, p. 10243
  • Magaz, S., Maisano, G., Migliardo, P., Middendorf, H.D., Villari, V., (1998) J. Chem. Phys., 109, p. 1170
  • Magaz, S., Maisano, G., Migliardo, P., Villari, V., (1999) J. Chem. Phys., 111, p. 9086
  • Branca, C., Magaz, S., Maisano, G., Migliardo, P., Villari, V., Sokolov, A.P., (1999) J. Phys.: Condens. Matter, 11, p. 3823
  • Branca, C., Magaz, S., Maisano, G., Migliardo, F., Migliardo, P., Romeo, G., (2001) J. Phys. Chem. B, 105, p. 10140
  • Elias, M.E., Elias, A.M., (1999) J. Mol. Liq., 83, p. 303
  • Miller, D.P., Conrad, P.B., Fucito, S., Corti, H.R., De Pablo, J.J., (2000) J. Phys. Chem. B, 104, p. 10419
  • Rampp, M., Buttersack, C., Lüdemann, H.D., (2000) Carbohydr. Res., 328, p. 561
  • http://www.aip.org/pubservs/epaps.html, See EPAPS Document No. E-JPCRBU-37-001803 for the source data of the viscosity of sucrose and trehalose aqueous solutions cited in this paper. For more information on EPAPS, see; Angell, C.A., Bressel, R.D., Green, J.L., Kanno, H., Oguni, M., Sare, E.J., (1994) J. Food. Eng., 22, p. 115
  • Gordon, J.M., Taylor, J.S., (1952) J. Appl. Chem., 2, p. 493
  • Longinotti, M.P., (2007), Ph.D. thesis, University of Buenos Aires; Blond, G., Simatos, D., Catt́, M., Dussap, C.G., Gros, J.B., (1997) Carbohydr. Res., 298, p. 139
  • Chen, T., Fowler, A., Toner, M., (2000) Cryobiology, 40, p. 277
  • Luyet, B., Rasmussen, D., (1968) Biodynamica, 10, p. 169
  • Shalaev, E.Y., (1991), Ph. D. thesis, Vector Institute; Green, L., Angell, C.A., (1989) J. Phys. Chem., 93, p. 2880
  • Roos, Y., (1993) Carbohydr. Res., 238, p. 39
  • Roos, Y., Karel, M., (1991) Int. J. Food Sci. Technol., 26, p. 553
  • Izzard, M.J., Abblet, S., Lillford, P., (1991) Food Polymers, Gels and Colloids, p. 289. , in, edited by E. Dickson (The Royal Society of Chemistry, Cambridge, UK),
  • MacKenzie, A.P., (1977) Philos. Trans. R. Soc. London, Ser. B, 278, p. 167
  • Ottenhof, M.A., MacNaughtan, W., Farhat, I.A., (2003) Carbohydr. Res., 338, p. 2195
  • Goff, H.D., (1995) Pure Appl. Chem., 67, p. 1801
  • Saleki-Gerhardt, A., (1993), Ph.D. thesis, University of Wisconsin; Frank, G., (2007) J. Phys. Chem. Ref. Data, 36, p. 1279
  • Quintas, M., Brandao, T.R.S., Silva, C.L.M., Cuhna, R.L., (2007) J. Phys. Chem. B, 111, p. 3192
  • Mageean, M.P., Kristott, J.U., Jones, S.A., (1991) BFMIRA Scientific and Technical Survey No. 172, p. 251. , in, 2nd ed. (British Food Industries Research Association, Leatherhead, UK),

Citas:

---------- APA ----------
Longinotti, M.P. & Corti, H.R. (2008) . Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime. Journal of Physical and Chemical Reference Data, 37(3), 1503-1515.
http://dx.doi.org/10.1063/1.2932114
---------- CHICAGO ----------
Longinotti, M.P., Corti, H.R. "Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime" . Journal of Physical and Chemical Reference Data 37, no. 3 (2008) : 1503-1515.
http://dx.doi.org/10.1063/1.2932114
---------- MLA ----------
Longinotti, M.P., Corti, H.R. "Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime" . Journal of Physical and Chemical Reference Data, vol. 37, no. 3, 2008, pp. 1503-1515.
http://dx.doi.org/10.1063/1.2932114
---------- VANCOUVER ----------
Longinotti, M.P., Corti, H.R. Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime. J. Phys. Chem. Ref. Data. 2008;37(3):1503-1515.
http://dx.doi.org/10.1063/1.2932114